121 research outputs found
Growth of large single crystals of Rare Earth Hexaborides
Single crystal growth of several rare earth hexaborides has been carried out
by the floating zone technique. A high power Xenon arc lamp image furnace was
used for the crystal growth. Large high quality crystals of LaB,
CeB, PrB and NdB, about 1 cc in volume have been obtained.
Crystals of all these compounds have also been grown using enriched B
isotope for use in neutron scattering experiments.Comment: 3 pages, 3 figures, in press (J. Crystal Growth
Crystal Field, Magnetic Anisotropy and Excitations in Rare-Earth Hexaborides
We clarify the role of crystalline electric field (CEF) induced magnetic
anisotropy in the ground state and spin-wave spectrum of cubic rare-earth
materials with dominating isotropic magnetic exchange interactions. In
particular we study the hexaboride NdB_6 which is shown to exhibit strong
spin-quadrupolar coupling. The CEF scheme is analyzed and a non-collinear
magnetization response is found. The spin orientation in the
antiferromagnetically ordered ground-state is identified. Moreover, the spin
excitations are evaluated and in agreement with inelastic neutron scattering a
suppression of one of the two magnetic modes in the strong-coupling regime is
predicted.Comment: 4 pages, 1 eps-figur
Magnetic Field Dependence of the Paramagnetic to the High Temperature Magnetically Ordered Phase Transition in CeB6
We have measured the magnetic field dependence of the paramagnetic to high
temperature magnetically ordered phase transition TQ(H) in CeB6 from 2 to 30 T
using cantilever magnetometry. It is found that the phase separation
temperature continuously increases in field with an increasingly positive
slope. In addition, we find that measurements in strong magnetic field
gradients have no effect on the phase transition.Comment: 6 total page including 3 figures, submitted to Physical Review B
(also available at
http://publish.aps.org/eprint/gateway/eplist/aps1999dec08_006) v2: Corrected
typos, added 1 reference, minor content changes (deleted 1 sentence in
introduction, added 2 sentences in discussion to explain added reference),
fixed the "et al"s in the bibliograph
Fluctuation Effects on the Quadrupolar Ordering in Magnetic Field
Effects of magnetic field on the quadrupolar ordering are investigated with
inclusion of fluctuation of order parameters. For the simplest model with the
nearest-neighbor quadrupolar interaction, the transition temperature and the
specific heat are derived by the use of the recently proposed effective medium
theory. It is shown that magnetic field H has two competing effects on the
quadrupolar ordering; one is to encourage the ordering by suppressing the
fluctuation among different components of order parameters, and the other is to
block the ordering as in antiferromagnets. The former is found to be of order
H^2 and the latter of order H^4. Hence the fluctuation is suppressed for weak
fields, and the transition temperature increases with magnetic field. The
fluctuation effect is so strong that the entropy released at the quadrupolar
ordering is only about half of the full value ln 4 even without the Kondo
effect.Comment: 10 pages including 3 Postscript figure
Interpocket polarization model for magnetic structures in rare-earth hexaborides
The origin of peculiar magnetic structures in cubic rare-earth (R)
hexaborides RB_6 is traced back to their characteristic band structure. The
three sphere-like Fermi surfaces induce interpocket polarization of the
conduction band as a part of a RKKY-type interaction. It is shown for the
free-electron-like model that the interpocket polarization gives rise to a
broad maximum in the intersite interaction I(q) around q=(1/4,1/4,1/2) in the
Brillouin zone. This maximum is consistent with the superstructure observed in
R=Ce, Gd and Dy. The wave-number dependence of I(q) is independently extracted
from analysis of the spin-wave spectrum measured for NdB_6. It is found that
I(q) obtained from fitting the data has a similarly to that derived by the
interpocket polarization model, except that the absolute maximum now occurs at
(0,0,1/2) in consistency with the A-type structure. The overall shape of I(q)
gives a hint toward understanding an incommensurate structure in PrB_6 as well.Comment: 5 pages, 3 figures, submitted to J.Phys.Soc.Jp
Non-Collinear Magnetism due to Orbital Degeneracy and Multipolar Interactions
The origin of non-collinear magnetism under quadrupolar ordering is
investigated with CeB6 taken as a target system. The mode-mixing effect among
15 multipoles is analyzed based on the Ginzburg-Landau free energy. Then the
lower magnetic transition temperature and the order parameters are derived
within the mean-field approximation. In the presence of pseudo-dipole-type
interactions for the next-nearest neighbors, the observed pattern of
non-collinear ordering is indeed stabilized for certain set of interaction
parameters. The stability of the phase III' in the magnetic field is also
explained, which points to the importance of the next-nearest-neighbor
octupole-octupole interaction. Concerning the phase IV in CexLa1-xB6 with x ~
0.75, a possibility of pure octupole ordering is discussed based on slight
modifications of the strength of interactions.Comment: 12 pages, 7 figures, 3 tables, to appear in J. Phys. Soc. Jpn. 70 (6)
(2001
Large, high quality single-crystals of the new Topological Kondo Insulator, SmB6
SmB6 has recently been predicted to be a Topological Kondo Insulator, the first strongly correlated heavy fermion material to exhibit topological surface states. High quality crystals are necessary to investigate the topological properties of this material. Single crystal growth of the rare earth hexaboride, SmB6, has been carried out by the floating zone technique using a high power xenon arc lamp image furnace. Large, high quality single-crystals are obtained by this technique. The crystals produced by the floating zone technique are free of contamination from flux materials and have been characterised by resistivity and magnetisation measurements. These crystals are ideally suited for the investigation of both the surface and bulk properties of SmB6
Detection of Neutron Scattering from Phase IV of Ce0.7La0.3B6: A Confirmation of the Octupole Order
We have performed a single crystal neutron scattering experiment on
Ce0.7La0.3B6 to investigate the order parameter of phase IV microscopically.
Below the phase transition temperature 1.5 K of phase IV, weak but distinct
superlattice reflections at the scattering vector (h/2,h/2,l/2) (h, l = odd
number) have been observed by neutron scattering for the first time. The
intensity of the superlattice reflections is stronger for high scattering
vectors, which is quite different from the usual magnetic form factor of
magnetic dipoles. This result directly evidences that the order parameter of
phase IV has a complex magnetization density, consistent with the recent
experimental and theoretical prediction in which the order parameter is the
magnetic octupoles Tbeta with Gamma5 symmetry of point group Oh. Neutron
scattering experiments using short wavelength neutrons, as done in this study,
could become a general method to study the high-rank multipoles in f electron
systems.Comment: 4 pages, 4 figure
Orbital Kondo Effect in CeLaB: Scaling Analysis
Peculiarity of the Kondo effect in CeLaB is investigated on
the basis of the scaling equations up to third order. For the case where the
- charge fluctuation enters in addition to the - one, the
effective exchange interaction becomes anisotropic with respect to the orbital
pseudospins which represent the two different orbitals in the ground
state. Because of different characteristic energies for electric and magnetic
tensors, scaling with the single Kondo temperature does not apply to physical
quantities such as the resistivity and magnetic susceptibility. Possibility of
a bizzare phase is pointed out where the RKKY interaction leads to the spin
ordering without orbital ordering. This phase serves as a candidate of the
phase IV which is observed to be isotropic magnetically.Comment: 10 pages, 4 eps figures, submitted to PR
Antiferroquadrupolar Order in the Magnetic Semiconductor TmTe
The physical properties of the antiferroquadrupolar state occurring in TmTe
below TQ=1.8 K have been studied using neutron diffraction in applied magnetic
fields. A field-induced antiferromagnetic component k = (1/2,1/2,1/2) is
observed and, from its magnitude and direction for different orientations of H,
an O(2,2) quadrupole order parameter is inferred. Measurements below TN ~= 0.5
K reveal that the magnetic structure is canted, in agreement with theoretical
predictions for in-plane antiferromagnetism. Complex domain repopulation
effects occur when the field is increased in the ordered phases, with
discontinuities in the superstructure peak intensities above 4 T.Comment: 6 pages, 6 figures, Presented at the International Conference on
Strongly Correlated Electrons with Orbital Degrees of Freedom (ORBITAL 2001),
September 11-14, 2001 (Sendai, JAPAN). To appear in: Journal of the Physical
Society of Japan (2002
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