322 research outputs found
Evolution of magneto-orbital order upon B-site electron doping in Na1-xCaxMn7O12 quadruple perovskite manganites
We present the discovery and refinement by neutron powder diffraction of a
new magnetic phase in the Na1-xCaxMn7O12 quadruple perovskite phase diagram,
which is the incommensurate analogue of the well-known pseudo-CE phase of the
simple perovskite manganites. We demonstrate that incommensurate magnetic order
arises in quadruple perovskites due to the exchange interactions between A and
B sites. Furthermore, by constructing a simple mean field Heisenberg exchange
model that generically describes both simple and quadruple perovskite systems,
we show that this new magnetic phase unifies a picture of the interplay between
charge, magnetic and orbital ordering across a wide range of compounds.Comment: Accepted for publication in Physical Review Letter
Optical study of the vibrational and dielectric properties of BiMnO3
BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also
ferroelectric (FE) due to a non-centro-symmetric C2 structure, until
diffraction data indicated that its space group is the centro-symmetric C2/c.
Here we present infrared phonon spectra of BMO, taken on a mosaic of single
crystals, which are consistent with C2/c at any T > 10 K, as well as
room-temperature Raman data which strongly support this conclusion. We also
find that the infrared intensity of several phonons increases steadily for
decreasing T, causing the relative permittivity of BMO to vary from 18.5 at 300
K to 45 at 10 K. At variance with FE materials of displacive type, no
appreciable softening has been found in the infrared phonons. Both their
frequencies and intensities, moreover, appear insensitive to the FM transition
at Tc
Thermoelectric behavior of Ruddlesden-Popper series iridates
The goal of this work is studying the evolution of thermoelectric transport
across the members of the Ruddlesden-Popper series iridates Srn+1IrnO3n+1,
where a metal-insulator transition driven by bandwidth change occurs, from the
strongly insulating Sr2IrO4 to the metallic non Fermi liquid behavior of
SrIrO3. Sr2IrO4 (n=1), Sr3Ir2O7 (n=2) and SrIrO3 (n=inf.) polycrystals are
synthesized at high pressure and characterized by structural, magnetic,
electric and thermoelectric transport analyses. We find a complex
thermoelectric phenomenology in the three compounds. Thermal diffusion of
charge carriers accounts for the Seebeck behavior of Sr2IrO4, whereas
additional drag mechanisms come into play in determining the Seebeck
temperature dependence of Sr3Ir2O7 and SrIrO3. These findings reveal close
relationship between magnetic, electronic and thermoelectric properties, strong
coupling of charge carriers with phonons and spin fluctuations as well as
relevance of multiband description in these compounds.Comment: main paper + supplementary informatio
Synthesis and characterization of multiferroic BiMnO
We report on the high pressure synthesis of BiMnO, a manganite
displaying a "quadruple perovskite" structure. Structural characterization of
single crystal samples shows a distorted and asymmetrical coordination around
the Bi atom, due to presence of the lone pair, resulting in
non-centrosymmetric space group Im, leading to a permanent electrical dipole
moment and ferroelectric properties. On the other hand, magnetic
characterization reveals antiferromagnetic transitions, in agreement with the
isostructural compounds, thus evidencing two intrinsic properties that make
BiMnO a promising multiferroic material.Comment: 4 pages, 3 figure
Internal-strain mediated coupling between polar Bi and magnetic Mn ions in the defect-free quadruple-perovskite BiMnMnO
By means of neutron powder diffraction, we investigated the effect of the
polar Bi ion on the magnetic ordering of the Mn ions in
BiMnMnO, the counterpart with \textit{quadruple} perovskite
structure of the \textit{simple} perovskite BiMnO. The data are consistent
with a \textit{noncentrosymmetric} spacegroup which contrasts the
\textit{centrosymmetric} one previously reported for the isovalent and
isomorphic compound LaMnMnO, which gives evidence of a
Bi-induced polarization of the lattice. At low temperature, the two
Mn sublattices of the and sites order antiferromagnetically
(AFM) in an independent manner at 25 and 55 K, similarly to the case of
LaMnMnO. However, both magnetic structures of
BiMnMnO radically differ from those of LaMnMnO.
In BiMnMnO the moments of the sites form
an anti-body AFM structure, whilst the moments \textbf{M} of the
sites result from a large and \textit{uniform} modulation along the b-axis of the moments \textbf{M} in the
-plane. The modulation is strikingly correlated with the displacements of
the Mn ions induced by the Bi ions. Our analysis unveils a strong
magnetoelastic coupling between the internal strain created by the Bi
ions and the moment of the Mn ions in the sites. This is ascribed to
the high symmetry of the oxygen sites and to the absence of oxygen defects, two
characteristics of quadruple perovskites not found in simple ones, which
prevent the release of the Bi-induced strain through distortions or
disorder. This demonstrates the possibility of a large magnetoelectric coupling
in proper ferroelectrics and suggests a novel concept of internal strain
engineering for multiferroics design.Comment: 9 pages, 7 figures, 5 table
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