2,910 research outputs found
Exclusion zone phenomena in water -- a critical review of experimental findings and theories
The existence of the exclusion zone (EZ), a layer of water in which plastic
microspheres are repelled from hydrophilic surfaces, has now been independently
demonstrated by several groups. A better understanding of the mechanisms which
generate EZs would help with understanding the possible importance of EZs in
biology and in engineering applications such as filtration and microfluidics.
Here we review the experimental evidence for EZ phenomena in water and the
major theories that have been proposed. We review experimental results from
birefringence, neutron radiography, nuclear magnetic resonance, and other
studies. Pollack and others have theorized that water in the EZ exists has a
different structure than bulk water, and that this accounts for the EZ. We
present several alternative explanations for EZs and argue that Schurr's theory
based on diffusiophoresis presents a compelling alternative explanation for the
core EZ phenomenon. Among other things, Schurr's theory makes predictions about
the growth of the EZ with time which have been confirmed by Florea et al. and
others. We also touch on several possible confounding factors that make
experimentation on EZs difficult, such as charged surface groups, dissolved
solutes, and adsorbed nanobubbles.Comment: 14 pg
One- and Two-Dimensional Analysis of Earth Dams
Earth dams may experience reduction in shear strength due to seismically induced pore pressures. Such reduction may be large enough to result in large deformations and eventual loss of the reservoir. While the analysis of embankment dams subject to earthquake loading is a complicated process, it is required for evaluation of seismic stability. In particular, the possibility of liquefaction in older, hydraulically-filled or otherwise poorly compacted dams during earthquakes presents a threat that must be addressed. This paper compares two methods of calculating the peak dynamic shear stress (critical to liquefaction evaluation) that occurs in an embankment during an earthquake. The first method is a one-dimensional analysis, which is simple, rapid and inexpensive. The second method is a two-dimensional finite element analysis, which is complicated, long and expensive. Because it is more desirable to use the simpler one-dimensional analysis, the results from the two analyses were compared and indicated that for slopes up to 35° the stresses were comparable
The Buckland Park air shower array
The new Buckland Park Air Shower Array has been producing analyzed shower data since July 1984. The array is described and some preliminary performance figures are presented
Risk-Seeking versus Risk-Avoiding Investments in Noisy Periodic Environments
We study the performance of various agent strategies in an artificial
investment scenario. Agents are equipped with a budget, , and at each
time step invest a particular fraction, , of their budget. The return on
investment (RoI), , is characterized by a periodic function with
different types and levels of noise. Risk-avoiding agents choose their fraction
proportional to the expected positive RoI, while risk-seeking agents
always choose a maximum value if they predict the RoI to be positive
("everything on red"). In addition to these different strategies, agents have
different capabilities to predict the future , dependent on their
internal complexity. Here, we compare 'zero-intelligent' agents using technical
analysis (such as moving least squares) with agents using reinforcement
learning or genetic algorithms to predict . The performance of agents is
measured by their average budget growth after a certain number of time steps.
We present results of extensive computer simulations, which show that, for our
given artificial environment, (i) the risk-seeking strategy outperforms the
risk-avoiding one, and (ii) the genetic algorithm was able to find this optimal
strategy itself, and thus outperforms other prediction approaches considered.Comment: 27 pp. v2 with minor corrections. See http://www.sg.ethz.ch for more
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Accurate estimation of third-order moments from turbulence measurements
Politano and Pouquet's law, a generalization of Kolmogorov's four-fifths law
to incompressible MHD, makes it possible to measure the energy cascade rate in
incompressible MHD turbulence by means of third-order moments. In
hydrodynamics, accurate measurement of third-order moments requires large
amounts of data because the probability distributions of velocity-differences
are nearly symmetric and the third-order moments are relatively small.
Measurements of the energy cascade rate in solar wind turbulence have recently
been performed for the first time, but without careful consideration of the
accuracy or statistical uncertainty of the required third-order moments. This
paper investigates the statistical convergence of third-order moments as a
function of the sample size N. It is shown that the accuracy of the
third-moment depends on the number of correlation lengths spanned by the data
set and a method of estimating the statistical uncertainty of the third-moment
is developed. The technique is illustrated using both wind tunnel data and
solar wind data.Comment: Submitted to: Nonlinear Processes in Geophysic
The specialty choices of graduates from Brighton and Sussex Medical School: a longitudinal cohort study
BACKGROUND
Since 2007 junior doctors in the UK have had to make major career decisions at a point when previously many had not yet chosen a specialty. This study examined when doctors in this new system make specialty choices, which factors influence choices, and whether doctors who choose a specialty they were interested in at medical school are more confident in their choice than those doctors whose interests change post-graduation.
METHODS
Two cohorts of students in their penultimate year at one medical school (n = 227/239) were asked which specialty interested them as a career. Two years later, 210/227 were sent a questionnaire measuring actual specialty chosen, confidence, influence of perceptions of the specialty and experiences on choice, satisfaction with medicine, personality, self-efficacy, and demographics. Medical school and post-graduation choices in the same category were deemed 'stable'. Predictors of stability, and of not having chosen a specialty, were calculated using bootstrapped logistic regression. Differences between specialties on questionnaire factors were analysed.
RESULTS
50% responded (n = 105/277; 44% of the 239 Year 4 students). 65% specialty choices were 'stable'. Factors univariately associated with stability were specialty chosen, having enjoyed the specialty at medical school or since starting work, having first considered the specialty earlier. A regression found doctors who chose psychiatry were more likely to have changed choice than those who chose general practice. Confidence in the choice was not associated with stability. Those who chose general practice valued lifestyle factors. A psychiatry choice was associated with needing a job and using one's intellect to help others. The decision to choose surgical training tended to be made early. Not having applied for specialty training was associated with being lower on agreeableness and conscientiousness.
CONCLUSION
Medical school experiences are important in specialty choice but experiences post-graduation remain significant, particularly in some specialties (psychiatry in our sample). Career guidance is important at medical school and should be continued post-graduation, with senior clinicians supported in advising juniors. Careers advice in the first year post-graduation may be particularly important, especially for specialties which have difficulty recruiting or are poorly represented at medical school
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