A new comparison between solid-state thermionics and thermoelectrics

It is shown that equations for electrical current in solid-state thermionic and thermoelectric devices converge for devices with a width equal to the mean free path of electrons, yielding a common expression for intensive electronic efficiency in the two types of devices. This result is used to demonstrate that the materials parameters for thermionic and thermoelectric devices are equal, rather than differing by a multiplicative factor as previously thought

Dual Band Electrodes in Generator-Collector Mode: Simultaneous Measurement of Two Species

A computational model for the simulation of a double band collector-generator experiment is applied to the situation where two electrochemical reactions occur concurrently. It is shown that chronoamperometric measurements can be used to take advantage of differences in diffusion coefficients to measure the concentrations of both electroactive species simultaneously, by measuring the time at which the collection efficiency reaches a specific value. The separation of the electrodes is shown to not affect the sensitivity of the method (in terms of percentage changes in the measured time to reach the specified collection efficiency), but wider gaps can provide a greater range of (larger) absolute values of this characteristic time. It is also shown that measuring the time taken to reach smaller collection efficiencies can allow for the detection of smaller amounts of whichever species diffuses faster. The case of a system containing both ascorbic acid and opamine in water is used to exemplify the method, and it is shown that mole fractions of ascorbic acid between 0.055 and 0.96 can, in principle, be accurately measured.Comment: 34 pages, 8 figure

Long-range behavior of the optical potential for the elastic scattering of charged composite particles

The asymptotic behavior of the optical potential, describing elastic scattering of a charged particle $\alpha$ off a bound state of two charged, or one charged and one neutral, particles at small momentum transfer $\Delta_{\alpha}$ or equivalently at large intercluster distance $\rho_{\alpha}$, is investigated within the framework of the exact three-body theory. For the three-charged-particle Green function that occurs in the exact expression for the optical potential, a recently derived expression, which is appropriate for the asymptotic region under consideration, is used. We find that for arbitrary values of the energy parameter the non-static part of the optical potential behaves for $\Delta_{\alpha} \rightarrow 0$ as $C_{1}\Delta_{\alpha} + o\,(\Delta_{\alpha})$. From this we derive for the Fourier transform of its on-shell restriction for $\rho_{\alpha} \rightarrow \infty$ the behavior $-a/2\rho_{\alpha}^4 + o\,(1/\rho_{\alpha}^4)$, i.e., dipole or quadrupole terms do not occur in the coordinate-space asymptotics. This result corroborates the standard one, which is obtained by perturbative methods. The general, energy-dependent expression for the dynamic polarisability $C_{1}$ is derived; on the energy shell it reduces to the conventional polarisability $a$ which is independent of the energy. We emphasize that the present derivation is {\em non-perturbative}, i.e., it does not make use of adiabatic or similar approximations, and is valid for energies {\em below as well as above the three-body dissociation threshold}.Comment: 35 pages, no figures, revte

FRW Universe Models in Conformally Flat Spacetime Coordinates. II: Universe models with negative and vanishing spatial curvature

We deduce general expressions for the line element of universe models with negative and vanishing spatial curvature described by conformally flat spacetime coordinates. The empty Milne universe model and models with dust, radiation and vacuum energy are exhibited. Discussing the existence of particle horizons we show that there is continual creation of space, matter and energy when conformal time is used in Friedmann-Robertson-Walker models with negative spatial curvature.Comment: 25 pages, 12 figure

Proof of Bose-Einstein Condensation for Interacting Gases with a One-Particle Spectral Gap

Using a specially tuned mean-field Bose gas as a reference system, we establish a positive lower bound on the condensate density for continuous Bose systems with superstable two-body interactions and a finite gap in the one-particle excitations spectrum, i.e. we prove for the first time standard homogeneous Bose-Einstein condensation for such interacting systems

Delivery of nucleating materials to cloud systems from individual ground generators

CER69-70LOG-JEC-MMO24.February 1968.Includes bibliographical references (pages 40-42).Presented to the Bureau of Reclamation Third Skywater Conference on the Production and Delivery of Cloud Nucleating Materials February 14-16, 1968.Delivery of nucleating materials to cloud systems from individual ground generators can play an important role in the beneficial modification of orographic cloud systems. Substantial evidence from the Colorado State University mountain study at Climax is presented to show that ground-released seeding materials do under some weather situations in fact enter the mountain cloud systems and produce changes in the precipitation. Evidence is also presented to show that under other weather situations seeding materials are not carried to the proper clouds at a place and time to be of value. A discussion of atmospheric transport mechanisms is presented to serve as a basis for understanding the motions of seeding materials once released from a ground source. The approaches, or directions, for further research are discussed. This includes consideration of the coagulation problem in the vicinity of the generator site. The use of wind tunnel modeling, which can provide basic information and specific results for specific areas, is emphasized

Research and development technique for estimating airflow and diffusion parameters in connection with the Atmospheric Water Resources Program : final report

CER69-70JEC-LOG-MMO-11.August 1969.Includes bibliographical references (pages 47-48).Period March 15, 1968 to June 30, 1969 Atmospheric Water Resources Research Bureau of Reclamation Contract No. 14-06-D-6455.A stably stratified atmospheric boundary layer was simulated in a wind tunnel and utilized to determine radioactive krypton dispersion patterns over a 1:9600 scale model of the Eagle River Valley and topography surrounding Climax, Colorado. Geometric, dynamic, and thermal similarity are considered, primarily, for barostromatic airflow. Similarity criteria for transport and dispersion are considered also. This is the first time that a barostromatic airflow produced by cooling with dry ice has been documented by temperature and velocity profile measurements. Field Gata indicate that airflow and temperature characteristics over the model are approximately similar to a prototype storm. Dispersion measurements were taken by using sources representative of field ground sources. Model and field measurements confirm that seeding nuclei are reaching the target area from the present existing ground sources. Limited field measurements of ice nuclei concentrations at Chalk Mountain show a variation of 5 to 300 part./liter or XU/Q ~ 1 x 10 -9m-2 to 68 x 10-9m-2. Concentration values deduced from radioactive gas measurements over the model show values within the same range but closer to the optimum values indicated by present cloud physics models, i.e., XU/Q ~ 15 to 18 x 10-9m-2. The barostromatic airflow model indicated that topography plays an important role in determining the downwind direction of the particulate plume.Under contract no. 14-06-D-6455

Research and development technique for estimating airflow and diffusion parameters in connection with the Atmospheric Water Resources Program: interim report

CER70-71MMO78.Period September 2, 1970 to February 28, 1971.Includes bibliographical references (pages 38-39).Atmospheric Water Resources Research, Bureau of Reclamation, Contract No. 14-06-0-6842.This report presents a summary of the research and tentative findings on the use of scaled topographic models and laboratory techniques to study the transport and dispersion of cloud seeding material over mountainous terrain. Three mountainous areas along the continental divide have been selected by the Bureau of Reclamation for such studies. Each area has cloud seeding programs in progress