High resolution cathodoluminescence hyperspectral imaging of surface features in InGaN/GaN multiple quantum well structures

InGaN/GaN multiple quantum wells (MQWs) have been studied by using cathodoluminescence hyperspectral imaging with high spatial resolution. Variations in peak emission energies and intensities across trench-like features and V-pits on the surface of the MQWs are investigated. The MQW emission from the region inside trench-like features is red-shifted by approximately 45 meV and more intense than the surrounding planar regions of the sample, whereas emission from the V-pits is blue-shifted by about 20 meV and relatively weaker. By employing this technique to the studied nanostructures it is possible to investigate energy and intensity shifts on a 10 nm length scale.Comment: 3 pages, 3 figure

Student Demand Projections: Supporting Analysis: Gippsland Tertiary Education Plan

There is considerable interest in the provision of, and access to, tertiary education within Victoria by the State Government. In 2010, a Tertiary Education Plan was released by the Government, detailing various targets and policy objectives in this sector. Despite a change of Government, the broad objectives in the plan continue to be pursued. As such, a number of more specific plans, based on geographic locations within Victoria, are being constructed. One such plan is being constructed for Gippsland. An Expert Panel has been formed to create the plan for Gippsland, chaired by Professor Kwong Lee Dow. This document provides supporting analysis for the Expert Panel to use in the formation of the Gippsland Tertiary Education Plan. Specifically, this document provides a modelling of tertiary demand in the Gippsland region. It provides three projections of attendance rates at technical and vocational courses, and tertiary courses, for persons aged 18-65 in the Gippsland region. For the purpose of this project, Gippsland is divided into 6 Local Government Areas (LGA). These are Baw-Baw, Bass Coast, East Gippsland, La Trobe City, South Gippsland and Wellington

The early evolution of land plants, from fossils to genomics: a commentary on Lang (1937) ‘On the plant-remains from the Downtonian of England and Wales'

© 2015 The Authors. Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited. The file attached is the published version of the article

Influence of substrate miscut angle on surface morphology and luminescence properties of AlGaN

The influence of substrate miscut on Al0.5Ga0.5 N layers was investigated using cathodoluminescence (CL) hyperspectral imaging and secondary electron imaging in an environmental scanning electron microscope. The samples were also characterized using atomic force microscopy and high resolution X-ray diffraction. It was found that small changes in substrate miscut have a strong influence on the morphology and luminescence properties of the AlGaN layers. Two different types are resolved. For low miscut angle, a crack-free morphology consisting of randomly sized domains is observed, between which there are notable shifts in the AlGaN near band edge emission energy. For high miscut angle, a morphology with step bunches and compositional inhomogeneities along the step bunches, evidenced by an additional CL peak along the step bunches, are observed

High-resolution cathodoluminescence hyperspectral imaging of nitride nanostructures

Hyperspectral cathodoluminescence imaging provides spectrally and spatially resolved information on luminescent materials within a single dataset. Pushing the technique toward its ultimate nanoscale spatial limit, while at the same time spectrally dispersing the collected light before detection, increases the challenge of generating low-noise images. This article describes aspects of the instrumentation, and in particular data treatment methods, which address this problem. The methods are demonstrated by applying them to the analysis of nanoscale defect features and fabricated nanostructures in III-nitride-based materials

Fate and Persistence of Crude Oil Stranded on a Sheltered Beach

Detailed observations, mapping and sampling were conducted following an experimental spill of 15 cu m of crude oil adjacent to the coast at Cape Hatt, Baffin Island, N.W.T. The beach could not retain all of the oil that reached the shoreline, and as a result, one-third of the spill oil was recovered in cleanup activities on the water, approximately one-third was lost to the atmosphere and to the ocean and one-third remained stranded on the intertidal zone. The stranded oil was subject to natural cleaning processes during approximately 6 months of open-water periods from 1981 to 1983. Over this period the surface area of oil cover was reduced by approximately half, whereas estimates indicate that 80% of the oil initially stranded (5.3 cu m) was removed. This natural removal of stranded oil occurred in a very sheltered environment. The reduction of the surface area and of the volume of oil resulted primarily from the physical processes associated with wave activity and ground-water leaching. By 1983 an asphalt pavement had developed in the upper intertidal zone on the beach-face slope. Total hydrocarbon concentrations of samples collected from the asphalt pavement indicated a significant increase in oil-in-sediment values in this zone to concentrations in the order of 2-5%. Oil removed from the beach was transported into the adjacent nearshore bottom sediments, where oil concentrations increased sixfold between 1981 and 1983. Physio-chemical weathering rates were relatively rapid immediately following the release of the oil, as the lower molecular weight (C1 to C10) hydrocarbons evaporated. Subsequent physio-chemical changes were heterogeneous .... The primary conclusion from the investigations undertaken to date is that oil is removed in substantial quantities from the intertidal zone even in such a sheltered, low-energy arctic environment. Similar changes should also be expected from comparable environments in lower latitudes.Key words: oil spill, natural oil weathering, asphalt pavement, beached oilMots clés: déversement de pétrole, dégradation naturelle du pétrole, plaque d’asphalte, pétrole échou&eacute

Cathodoluminescence hyperspectral imaging of trench-like defects in InGaN/GaN quantum well structures

Optoelectronic devices based on the III-nitride system exhibit remarkably good optical efficiencies despite suffering from a large density of defects. In this work we use cathodoluminescence (CL) hyperspectral imaging to study InGaN/GaN multiple quantum well (MQW) structures. Different types of trench defects with varying trench width, namely wide or narrow trenches forming closed loops and open loops, are investigated in the same hyperspectral CL measurement. A strong redshift (90 meV) and intensity increase of the MQW emission is demonstrated for regions enclosed by wide trenches, whereas those within narrower trenches only exhibit a small redshift (10 meV) and a slight reduction of intensity compared with the defect-free surrounding area. Transmission electron microscopy (TEM) showed that some trench defects consist of a raised central area, which is caused by an increase of about 40% in the thickness of the InGaN wells. The causes of the changes in luminescences are also discussed in relation to TEM results identifying the underlying structure of the defect. Understanding these defects and their emission characteristics is important for further enhancement and development of light-emitting diodes

A novel FRET-based screen in high-throughput format to identify inhibitors of malarial and human glucose transporters

The glucose transporter PfHT is essential to the survival of the malaria parasite Plasmodium falciparum and has been shown to be a druggable target with high potential for pharmacological intervention. Identification of compounds against novel drug targets is crucial to combating resistance against current therapeutics. Here, we describe the development of a cell-based assay system readily adaptable to high-throughput screening that directly measures compound effects on PfHT-mediated glucose transport. Intracellular glucose concentrations are detected using a genetically encoded fluorescence resonance energy transfer (FRET)-based glucose sensor. This allows assessment of the ability of small molecules to inhibit glucose uptake with high accuracy (Z′ factor of >0.8), thereby eliminating the need for radiolabeled substrates. Furthermore, we have adapted this assay to counterscreen PfHT hits against the human orthologues GLUT1, -2, -3, and -4. We report the identification of several hits after screening the Medicines for Malaria Venture (MMV) Malaria Box, a library of 400 compounds known to inhibit erythrocytic development of P. falciparum. Hit compounds were characterized by determining the half-maximal inhibitory concentration (IC(50)) for the uptake of radiolabeled glucose into isolated P. falciparum parasites. One of our hits, compound MMV009085, shows high potency and orthologue selectivity, thereby successfully validating our assay for antimalarial screening

Reconstructing the archosaur radiation using a Middle Triassic archosauriform tooth assemblage from Tanzania

Following the Permo–Triassic mass extinction, Archosauriformes—the clade that includes crocodylians, birds, and their extinct relatives outside crown Archosauria—rapidly diversified into many distinct lineages, became distributed globally, and, by the Late Triassic, filled a wide array of resource zones. Current scenarios of archosauriform evolution are ambiguous with respect to whether their taxonomic diversification in the Early–Middle Triassic coincided with the initial evolution of dietary specializations that were present by the Late Triassic or if their ecological disparity arose sometime after lineage diversification. Late Triassic archosauriform dietary specialization is recorded by morphological divergence from the plesiomorphic archosauriform tooth condition (laterally-compressed crowns with serrated carinae and a generally triangular lateral profile). Unfortunately, the roots of this diversification are poorly documented, with few known Early­–Middle Triassic tooth assemblages, limiting characterizations of morphological diversity during this critical, early period in archosaur evolution. Recent fieldwork (2007–2017) in the Middle Triassic Manda Beds of the Ruhuhu Basin, Tanzania, recovered a tooth assemblage that provides a window into this poorly sampled interval. To investigate the taxonomic composition of that collection, we built a dataset of continuous quantitative and discrete morphological characters based on in situ teeth of known taxonomic status (e.g., Nundasuchus, Parringtonia: N = 65) and a sample of isolated teeth (N = 31). Using crown heights from known taxa to predict tooth base ratio (= base length/width), we created a quantitative morphospace for the tooth assemblage. The majority of isolated, unassigned teeth fall within a region of morphospace shared by several taxa from the Manda Beds (e.g., Nundasuchus, Parringtonia); two isolated teeth fall exclusively within a “Pallisteria” morphospace. A non-metric multidimensional scaling ordination (N = 67) of 11 binary characters reduced overlap between species. The majority of the isolated teeth from the Manda assemblage fall within the Nundasuchus morphospace. This indicates these teeth are plesiomorphic for archosauriforms as Nundasuchus exhibits the predicted plesiomorphic condition of archosauriform teeth. Our model shows that the conservative tooth morphologies of archosauriforms can be differentiated and assigned to species and/or genus, rendering the model useful for identifying isolated teeth. The large overlap in tooth shape among the species present and their overall similarity indicates that dietary specialization lagged behind species diversification in archosauriforms from the Manda Beds, a pattern predicted by Simpson’s “adaptive zones” model. Although applied to a single geographic region, our methods offer a promising means to reconstruct ecological radiations and are readily transferable across a broad range of vertebrate taxa throughout Earth history