4 research outputs found
Space Nuclear Power Systems: Enabling Innovative Space Science and Exploration Missions
The European Space Agency’s (ESA’s) 241Am radioisotope power systems (RPSs) research and development programme is ongoing. The chemical form of the americium oxide ‘fuel’ has yet to be decided. The fuel powder will need to be sintered. The size and shape of the oxide powder particles are expected to influence sintering. The current chemical flow-sheet creates lath-shaped AmO2. Investigations with surrogates help to minimise the work with radioactive americium.
This study has proposed that certain cubic Ce1-xNdxO2-(x/2) oxides (Ia-3 crystal structures with 0.5 < x < 0.7) could be potential surrogates for some cubic AmO2-(x/2) phases. A new wet-chemical-synthesis-based process for fabricating Ce1-xNdxO2-(x/2) with a targeted x-values has been demonstrated. It uses a continuous oxalate coprecipitation and calcination route. An x of 0.6 was nominally targeted. Powder X-ray diffraction (PXRD) and Raman spectroscopy confirmed its Ia-3 structure. An increase in precipitation temperature (25 °C to 60 °C) caused an increase in oxalate particle median size. Lath/plate-shaped particles were precipitated. Ce Nd oxide PXRD data was Rietveld refined to precisely determine its lattice parameter. The data will be essential for future sintering trials with the oxide where variations in its crystal structure during sintering will be investigated.
Sintering investigations with micrometric CeO2 and Nd2O3 have been conducted to understand how AmO2 and Am2O3 may sinter. This is the first reported pure Nd2O3 spark plasma sintering (SPS) investigation. A comparative study on the SPS and the cold-press-and-sinter of CeO2 has been conducted. This is the first study to report sintering lath-shaped CeO2 particles. Differences in their sizes and specific surface areas affected powder cold-pressing and caused variations in cold-pressed-and-sintered CeO2 relative density and Vickers hardness. The targeted density range (85-90%) was met using both sintering techniques. The cold-press-and-sinter method created intact CeO2 discs with reproducible geometry and superior Vickers hardness to those made by SPS
Research in Support of European Radioisotope Power System Development at the European Commission’s Joint Research Centre
Radioisotope Power Systems (RPS) represent a Key Enabling Technology for European autonomy in space exploration. The European Commission’s Joint Research Centre (JRC) is supporting the European Space Agency (ESA) in the development of a European RPS by performing research on Am-241 and Pu-238 based fuel forms. The research activities on Am-241, which is the current technology basis for the ESA programme, are based on three pillars. The first is the optimization of the chemical stabilization of AmO2in its cubic form over a wide range of conditions. JRC research has shown that this can be achieved by addition of a small amount of Uranium, which will allow the pelletisation of AmO2with a suitable microstructure. The second research pillar is the determinationof safety relevant thermophysical properties of stabilized AmO2, as well as safety testing of AmO2under relevant operational and accidental conditions, with emphasis on the pellet integrity and compatibility with the cladding. These activities are performed in close collaboration with ESA and its partner organizations, the National Nuclear Laboratory (NNL) and the University of Leicester, both UK. Recently, a Collaborative Research Agreement between ESA and JRC has been concluded to streamline the common activities and to provide a framework for further development of the research agenda. The third pillar of JRC’s research on Am-241 based RPS is a more basic research-oriented approach to look into other compounds of Am, and to perform a systematic assessment to potentially find alternative chemical forms other than the oxide, which should be stable and have a high specific Am density. So far, five different Am-compounds have been synthesized, were characterized for their chemical and thermophysical properties, and were tested for their stability under relevant conditions, including accident situations and post-accident environments. In addition to the research on Am-241 based RPS, JRC has recently partnered the H-EURATOM collaborative research project PULSAR on the establishment of a European supply chain of Pu-238 for space exploration. In the frame of this project, JRC is investigating the synthesis of stable PuO2pellets with suitable microstructure that is targeted for Pu-238 sources. This work is complemented by an assessment of handling large quantities of Pu-238 with high specific power in a nuclear laboratory, and the development of a Laser welding technique to perform qualified close-welds of Iridium safety encapsulation. In this contribution, we will give an overview of the ongoing work in support of a European RPS development at the Joint Research Centre in Karlsruhe, Germany, as well as an overview of recent research results and an outlook into future activities.</p
Am-241 Powered Dynamic Radioisotope Power System (DRPS) for Long Duration Lunar Rovers
No description supplie
Thermal Properties and Behaviour of Am-Bearing Fuel in European Space Radioisotope Power Systems
The European Space Agency is funding the research and development of 241Am-bearing oxide-fuelled radioisotope power systems (RPSs) including radioisotope thermoelectric generators (RTGs) and European Large Heat Sources (ELHSs). The RPSs’ requirements include that the fuel’s maximum temperature, Tmax, must remain below its melting temperature. The current prospected fuel is (Am0.80U0.12Np0.06Pu0.02)O1.8. The fuel’s experimental heat capacity, Cp, is determined between 20 K and 1786 K based on direct low temperature heat capacity measurements and high temperature drop calorimetry measurements. The recommended high temperature equation is Cp(T/K) = 55.1189 + 3.46216 × 102 T − 4.58312 × 105 T−2 (valid up to 1786 K). The RTG/ELHS Tmax is estimated as a function of the fuel thermal conductivity, k, and the clad’s inner surface temperature, Ti cl, using a new analytical thermal model. Estimated bounds, based on conduction-only and radiation-only conditions between the fuel and clad, are established. Estimates for k (80–100% T.D.) are made using Cp, and estimates of thermal diffusivity and thermal expansion estimates of americium/uranium oxides. The lowest melting temperature of americium/uranium oxides is assumed. The lowest k estimates are assumed (80% T.D.). The highest estimated Tmax for a ‘standard operating’ RTG is 1120 K. A hypothetical scenario is investigated: an ELHS Ti cl = 1973K-the RPSs’ requirements’ maximum permitted temperature. Fuel melting will not occur