On the characterization of VLF radio signal propagation in atmosphere in quite solar conditions

In this work we use Very Low Frequency (VLF) radio signals, having a frequency in the bands 20-80 kHz, to study the VLF signal propagation in the atmosphere quite undisturbed conditions by selecting the signals recorded during night. As a good approximation, we can model the propagation of VLF radio signals as characterized by a ground-wave and a sky wave propagation mode. The first one generates a radio signal that propagates in the channel ground-troposphere, while the second one generates a signal which propagates using the lower ionosphere as a reflector. The VLF receivers of the INFREP (European Network of Electromagnetic Radiation) network are used. These receivers have been installed since 2009 mainly in southern and central Europe and currently the INFREP network consists of 9 receivers. A 1-minute sampling interval is used to record the amplitude of VLF signals. Long time-series of VLF signals propagating during night are extracted from recorded signals to study possible seasonal effects due to temporal variations in the physical properties of troposphere. A graph theory approach is used to investigate the spatial correlation of the aforementioned effects at different receivers. A multivariate analysis is also applied to identify common temporal changes observed at VLF receivers

Variations revealed by INFREP Radio Network in correspondence of six earthquakes with MW greater than 5.0 occurred in the Balkan Peninsula and Adriatic Sea on 26 and 27 November, 2019

In this work we analyse variations in VLF/LF radio signal amplitudes recorded by the INFREP network in the period 16 November – 6 December, 2019 characterized by very intensive seismic activities in the Balkan peninsula, Crete, and Adriatic, Aegean and Black seas. Namely, 38 earthquakes with magnitude greater than 4.0 occurred in this area during the noticed period; the most intensive of them occurred on 26 and 27 November: three events in Albania (Mw= 6.4, 5.3, 5.1), one in Crete (Mw= 6), one in Bosnia and Herzegovina (Mw= 5.4) and two in Adriatic sea (Mw= 5.4, 5.3). We study both long- and short- term variations that are already recorded in earlier studies. The long-term variations relate to changes in the amplitude intensities in periods of several days and their existence is shown in many previous studies. The recent analyses also indicate short-term variations in signal amplitude noises started about several tents of minutes before the earthquake (Nina et al. 2020). In this work, we analyse different areas using INFREP network, which allow us to study local changes in the atmosphere. In order to examine possible precursors we considered longer time started and ended 10 days before and after the most intensive of the considered earthquakes, respectively

In Situ Growth of Mg-Fe Layered Double Hydroxides (LDH) Film on Titanium Dental Implant Substrates for pH Regulation in Oral Environments

Layered double hydroxides (LDHs) consist of two-dimensional, positively charged lamellar structures with the ability to host various anions in the interlayer spaces, which grants them unique properties and tunable characteristics. LDHs, a class of versatile inorganic compounds, have recently emerged as promising candidates for enhancing osseointegration. A suitable alkaline microenvironment is thought to be beneficial for stimulating osteoblasts’ differentiation (responsible for bone matrix formation) while suppressing osteoclast generation (responsible for bone matrix disintegration). LDHs are prone to adjusting their alkalinity and thus offering us the chance to study how pH affects cellular behavior. LDHs can indeed modulate the local pH, inflammatory responses, and oxidative stress levels, factors that profoundly influence the behavior of osteogenic cells and their interactions with the implant surface. Herein, we deposited Mg–Fe LDH films on titanium substrates for dental implants. The modified Ti substrates was more alkaline in comparison to the bare ones, with a pH higher than 8 after hydrolysis in an aqueous environment

A pre seismic radio anomaly revealed in the area where the Abruzzo earthquake ( M =6.3) occurred on 6 April 2009

Abstract. On 6 April 2009 a strong (Mw=6.3) earthquake occurred in the Abruzzo region (central Italy). Since 1996, the intensity of CLT (f=189 kHz, Sicily, Italy), MCO (f=216 kHz, France) and CZE (f=270 kHz, Czech Republic) broadcast signals has been collected with a ten minutes sampling rate by a receiver operating in a place located about 13 km far from the epicenter. During March 2009, the old receiver was substituted with a new one able to measure, with one minute sampling rate, the intensity of five VLF signals and five LF signals radiated by transmitters located in different zones of Europe. The MCO and CZE transmitters mentioned above are included among them. From 31 March to 1 April the intensity of the MCO radio signal dropped and this drop was observed only in this signal. The possibility that the drop was connected to problems in the transmitter or in the receiver was investigated and excluded. So, the drop indicates a defocusing of the radiated signal. Since no particular meteorological situation along the path transmitter-receiver happened, the defocusing must be related to other causes, and a possibility is presented that it is a precursor of the Abruzzo earthquake

Anomalies in VLF radio signals prior the Abruzzo earthquake (M=6.3) on 6 April 2009

Abstract. The VLF/LF radio signals method for studying preseimic activity is applied to the Abruzzo earthquake (M=6.3, 6 April 2009). The data collected by three receivers located in Moscow (Russia), Graz (Austria) and Bari (Italy) at about 3000 km, 1000 km and 500 km from the epicenter were used. The signals received from the Sardinia (20.27 kHz) and the Sicily (45.9 kHz) transmitters, both located in Italy, were compared with those received from the Iceland (37.5 kHz), the Great Britain (19.58 kHz) and the Germany (23.4 kHz) transmitters. The propagation paths of the two Italian transmitters cross the epicentral area (seismic paths) unlike the paths of the other three signals (control paths). Using two different analyses, that are the study of the night-time signal and the research of shifts in the evening terminator times, clear anomalies were revealed 2–8 days before the occurrence of the Abruzzo earthquake in the seismic paths, while no anomalies have been found in the control paths

Wavelet analysis applied on temporal data sets in order to reveal possible pre-seismic radio anomalies and comparison with the trend of the raw data

Since 2009, several radio receivers have been installed throughout Europe in order to realize the INFREP European radio network for studying the VLF (10-50 kHz) and LF (150-300 kHz) radio precursors of earthquakes. Precursors can be related to “anomalies” in the night-time behavior of VLF signals. A suitable method of analysis is the use of the Wavelet spectra. Using the “Morlet function”, the Wavelet transform of a time signal is a complex series that can be usefully represented by its square amplitude, i.e. considering the so-called Wavelet power spectrum. The power spectrum is a 2D diagram that, once properly normalized with respect to the power of the white noise, gives information on the strength and precise time of occurrence of the various Fourier components, which are present in the original time series. The main difference between the Wavelet power spectra and the Fourier power spectra for the time series is that the former identifies the frequency content along the operational time, which cannot be done with the latter. Anomalies are identified as regions of the Wavelet spectrogram characterized by a sudden increase in the power strength. On January 30, 2020 an earthquake with Mw= 6.0 occurred in Dodecanese Islands. The results of the Wavelet analysis carried out on data collected some INFREP receivers is compared with the trends of the raw data. The time series from January 24, 2020 till January 31, 2000 was analyzed. The Wavelet spectrogram shows a peak corresponding to a period of 1 day on the days before January 30. This anomaly was found for signals transmitted at the frequencies 19,58 kHz, 20, 27 kHz, 23,40 kHz with an energy in the peak increasing from 19,58 kHz to 23,40 kHz. In particular, the signal at the frequency 19,58 kHz, shows a peak on January 29, while the frequencies 20,27 kHz and 23,40 kHz are characterized by a peak starting on January 28 and continuing to January 29. The results presented in this work shows the perspective use of the Wavelet spectrum analysis as an operational tool for the detection of anomalies in VLF and LF signal potentially related to EQ precursors

Study of VLF/LF wave propagations above seismic areas

Abstract: We report on radio transmitter signals recorded in Europe by INFREP network which is mainly devoted to search for earthquakes electromagnetic precursors (Biagi et al., 2011). We consider in this analysis the detection of transmitter signals recorded by INFREP receivers located in different regions of Europe, i.e. Romania, Italy, Greece and Austria. The aim is the investigation of the electromagnetic environment above earthquakes regions. We selected seismic events which occurred in the year 2016 and characterized by a moment magnitude (Mw) above 5.0 and a depth of less than 50 km. A common method is applied to all events and which involves the analysis of the VLF/LF signal detection taking into consideration the following parameters: (a) the distance transmitters-receivers, (b) the signal to noise ratio during the diurnal and night observations, (c) the daily and night averaged amplitude and (d) the sunset and sunrise termination times. This leads us to specify the key factors which can be considered as criteria to distinguish and to identify earthquakes precursors. We discuss in this contribution the radio wave propagation in the D- and E-layers and their impacts on the VLF/LF amplitude signal. We show that the 'seismic anomaly' requests a more precise analysis of the 'quiet' and 'disturbed' ionospheric conditions and their corresponding spectral traces on the VLF/LF transmitter signals

Geochemical and VLF-LF radio precursors of strong earthquakes: a review.

Results obtained by the authors during many years of observations related to hydro-geochemical parameters and LF/VLF radio signals are presented. Firstly, the analysis carried out for more than ten years on the ions and gases content data collected from the groundwater of six deep wells and two natural springs in the southern area of the Kamchatka peninsula (Russia) is reported. The following general statements can be made: a) middle-term precursors could be observed during the preparatory phase of earthquakes with M (magnitude) around 7.0 and larger, located at distances less than 100-150 km from the measurement site; b) for larger distances, short-term precursors could be observed on the occasion of large but very shallow earthquakes and probably, in such cases, the dissolved gases are parameters more sensitive than the ions; c) on the occasion of large earthquakes, post-seismic effects can be observed; d) all the previous effects do not appear at each measurement site of a hydro-geochemical network and it means that they are related to some local phenomenology connected with the underground structural situation; e) long-term (some years) precursors could appear at each measurement site of a hydro-geochemical network. In such a case, probably a great increase of stress must be claimed and, as precursors, the variations could be related to more than only one large earthquake. The mentioned results were obtained in Kamchatka, that is an active margin where the Pacific plate subducts beneath the North American and Eurasia plate. In any case, they should represent the general behavior of the hydro-geochemical parameters in connection with the seismic activity. As concerns the LF and VLF radio signals, the results are reported obtained with the VLF and LF receivers located in Bari (south Italy) and in Assergi (central Italy), respectively. The following general statements can be made: a) a good possibility exists that the earthquakes with M≥4.3 can produce some decrease in the intensity of the VLF radio signals, when the path is near enough to the epicenters. The decreases can represent a pre-seismic or a post-seismic effect. B) the LF radio signals can supply two different types of information related to the ground wave and to the sky wave. Particularly, anomalies appearing mainly in the ground wave could be related to variations in some parameters of the ground and/or of the troposphere , which control the ground wave propagation mode. On the other hand, anomalies mainly appearing in the sky wave seem to be connected with disturbances in the ionosphere. In both the cases, such variations can be produced by the processes that take place during the preparatory phase of earthquakes

The European VLF/LF Radio Network: Advances and Recent Results

Since 2009 a network of VLF (20-60 kHz) and LF (150-300 kHz) radio receivers has been put into operation in Europe in order to study earthquakes precursors. At the moment the network consists of ten receivers three of which are located in Italy, two in Greece and one in Portugal, Romania, Malta, Cyprus and Turkey. The data (sampling rate of 1min) are downloaded automatically at the end of each day and are collected at the Department of Physics of the University of Bari (Italy) that is the central node of the network. A detailed study of the radio data collected in the radio network from July 2009 to September 2011 was performed, using different methods of analysis. In total 27 cases suitable for analyzing were found and successes, i.e. radio anomalies preceding the subsequent earthquake (Mw 5.0) and clearly related to the event, were obtained in 70% of the cases; but increasing the value of the Mw threshold for the earthquakes this percentage seems to increase. Among the different methods of analysis the Wavelet spectra appear to be the most sensitive ones. At the moment a system able to apply on the radio data the Wavelet analysis automatically at the end of each day is being developed. On May 20, 2012 an earthquake with Mw=6.1 occurred in north Italy (Emilia region); the epicenter is located inside the “sensitive” area of the network. The results obtained in such occasion are presented

Using VLF time series from the INFREP network for the study of pre-seismic radio anomalies

This work presents an application of the Perceptually Important Points (PIP) technique for the analysis of VLF time series. The aim of the analysis is to detect anomalies with respect to the normal variations of the data trends. Such anomalies could reveal possible radio precursors of the earthquake. Since 2009, several radio receivers have been installed throughout Europe in order to realize the INFREP European radio network for studying the VLF (10-50 kHz) and LF (150-300 kHz) radio precursors of earthquakes. The time series used for experiments was collected during the Dodecanese islands earthquakes (MW=5.6 and MW=5.7) occurred on January 30, 2020