11 research outputs found
Elastic constants of nematic liquid crystals of uniaxial symmetry
We study in detail the influence of molecular interactions on the Frank
elastic constants of uniaxial nematic liquid crystals composed of molecules of
cylindrical symmetry. A brief summary of the status of theoretical development
for the elastic constants of nematics is presented. Considering a pair
potential having both repulsive and attractive parts numerical calculations are
reported for three systems MBBA, PAA and 8OCB. For these systems the
length-to-width ratio is estimated from the experimentally proposed
structure of the molecules. The repulsive interaction is represented by a
repulsion between hard ellipsoids of revolution (HER) and the attractive
potential is represented by the quadrupole and dispersion interactions. From
the numerical results we observe that in the density range of nematics the
contribution of the quadrupole and dispersion interactions are small as
compared to the repulsive HER interaction. The inclusion of attractive
interaction reduces the values of elastic constants ratios. The temperature
variation of elastic constants ratios are reported and compared with the
experimental values. A reasonably good agreement between theory and experiment
is observed
Theory of bivacancy contribution to the coefficient of self-diffusion in monatomic molecular crystals
Statistical determination of the coefficient of self-diffusion in a monatomic molecular crystal
A statistical-mechanical model for calculating equilibrium properties of a nematic liquid crystal
We have proposed an optimized statistical-mechanical model of a nematic liquid crystal using the method of conditional distributions due to Rott. The calculations have been carried out for hexagonal and cubic close packings with the nearest neighbour Gay-Berne intermolecular potential. The theory takes pair intermolecular correlations into account. The hexagonal close packing proves to be favourable as compared to the cubic one. Optimized values of the cell model parameter have been calculated providing the minimum Helmholtz free energy of a liquid crystal