1 research outputs found
Kinetic Approach to Elucidate Size Controllable Features in Nanocomposites of Gold Nanoparticles and Poly(3,4-ethylenedioxythiophene) in Aqueous Dispersion Stabilized by Gum Acacia
Research and development of conductive
nanomaterials based on biocompatible
matrices has been greatly rising in the past decade since synergistic
properties can be achieved by combining metallic nanoparticles and
natural/conductive polymers. PolyÂ(3,4-ethylenedioxythiophene) (PEDOT)
is known to be an intrinsically conductive polymer, difficult to handle
in aqueous medium. Therefore, in this work, we present a physical-chemical
perspective in the development of novel aqueous dispersible nanocomposites
of gold nanoparticles (AuNPs) and PEDOT, obtained through a one-pot
synthesis, using the biopolymer gum acacia (GA) as stabilizer. A thorough
kinetic study was carried out and correlated with microscopy analyses,
evidencing that the concentration of GA influences the AuNP size by
affecting their nucleation and growth stages. A quantitative detailing
using kinetic models is shown, which to the best of our knowledge
is the first report relating mechanism and rate constants with size
controllable features of the stabilizer. Two distinct kinetic profiles
were obtained and related to a critical concentration of GA (1%<sub>w/v</sub>): (i) above, a characteristic nucleation–growth
sigmoidal profile and (ii) below, an unexpected bilogistic profile,
accounted to a two-step growth process. Indeed, the bilogistic kinetic
model, usual in population growth studies, is presented herein for
the first time regarding NP formation. These results incite the targeted
design of novel nanomaterials, using kinetic studies as a promising
tool to understand the mechanism of the size-controllable features
of GA. Overall, we evidence that the nanocomposite characteristics
can be optimized rationally. Also, considering the natural occurrence
of GA, we contribute to the sustainable development of highly water-dispersible
PEDOT-derived nanocomposites