Thermal stability and grain growth behavior of mechanically alloyed nanocrystalline Fe-Cu alloys

X-ray diffraction, transmission electron microscopy, and differential scanning calorimetry were used to study the thermal stability of highly supersaturated nanocrystalline FexCu100−x alloys (10~80. For 60<=x<=80 fcc and bcc phases coexist. Heating to elevated temperatures leads to structural relaxation, phase separation, and grain growth of the metastable nanocrystalline solid solutions. Single-phase fcc and bcc alloys undergo significant strain release but no appreciable grain growth prior to phase separation. After phase separation pronounced grain growth sets in. In contrast, samples in the two-phase region show some grain growth and significant chemical redistribution even at low temperatures. The phase separation of single-phase fcc and bcc alloys proceeds via different mechanisms: fcc solid solutions decompose by forming small Fe precipitates, while demixing in bcc alloys starts by segregation of Cu atoms to bcc grain boundaries before nucleation of Cu precipitates. These results show that the stability and grain growth behavior of nanocrystalline alloys is strongly affected by the microstructure of the material

The reality of design process planning

Most companies struggle with the efficiency of their processes. One contributory factor is the lack of efficient process planning. This paper describes current planning practise in industry, which uses a multitude of different plans in parallel. The units of planning and their resulting plans roughly fall into product plans considering cost, bill of material and procurement considerations; process plans including different milestone, task and activity plans and quality plans. This paper maps out the ownership of these plans, and establishes that organisations work because individuals use more then one plan and have a tacit understanding of the relationships between these plans. The lack of effective plans affects the company through a lack of understanding of process connectivity and in consequence bad communication

Complexity models in design

Complexity is a widely used term; it has many formal and informal meanings. Several formal models of complexity can be applied to designs and design processes. The aim of the paper is to examine the relation between complexity and design. This argument runs in two ways. First designing provides insights into how to respond to complex systems – how to manage, plan and control them. Second, the overwhelming complexity of many design projects lead us to examine how better understanding of complexity science can lead to improved designs and processes. This is the focus of this paper. We start with an outline of some observations on where complexity arises in design, followed by a brief discussion of the development of scientific and formal conceptions of complexity. We indicate how these can help in understanding design processes and improving designs

Model granularity and related concepts

Models are integral to engineering design and basis for many decisions. Therefore, it is necessary to comprehend how a model’s properties might influence its behaviour. Model granularity is an important property but has so far only received limited attention. The terminology used to describe granularity and related phenomena varies and pertinent concepts are distributed across communities. This article positions granularity in the theoretical background of models, collects formal definitions for relevant terms from a range of communities and discusses the implications for engineering design

Determination of Caries Lesion Activity: Reflection and Roughness for Characterization of Caries Progression

Used by permission. © Operative Dentistry, Inc. Transmission or reproduction of protected items beyond that allowed by fair use requires the written permission of Operative Dentistry, Inc.Caries lesion progression is difficult to determine with visual and tactile examinations. The hypothesis of this study was that reflection and roughness measurements could determine caries progression. Ground/polished sound human enamel specimens were analyzed at baseline (sound) and after two four-day demineralization periods for reflection using optical reflectometry (ORef) and for roughness using optical surface profilometry (SPro). Specimens were demineralized using a microbial–Streptococcus mutans aries model. Comparisons among the periods for ORef and SPro were performed using repeated measures analysis of variance. Two-sample t-tests were used for differences in transverse microradiography. The integrated mineral loss and depth of the four-day demineralization period were significantly smaller than those for the eight-day demineralization period (p<0.01). With increased demineralization time, reflection was significantly decreased and roughness was significantly increased (p<0.01). Correlation between ORef and SPro was moderate (r=−0.63). Both reflection and roughness can be characterized for nondestructive longitudinal assessment of caries lesion progression

Towards a change process planning tool

The relationship between a product and its design process is generally complex and not fully understood. When modifying a product, industry still rarely considers the implementation process and its consequences for other design activities in the company, which is hard to assess with conventional planning methods. Although change processes are highly constrained, product and process constraints are not usually considered together or traded off against each other when planning the change. Inadequate assessment and planning of the change implementation process can lead to costly knock-on effects across the product and the design process. This paper argues for a combination of change and process research and discusses requirements for a change process planning tool. It proposes a system for the analysis of the impact of change on the product as well as other company activities. Then, a more informed selection between change alternatives is possible

Mechanically driven alloying and grain size changes in nanocrystalline Fe-Cu powders

Highly supersaturated nanocrystalline FexCu100-x alloys (10 less-than-or-equal-to x less-than-or-equal-to 95) have been prepared by mechanical alloying of elemental crystalline powders. The development of the microstructure is investigated by x-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The results are compared with data for ball-milled elemental Fe and Cu powders, samples prepared by inert gas condensation, and sputtered films. The deformation during milling reduces the grain size of the alloys to 6-20 nm. The final grain size of the powders depends on the composition of the material. Single-phase fcc alloys with x less-than-or-equal-to 60 and single-phase bcc alloys with x greater-than-or-equal-to 80 are formed even though the Fe-Cu system exhibits vanishingly small solid solubilities under equilibrium conditions. For 60 less-than-or-equal-to x less-than-or-equal-to 80, fcc and bcc solid solutions coexist. The alloy formation is discussed with respect to the thermodynamic conditions of the material. The role of the large volume fraction of grain boundaries between the nanometer-sized crystals, as well as the influence of internal strains and stored enthalpies introduced by ball milling, is critically assessed