Effect of Specific Immunoglobulin E Response and Comorbidities on Effectiveness of MP-AzeFlu in a Real-Life Study

Acknowledgements: We would like to thank the subjects who participated in the trial. Funding Sources: This study was supported by MEDA Pharma GmbH & Co. KG (a Mylan Company), Bad Homburg, Germany. Technical, editorial, and medical writing assistance were provided under the direction of the authors by Strategix, an affiliate of The Lynx Group, LLC. This assistance was supported by MEDA Pharma GmbH & Co. KG (a Mylan Company).Peer reviewedPublisher PD

SURPRISING DONOR-ACCEPTOR PREFERENCES IN ALCOHOL DIMERS: A JET-FTIR STUDY

$^{a}$T. H\""aber, U. Schmitt, M.A. Suhm, Phys. Chem. Chem. Phys. 1 (1999) 5573 $^{b}$T. H\""aber, U. Schmitt, C. Emmeluth, M.A. Suhm, Faraday Discuss. 118 (2001) 331Author Institution: Institut f\""ur Physikalische Chemie, Universit\""at G\""ottingenWhen two alcohol molecules pair to form a hydrogen-bonded dimer, one of them will be the hydrogen bond donor, while the other one acts as the hydrogen bond acceptor. From an energetical standpoint, the preferences are often intuitive and can be confirmed by quantum-chemical calculations. A study of OH-stretching fundamentals for a range of alcohol dimers using the ragout-jet FTIR $technique^{a b}$ reveals surprising deviations from such energetical expectations. Pairings including methanol, ethanol, tert.-butanol, perfluoro-tert.-butanol, phenol, cresols and silanols are presented and possible explanations are discussed. For ethanol dimers, the most strongly shifted OH stretching band persists when Ar is added to the expansion. It is therefore due to the most stable dimer conformations and there is evidence that they involve two gauche monomers, although ethanol monomer prefers the trans conformation