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A Sequential Pd/Norbornene-Catalyzed Process Generates <i>o-</i>Biaryl Carbaldehydes or Ketones via a Redox Reaction or 6<i>H</i>‑Dibenzopyrans by C–O Ring Closure
<i>o</i>-Biaryl carbaldeydes and ketones are obtained
through the one-pot reaction of <i>o</i>-aryl iodides with <i>o</i>-bromobenzyl alcohols under the catalytic action of Pd
and norbornene, in the presence of a base. The same reaction can also
give dibenzopyrans by Pd and norbornene catalysis with a different
termination, leading to C–O ring closure. In both cases the
process first leads to a five-membered palladacycle, which controls
C–C coupling, then to a seven-membered oxapalladacycle, which
gives aldehydes and ketones or dibenzopyrans