7 research outputs found
Viscoelastic Flows in Simple Liquids Generated by Vibrating Nanostructures
Newtonian fluid mechanics, in which the shear stress is proportional to the strain rate, is synonymous with the flow of simple liquids such as water. We report the measurement and theoretical verification of non-Newtonian, viscoelastic flow phenomena produced by the high-frequency (20 GHz) vibration of gold nanoparticles immersed in water-glycerol mixtures. The observed viscoelasticity is not due to molecular confinement, but is a bulk continuum effect arising from the short time scale of vibration. This represents the first direct mechanical measurement of the intrinsic viscoelastic properties of simple bulk liquids, and opens a new paradigm for understanding extremely high frequency fluid mechanics, nanoscale sensing technologies, and biophysical processes
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Solution and Substrate Assembly of Noble Metal Nanoparticles
Gold Bipyramid Nanoparticle Dimers
An aqueous synthesis of gold bipyramid
dimers is presented. The
methodology, its selectivity, and the characterization of the resulting
structures with optical dark-field and scanning electron microscopy
are presented and discussed. In the bowtie orientation, the dimers
exhibit a 20% red shift in their plasmon resonance as compared to
the individual particles, with a weak dependence on the interparticle
separation. From the analysis, it was found that the in situ absorption
peaks that develop during the assembly can be assigned to specific
dimer structures, which has not been shown previously. Last, the kinetics
of the assembly are analyzed
Scalable Ligand-Mediated Transport Synthesis of Organic–Inorganic Hybrid Perovskite Nanocrystals with Resolved Electronic Structure and Ultrafast Dynamics
Colloidal
perovskite nanocrystals support bright, narrow PL tunable
over the visible spectrum. However, bandgap tuning of these materials
remains limited to laboratory-scale syntheses. In this work, we present
a polar-solvent-free ligand-mediated transport synthesis of high-quality
organic–inorganic perovskite nanocrystals under ambient conditions
with photoluminescence quantum yields up to 97%. Our synthesis employs
a ligand-mediated transport mechanism that circumvents the need for
exquisite external control (<i>e</i>.<i>g</i>.,
temperature control, inert-gas protection, dropwise addition of reagents)
required by other methods due to extremely fast reaction kinetics.
In the ligand-mediated transport mechanism, multiple equilibria cooperatively
dictate reaction rates and enable precise control over NC size. These
small nanocrystals exhibit high photoluminescence quantum yields due
to quantum confinement. Nanosecond transient absorption spectroscopy
experiments reveal a fluence-independent PL decay originating from
exciton recombination. Two-dimensional electronic spectroscopy resolves
multiple spectral features reflecting the electronic structure of
the nanocrystals. The resolved features exhibit size-dependent spectral
positions, further indicating the synthesized nanocrystals are quantum-confined