50 research outputs found
Benzodithiazoles-sulfoximines : syntheses of new powerful radical fluoroalkylating reagents
International audienc
Palladium versus Nickel dual catalysis: two routes for coupling ortho-iodoperfluorosulfoximines with thiosugars
International audienc
Hypervalent Iodosulfoximines synthesis - An access to new perfluoroalkylating reagents
International audienc
New access to s-perfluoroalkylated sulfoximines and their functionalization
International audienc
Radicaux perfluoroalkylés: génération, réactivité et mise en évidence par RPE
International audienc
Perfluoroalkylation of aliphatic thiols in the presence of sodium hydroxymethanesulfinate
Direct perfluoroalkylation of aliphatic thiols was performed in the presence of sodium hydroxymethanesulfinate (Rongalite). Reaction of mercaptoalkanoic esters with trifluoromethyl bromide gave the corresponding trifluoromethylthio ethers. Condensation of alkane dithiols with perfluoroalkyl iodides led mainly to fluorinated dithioethers. These alkylation reactions are interpreted as occurring via in situ formation of dialkyldisulfides