Contributor Notes

FOR production of standard grade Ferro-manganese the iron content in manganese ores should not exceed certain limits. Vast reserves of ferruginous manganese ores exist in several locations in U. A. R., which do not find good markets on account of their high iron content. Preliminary work showed that the iron content could be successfully reduced by magnetic roasting followed by magnetic sepa-ration. As reduction to the magnetic stage takes place readily in the fluidized state`, it was decided to use the fluidization technique in the present study

A Novel Hydro-Thermal Synthesis of Nano-Structured Molybdenum-Iron Intermetallic Alloys at Relatively Low Temperatures

Nano-structured Mo/Fe intermetallics were synthesized from precursors that contained 72/28% and 30/70% molar ratios of Mo/Fe, which were given as precursors A and B, respectively. These precursors were prepared from the co-precipitation of aqueous hot solutions of ammonium heptamolybdate tetrahydrate (AHM) and ferrous oxalate. The dry precipitates were thermally treated using TG-DSC to follow up their behavior during roasting, in an Ar atmosphere of up to 700 °C (10° K/min). The TG profile showed that 32.5% and 55.5% weight losses were measured from the thermal treatment of precursors A and B, respectively. The DSC heat flow profile showed the presence of endothermic peaks at 196.9 and 392.5–400 °C during the thermal decomposition of the AHM and ferrous oxalate, respectively. The exothermic peak that was detected at 427.5 °C was due to the production of nano-sized iron molybdate [Fe2(MoO4)3]. An XRD phase analysis indicated that iron molybdate was the only phase that was identified in precursor A, while iron molybdate and Fe2O3 were produced in precursor B. Compacts were made from the pressing of the nano-sized precursors, which were roasted at 500 °C for 3 h. The roasted compacts were isothermally reduced in H2 at 600–850 °C using microbalance, and the O2 weight loss that resulted from the reduction reactions was continuously recorded as a function of time. The influence of the reduction temperature and precursor composition on the reduction behavior of the precursors was studied and discussed. The partially and completely reduced compacts were examined with X-ray powder diffraction (XRD), a reflected light microscope (RLM), and a scanning electron microscope (SEM-EDS). Depending on the precursor composition, the reduction reactions of the [Fe2(MoO4)3] and Fe2O3 proceeded through the formation of intermediate lower oxides, prior to the production of the MO/Fe intermetallic alloys. Based on the intermediate phases that were identified and characterized at the early, intermediate, and final reduction degrees, chemical reaction equations were given to follow up the formation of the MoFe and MoFe3 intermetallic alloys. The mechanism of the reduction reactions was predicted from the apparent activation energy values (Ea) that were computed at the different reduction degrees. Moreover, mathematical formulations that were derived from the gas–solid reaction model were applied to confirm the reduction mechanisms, which were greatly dependent on the precursor composition and reduction temperature. However, it can be reported that nano-structured MoFe and MoFe3 intermetallic alloys can be successfully fabricated via a gas–solid reaction technique at lower temperatures

Alternative reducing agents in metallurgical processes : gasification of shredder residue material

Shredder residue material (SRM) contains plastic material, which has a potential to replace metallurgical coal for reduction during bath-smelting processes. Among the important parameters affecting its implementation are the gasification and the reactivity of char. Therefore, prior to considering its application in metallurgical processes, the gasification characteristics of the produced char need to be studied. Although the char produced from SRM contains lower fixed carbon compared with coal char, it has a porous structure and high surface area, which makes it highly reactive during gasification experiments. In addition to physiochemical properties, the catalytic effect of ash content of SRM char is attributed to its higher reactivity and lower activation energy compared with coal char. Furthermore, the effect of devolatilization heating rate on the gasification characteristics of produced char is investigated. It was found that the devolatilization heating rate during char production has a considerable effect on morphological properties of the char product. Moreover, the gasification reactivity of char produced at a fast devolatilization heating rate was the highest, due to the less crystalline structure of the produced char. Validerad; 2017; Nivå 2; 2017-05-12 (andbra)</p

Reduction Behavior and Characteristics of Metal Oxides in the Nanoscale

The development of nanomaterials and nanotechnology enables the production of nanosized metallic alloys with advanced characteristics from their oxides via a thermal reduction technique. The aim of the present work was to produce metallic iron, nickel, and tungsten through the gaseous reduction of nanosized metal oxide powders as a preliminary step towards the fabrication of nanosized heavy tungsten alloys with unique properties. Nanosized NiO, Fe2O3, and WO3 were isothermally and non-isothermally reduced with H2, and the oxygen weight loss was continuously recorded as a function of time. The Thermogravimetric TG-DTA technique was applied in the non-isothermal reduction up to 1000 °C. The reduction extents were calculated from the TG curve, whereas the accompanying heat of the reaction was measured from the DTA curve. The results revealed that NiO was reduced at 2O3 was reduced at 3 was reduced at >950 °C. In the isothermal process, metal oxides were reduced with H2 at 700–1000 °C; a micro-force balance was used and the O2 weight loss was continuously recorded. At a given temperature, the rate of reduction increased in the order NiO > Fe2O3 > WO3. The nano-oxide powders and the reduced products were physically and chemically characterized. The activation energy (Ea) values were computed from the isothermal reduction in the initial and later stages to elucidate the corresponding reduction mechanism. The Ea values indicated that the reduction of metal oxides was controlled by the gas diffusion mechanism at both the initial and later stages of reduction. The results of the present study determined the optimal operation parameters at which the thermal gaseous reduction technique could be applied for preparing metallic alloys from nanosized metal oxides