40 research outputs found
Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation
Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH4+ production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface
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Magnetotelluric Imaging of the Lithospheric Structure of the Southern Oklahoma Aulacogen: Evidence for LongâTerm Weakening Caused by Rifting
Magnetotelluric data were used to study the lithosphere structure of the Southern Oklahoma Aulacogen (SOA). Inversion of the data revealed two low resistivity anomalies beneath the SOA. The first is located in the depth range 0â90 km in the crust and upper lithospheric mantle. The second extends from a depth 100 km to the base of the lithospheric mantle and extends away from the SOA to the ends of the profile. The cause of low resistivity anomalies is discussed in relation to the tectonic evolution of the region and recent laboratory experiments on rock conductivity. The first anomaly is attributed to the combination of (a) water present in mantle minerals and (b) the formation of hydrous mineral phases by interactions between a plume and the lithosphere during rifting. Grain size reduction and fabric alignment from deformation during the Ancestral Rocky Mountain (ARM) orogeny may have also contributed to the low resistivity. This enrichment phase may have mechanically weakened the lithosphere and allowed deformation to occur during the ARM orogeny. The low resistivity of the deeper anomaly is attributed to a fluorine-enriched phlogopite layer that is also coincident with an observed seismic mid-lithosphere discontinuity (MLD). A lithosphere keel of mantle minerals enriched in water underlies this layer and may have formed by accretion of the plume head to the lower lithosphere after rifting, which also rethickened the lithosphere to its present-day depths. The MLD may then reflect a melt layer along a paleo lithosphere-asthenosphere boundary entombed during the accretion
Fault controlled geometries by inherited tectonic texture at the southern end of the East African Rift System in the Makgadikgadi Basin, northeastern Botswana
One of the three narrow rift belts that mark the southern end of the East African Rift System (EARS) intersects the Makgadikgadi Basin of northeastern Botswana. Although tectonic activity in the region is known to have influenced the evolution of these pans, the interrelationship between shoreline geometry, fault strikes, and the intersection of the underlying tectonic terranes has yet to be fully realized. We analyzed faults and subsurface structures in the region of the pans using a field investigation in combination with satellite imagery and geophysical data, to constrain the influence that the regional tectonic regime has had on the formation of the present-day pan geometry. We find that pan shorelines are controlled by the intersection of three preferred fault orientations which can be understood in the context of the "older" terranes they overlie, namely the Magondi Belt and the Limpopo Belt. We propose that the pronounced curvature of the southern Magondi Belt has influ-enced the eastward curvature of the rift-related faults and was likely produced by the impingement of the developing fold belt on the Zimbabwe Craton. Furthermore, limited focal mechanism solutions data from earthquakes north and south of the pans suggests a change in regional extension direction from NW-SE to NE-SW. Determining the relationship between these fault orientations and the underlying tectonic terrains is an important step in understanding the formation of the Makgadikgadi Basin, and more broadly the current tectonic regime of Botswana. The evidence of fault-controlled shorelines within an evaporitic environment may also have implications for regional groundwater activity