Electrodeposition of Co-Ni-MoxOy Powders: Part I. The Influence of Deposition Conditions on Powder Composition and Morphology

The Co-Ni-MoxOy powders were obtained electrochemically at a constant current density from ammonia electrolyte. Ni and Co were anomalously deposited, inducing Mo deposition, which cannot be deposited separately from aqueous solutions. The obtained Co-Ni-MoxOy powders were investigated by energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and scanning electon microscope (SEM) methods. Based on the obtained experimental results, it was concluded that the particle size of deposited powders is influenced by the chemical composition of the electrolyte and current density imposed. XRD results suggested that obtained powders were of amorphous structure, although a Co3Mo compound can be formed if certain experimental conditions are applied

Electrodeposited Co-Cu/Cu multilayered microposts

X-ray lithography and electrodeposition were combined to deposit an array of Co-Cu/Cu multilayer microposts of 500 μm tall into deep recesses for novel giant magnetoresistance (GMR) architectures. A citrate-boric acid electrolyte was used with pulsed potential. The applied potential was determined through inspection of the polarization curve from linear sweep voltammetry, and scanning electron microscopy (SEM)/transmission electron microscope (TEM) confirmed the micropost layered structure. Room temperature magnetoresistance was reported for different bilayer sizes of the micropost, and up to 4% current perpendicular-to-plane giant magnetoresistance (CPP-GMR) with saturation values less than 1 T was observed. © 2008 Elsevier B.V. All rights reserved

A hybrid approach to fabricated nanowire-nanoparticle composites of a Co-W alloy and Au nanoparticles

Co-W nanowires were fabricated by pulsed electrodeposition from a citrate-glycine electrolyte onto rotating cylinder electrodes and into nanoporous polycarbonate membranes. The characterization of the electrodeposition conditions and alloy composition of electrodeposited Co-W alloy thin films were determined and used to guide conditions to electrodeposit the nanowires. Gold nanoparticles of 50 nm size were also added to the electrolyte and deposited during electrodeposition of the Co-W alloy nanowires, embedded within, and attached to the nanowire tip, introducing a novel procedure to attached nanoparticles onto nanowires