216 research outputs found
Surface relief of magnetoactive elastomeric films in a homogeneous magnetic field: Molecular dynamics simulations
The structure of a thin magnetoactive elastomeric (MAE) film adsorbed on a solid substrate is studied by molecular dynamics simulations. Within the adopted coarse-grained approach, a MAE film consists of magnetic particles modeled as soft-core spheres, carrying point dipoles, connected by elastic springs representing a polymer matrix. MAE films containing 20, 25 and 30 vol% of randomly distributed magnetic particles are simulated. Once a magnetic field is applied, the competition between dipolar, elastic and Zeeman forces leads to the restructuring of the layer. The distribution of the magnetic particles as well as elastic strains within the MAE films are calculated for various magnetic fields applied perpendicular to the film surface. It is shown that the surface roughness increases strongly with growing magnetic field. For a given magnetic field, the roughness is larger for the softer polymeric matrix and exhibits a nonmonotonic dependence on the magnetic particle concentration. The obtained results provide a better understanding of the MAE surface structuring as well as possible guidelines for fabrication of MAE films with a tunable surface topology. Β© The Royal Society of Chemistry 2019.Financial support of the Russian Foundation for Basic Research is gratefully acknowledged (grant no. 16-29-05276). The authors acknowledge support from the Ministry of Education and Science of the Russian Federation, Contract 02.A03.21.0006 (Project 3.1438.2017/4.6). P. A. S. and S. S. K. are also supported by the FWF START-Projekt Y 627-N27. S. S. K. also acknowledges support from ETN-COLLDENSE (H2020-MSCA-ITN-2014, Grant No. 642774). Computer simulations were carried out at the Vienna Scientific Cluster
Longitudinal Momentum Fraction X_L for Two High P_t Protons in pp->ppX Reaction
We present an analysis of new data from Experiment E850 at BNL. We have
characterized the inclusive cross section near the endpoint for pp exclusive
scattering in Hydrogen and in Carbon with incident beam energy of 6 GeV. We
select events with a pair of back-to-back hadrons at large transverse momentum.
These cross sections are parameterized with a form
, where is the ratio of the longitudinal momentum
of the observed pair to the total incident beam momentum. Small value of
may suggest that the number of partons participating in the reaction is large
and reaction has a strong dependence on the center-of-mass energy. We also
discuss nuclear effects observed in our kinematic region.Comment: 4 pages, 2 figures, to be published in Proceedings of CIPANP2000,
Quebec, May 22-28, 2000, requires aipproc.sty(included
Suppression of hole-hole scattering in GaAs/AlGaAs heterostructures under uniaxial compression
Resistance, magnetoresistance and their temperature dependencies have been
investigated in the 2D hole gas at a [001] p-GaAs/AlGaAs
heterointerface under [110] uniaxial compression. Analysis performed in the
frame of hole-hole scattering between carriers in the two spin splitted
subbands of the ground heavy hole state indicates, that h-h scattering is
strongly suppressed by uniaxial compression. The decay time of the
relative momentum reveals 4.5 times increase at a uniaxial compression of 1.3
kbar.Comment: 5 pages, 3 figures. submitted to Phys.Rev.
The Caspase-Related Protease Separase (EXTRA SPINDLE POLES) Regulates Cell Polarity and Cytokinesis in Arabidopsis
ΠΠ΅ΠΆΠ΄ΡΠ½Π°ΡΠΎΠ΄Π½ΡΠΉ ΠΈΠ½Π΄Π΅ΠΊΡ ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π° (I-DESI): ΡΠ΅Π½Π΄Π΅Π½ΡΠΈΠΈ ΡΠ°Π·Π²ΠΈΡΠΈΡ ΡΠΈΡΡΠΎΠ²ΡΡ ΡΠ΅Ρ Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ
Purpose of research. The aim of the study is to conduct statistical research and assess the level of digitalization of the economy of the European Union and some non-EU countries. The focus is on assessing the level, dynamics and directions of information and communication technologies development in the European economy on the example of the international index of digital economy and society (I-DESI). The strongest and weakest countries were identified, and the impact of components (sub-indexes) of the I-DESI index on GDP was studied.Materials and methods. For this study, the digital economy and society index (DESI β Digital Economy and Society Index), which is a composite measure that studies the digital indicators of Europe, developed by DG CONNECT (the European Commission) to provide an evidence-based contribution to the assessment of digital development in the EU as a whole, is considered as an assessment of the level of digitalization. Based on this index, the international digital economy and society index (I-DESI) was developed in 2018, which reflects and expands the EU-28 digital economy and society index. Based on the sub-indexes of this index, a multidimensional classification of European countries was carried out. The main components method identifies the main factors that were used to identify their impact on the level of GDP in various clusters. The Statistica package is used for information processing and analysis.Results. This study examined the values of sub-indexes of the I-DESI index in five dimensions: communication, digital skills, citizens' use of the Internet, integration of business technologies, and digital public services. According to the hierarchical classification based on these sub-indexes, 2 groups of countries were identified. Using the k-means method, the features of each cluster are identified. Comparisons of cluster analysis results by sub-indexes were made based on data from 2016 and 2013. Using the main components method, five main factors were identified out of twenty indicators characterizing the I-DESI index and their influence on the level of GDP in various clusters was revealed. The analysis of twenty indicators of the I-DESI 2018 index, applied in the method of main components, by the directions of the index itself, the economy in the context of GDP and the social sphere (life of society) through the HDI (human development index) in various clusters was also carried out.Conclusion. According to the research, two groups of countries were identified by the level of digitalization. The first group in 2016 included twenty two countries with high indicators of digital development of the economy and society. All the countries of the first cluster are developed countries that have a significant share of services in their economy, as well as investments in high-tech products. The second cluster is represented by twenty three countries. This cluster is mainly represented by developing countries, which still have a large share of production in GDP. The level of GDP in the first cluster countries with a high I-DESI index was mainly influenced by factors that characterize fixed broadband and digital public services. Two groups of factors also influenced the GDP level of the second cluster countries. One group of factors combined variables that characterize new technologies in business, the other group β the use of the Internet by the population. The study of the development of the digital economy has allowed us to conclude that in general, the trend of rapid spread of modern technologies is developing around the world. This suggests that society in the context of the state and the individual needs to be mobile and ready to adopt new technologies in advance.Π¦Π΅Π»Ρ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ. Π¦Π΅Π»ΡΡ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΡΠ²Π»ΡΠ΅ΡΡΡ ΡΡΠ°ΡΠΈΡΡΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΈ ΠΎΡΠ΅Π½ΠΊΠ° ΡΡΠΎΠ²Π½Ρ ΡΠΈΡΡΠΎΠ²ΠΈΡΠ°ΡΠΈΠΈ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΠ²ΡΠΎΡΠΎΡΠ·Π° ΠΈ Π½Π΅ΠΊΠΎΡΠΎΡΡΡ
ΡΡΡΠ°Π½ Π½Π΅ Π²Ρ
ΠΎΠ΄ΡΡΠΈΡ
ΠΠ‘. ΠΠΊΡΠ΅Π½Ρ ΡΠ΄Π΅Π»Π°Π½ Π½Π° ΠΎΡΠ΅Π½ΠΊΡ ΡΡΠΎΠ²Π½Ρ, Π΄ΠΈΠ½Π°ΠΌΠΈΠΊΠΈ ΠΈ Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½ΠΈΠΉ ΠΎΡΠ²ΠΎΠ΅Π½ΠΈΡ ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΎΠ½Π½ΠΎ-ΠΊΠΎΠΌΠΌΡΠ½ΠΈΠΊΠ°ΡΠΈΠΎΠ½Π½ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ Π² ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠ΅ Π΅Π²ΡΠΎΠΏΠ΅ΠΉΡΠΊΠΈΡ
ΡΡΡΠ°Π½ Π½Π° ΠΏΡΠΈΠΌΠ΅ΡΠ΅ ΠΌΠ΅ΠΆΠ΄ΡΠ½Π°ΡΠΎΠ΄Π½ΠΎΠ³ΠΎ ΠΈΠ½Π΄Π΅ΠΊΡΠ° ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π° I-DESI. ΠΡΠ΄Π΅Π»Π΅Π½Ρ Π½Π°ΠΈΠ±ΠΎΠ»Π΅Π΅ ΡΠΈΠ»ΡΠ½ΡΠ΅ ΠΈ ΡΠ»Π°Π±ΡΠ΅ ΡΡΡΠ°Π½Ρ, ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ Π²Π»ΠΈΡΠ½ΠΈΠ΅ ΡΠΎΡΡΠ°Π²Π»ΡΡΡΠΈΡ
(ΡΡΠ±ΠΈΠ½Π΄Π΅ΠΊΡΠΎΠ²) ΠΈΠ½Π΄Π΅ΠΊΡΠ° I-DESI Π½Π° ΠΠΠ.ΠΠ°ΡΠ΅ΡΠΈΠ°Π»Ρ ΠΈ ΠΌΠ΅ΡΠΎΠ΄Ρ. ΠΠ»Ρ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ΠΈΡ Π΄Π°Π½Π½ΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ ΠΎΡΠ΅Π½ΠΊΠ΅ ΡΡΠΎΠ²Π½Ρ ΡΠΈΡΡΠΎΠ²ΠΈΠ·Π°ΡΠΈΠΈ ΡΠ°ΡΡΠΌΠΎΡΡΠ΅Π½ ΠΈΠ½Π΄Π΅ΠΊΡ ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π° (DESI β Digital Economy and Society Index), ΡΠ²Π»ΡΡΡΠΈΠΉΡΡ ΡΠΎΡΡΠ°Π²Π½ΠΎΠΉ ΠΌΠ΅ΡΠΎΠΉ, ΠΊΠΎΡΠΎΡΠ°Ρ ΠΈΠ·ΡΡΠ°Π΅Ρ ΡΠΈΡΡΠΎΠ²ΡΠ΅ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»ΠΈ ΠΠ²ΡΠΎΠΏΡ, ΡΠ°Π·ΡΠ°Π±ΠΎΡΠ°Π½Π½ΡΠΉ DG CONNECT (ΠΠ²ΡΠΎΠΏΠ΅ΠΉΡΠΊΠΎΠΉ ΠΊΠΎΠΌΠΈΡΡΠΈΠ΅ΠΉ) Π΄Π»Ρ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠ΅Π½ΠΈΡ Π½Π°ΡΡΠ½ΠΎ ΠΎΠ±ΠΎΡΠ½ΠΎΠ²Π°Π½Π½ΠΎΠ³ΠΎ Π²ΠΊΠ»Π°Π΄Π° Π² ΠΎΡΠ΅Π½ΠΊΡ ΡΠΈΡΡΠΎΠ²ΠΎΠ³ΠΎ ΡΠ°Π·Π²ΠΈΡΠΈΡ Π² ΠΠ‘ Π² ΡΠ΅Π»ΠΎΠΌ. ΠΠ° ΠΎΡΠ½ΠΎΠ²Π΅ Π΄Π°Π½Π½ΠΎΠ³ΠΎ ΠΈΠ½Π΄Π΅ΠΊΡΠ° Π² 2018 Π³ΠΎΠ΄Ρ Π±ΡΠ» ΡΠ°Π·ΡΠ°Π±ΠΎΡΠ°Π½ ΠΠ΅ΠΆΠ΄ΡΠ½Π°ΡΠΎΠ΄Π½ΡΠΉ ΠΈΠ½Π΄Π΅ΠΊΡ ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π° (I-DESI), ΠΊΠΎΡΠΎΡΡΠΉ ΠΎΡΡΠ°ΠΆΠ°Π΅Ρ ΠΈ ΡΠ°ΡΡΠΈΡΡΠ΅Ρ ΠΠ½Π΄Π΅ΠΊΡ ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π° ΠΠ‘-28. ΠΠ° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΡΠ±ΠΈΠ½Π΄Π΅ΠΊΡΠΎΠ² Π΄Π°Π½Π½ΠΎΠ³ΠΎ ΠΈΠ½Π΄Π΅ΠΊΡΠ° Π±ΡΠ»Π° ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½Π° ΠΌΠ½ΠΎΠ³ΠΎΠΌΠ΅ΡΠ½Π°Ρ ΠΊΠ»Π°ΡΡΠΈΡΠΈΠΊΠ°ΡΠΈΡ ΡΡΡΠ°Π½ ΠΠ²ΡΠΎΠΏΡ. ΠΠ΅ΡΠΎΠ΄ΠΎΠΌ Π³Π»Π°Π²Π½ΡΡ
ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ Π²ΡΠ΄Π΅Π»Π΅Π½Ρ ΠΎΡΠ½ΠΎΠ²Π½ΡΠ΅ ΡΠ°ΠΊΡΠΎΡΡ, ΠΊΠΎΡΠΎΡΡΠ΅ Π±ΡΠ»ΠΈ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½Ρ Π΄Π»Ρ Π²ΡΡΠ²Π»Π΅Π½ΠΈΡ ΠΈΡ
Π²Π»ΠΈΡΠ½ΠΈΡ Π½Π° ΡΡΠΎΠ²Π΅Π½Ρ ΠΠΠ Π² ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
ΠΊΠ»Π°ΡΡΠ΅ΡΠ°Ρ
. ΠΠ»Ρ ΠΎΠ±ΡΠ°Π±ΠΎΡΠΊΠΈ ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΠΈ ΠΈ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ΠΈΡ Π°Π½Π°Π»ΠΈΠ·Π° ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ ΠΠΠ Statistica.Π Π΅Π·ΡΠ»ΡΡΠ°ΡΡ. Π ΡΠ°ΠΌΠΊΠ°Ρ
Π΄Π°Π½Π½ΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π±ΡΠ»ΠΈ ΡΠ°ΡΡΠΌΠΎΡΡΠ΅Π½Ρ Π·Π½Π°ΡΠ΅Π½ΠΈΡ ΡΡΠ±ΠΈΠ½Π΄Π΅ΠΊΡΠΎΠ² ΠΈΠ½Π΄Π΅ΠΊΡΠ° I-DESI ΠΏΠΎ ΠΏΡΡΠΈ ΠΈΠ·ΠΌΠ΅ΡΠ΅Π½ΠΈΡΠΌ: ΡΠ²ΡΠ·Ρ, ΡΠΈΡΡΠΎΠ²ΡΠ΅ Π½Π°Π²ΡΠΊΠΈ, ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π³ΡΠ°ΠΆΠ΄Π°Π½Π°ΠΌΠΈ ΠΠ½ΡΠ΅ΡΠ½Π΅ΡΠ°, ΠΈΠ½ΡΠ΅Π³ΡΠ°ΡΠΈΡ Π±ΠΈΠ·Π½Π΅Ρ-ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ, ΡΠΈΡΡΠΎΠ²ΡΠ΅ Π³ΠΎΡΡΠ΄Π°ΡΡΡΠ²Π΅Π½Π½ΡΠ΅ ΡΡΠ»ΡΠ³ΠΈ. Π‘ΠΎΠ³Π»Π°ΡΠ½ΠΎ ΠΈΠ΅ΡΠ°ΡΡ
ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΊΠ»Π°ΡΡΠΈΡΠΈΠΊΠ°ΡΠΈΠΈ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ Π΄Π°Π½Π½ΡΡ
ΡΡΠ±ΠΈΠ½Π΄Π΅ΠΊΡΠΎΠ² Π±ΡΠ»ΠΎ Π²ΡΠ΄Π΅Π»Π΅Π½ΠΎ 2 Π³ΡΡΠΏΠΏΡ ΡΡΡΠ°Π½. Π‘ ΠΏΠΎΠΌΠΎΡΡΡ ΠΌΠ΅ΡΠΎΠ΄Π° k-ΡΡΠ΅Π΄Π½ΠΈΡ
Π²ΡΡΠ²Π»Π΅Π½Ρ ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠΈ ΠΊΠ°ΠΆΠ΄ΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡΠ΅ΡΠ°. Π‘ΡΠ°Π²Π½Π΅Π½ΠΈΡ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠΎΠ² ΠΊΠ»Π°ΡΡΠ΅ΡΠ½ΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° ΠΏΠΎ ΡΡΠ±ΠΈΠ½Π΄Π΅ΠΊΡΠ°ΠΌ Π±ΡΠ»ΠΈ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½Ρ ΠΏΠΎ Π΄Π°Π½Π½ΡΠΌ 2016 Π³. ΠΈ 2013 Π³. ΠΠ΅ΡΠΎΠ΄ΠΎΠΌ Π³Π»Π°Π²Π½ΡΡ
ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ ΠΈΠ· Π΄Π²Π°Π΄ΡΠ°ΡΠΈ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Π΅ΠΉ, Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΠ·ΡΡΡΠΈΡ
ΠΈΠ½Π΄Π΅ΠΊΡ I-DESI, Π±ΡΠ»ΠΈ Π²ΡΠ΄Π΅Π»Π΅Π½Ρ ΠΏΡΡΡ ΠΎΡΠ½ΠΎΠ²Π½ΡΡ
ΡΠ°ΠΊΡΠΎΡΠΎΠ² ΠΈ Π²ΡΡΠ²Π»Π΅Π½ΠΎ ΠΈΡ
Π²Π»ΠΈΡΠ½ΠΈΠ΅ Π½Π° ΡΡΠΎΠ²Π΅Π½Ρ ΠΠΠ Π² ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
ΠΊΠ»Π°ΡΡΠ΅ΡΠ°Ρ
. Π’Π°ΠΊΠΆΠ΅ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ Π°Π½Π°Π»ΠΈΠ· 20 ΠΈΠ½Π΄ΠΈΠΊΠ°ΡΠΎΡΠΎΠ² ΠΈΠ½Π΄Π΅ΠΊΡΠ° I-DESI 2018, ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½Π½ΡΡ
Π² ΠΌΠ΅ΡΠΎΠ΄Π΅ Π³Π»Π°Π²Π½ΡΡ
ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ, ΠΏΠΎ Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½ΠΈΡΠΌ ΡΠ°ΠΌΠΎΠ³ΠΎ ΠΈΠ½Π΄Π΅ΠΊΡΠ°, ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ Π² ΡΠ°Π·ΡΠ΅Π·Π΅ ΠΠΠ ΠΈ ΡΠΎΡΠΈΠ°Π»ΡΠ½ΠΎΠΉ ΡΡΠ΅ΡΡ (ΠΆΠΈΠ·Π½ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π°) ΡΠ΅ΡΠ΅Π· ΠΠ Π§Π (ΠΈΠ½Π΄Π΅ΠΊΡ ΡΠ°Π·Π²ΠΈΡΠΈΡ ΡΠ΅Π»ΠΎΠ²Π΅ΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΏΠΎΡΠ΅Π½ΡΠΈΠ°Π»Π°) Π² ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
ΠΊΠ»Π°ΡΡΠ΅ΡΠ°Ρ
.ΠΠ°ΠΊΠ»ΡΡΠ΅Π½ΠΈΠ΅. ΠΠΎ Π΄Π°Π½Π½ΡΠΌ ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½Π½ΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ Π±ΡΠ»ΠΈ Π²ΡΡΠ²Π»Π΅Π½Ρ Π΄Π²Π΅ Π³ΡΡΠΏΠΏΡ ΡΡΡΠ°Π½ ΠΏΠΎ ΡΡΠΎΠ²Π½Ρ ΡΠΈΡΡΠΎΠ²ΠΈΠ·Π°ΡΠΈΠΈ. Π ΠΏΠ΅ΡΠ²ΡΡ Π³ΡΡΠΏΠΏΡ Π² 2016 Π³ΠΎΠ΄Ρ Π²ΠΎΡΠ»ΠΎ 22 ΡΡΡΠ°Π½Ρ Ρ Π²ΡΡΠΎΠΊΠΈΠΌΠΈ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»ΡΠΌΠΈ ΡΠΈΡΡΠΎΠ²ΠΎΠ³ΠΎ ΡΠ°Π·Π²ΠΈΡΠΈΡ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ ΠΈ ΠΎΠ±ΡΠ΅ΡΡΠ²Π°. ΠΡΠ΅ ΡΡΡΠ°Π½Ρ ΠΏΠ΅ΡΠ²ΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡΠ΅ΡΠ° β ΡΠ°Π·Π²ΠΈΡΡΠ΅ ΡΡΡΠ°Π½Ρ, ΠΈΠΌΠ΅ΡΡΠΈΠ΅ Π² ΡΠ²ΠΎΠ΅ΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠ΅ Π²Π΅ΡΠΎΠΌΡΡ Π΄ΠΎΠ»Ρ ΡΡΠ»ΡΠ³, Π° ΡΠ°ΠΊΠΆΠ΅ ΠΈΠ½Π²Π΅ΡΡΠΈΡΠΈΠΉ Π² Π²ΡΡΠΎΠΊΠΎΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ½ΡΠ΅ ΠΏΡΠΎΠ΄ΡΠΊΡΡ. ΠΡΠΎΡΠΎΠΉ ΠΊΠ»Π°ΡΡΠ΅Ρ ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»Π΅Π½ 23 ΡΡΡΠ°Π½Π°ΠΌΠΈ. ΠΠ°Π½Π½ΡΠΉ ΠΊΠ»Π°ΡΡΠ΅Ρ Π² ΠΎΡΠ½ΠΎΠ²Π½ΠΎΠΌ ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»Π΅Π½ ΡΠ°Π·Π²ΠΈΠ²Π°ΡΡΠΈΠΌΠΈΡΡ ΡΡΡΠ°Π½Π°ΠΌΠΈ, ΠΈΠΌΠ΅ΡΡΠΈΠΌΠΈ Π² ΠΠΠ ΠΏΠΎ-ΠΏΡΠ΅ΠΆΠ½Π΅ΠΌΡ Π±ΠΎΠ»ΡΡΡΡ Π΄ΠΎΠ»Ρ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Π°. ΠΠ° ΡΡΠΎΠ²Π΅Π½Ρ ΠΠΠ Π² ΡΡΡΠ°Π½Π°Ρ
ΠΏΠ΅ΡΠ²ΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡΠ΅ΡΠ°, Ρ Π²ΡΡΠΎΠΊΠΈΠΌ ΠΈΠ½Π΄Π΅ΠΊΡΠΎΠΌ I-DESI, ΠΎΡΠ½ΠΎΠ²Π½ΠΎΠ΅ Π²Π»ΠΈΡΠ½ΠΈΠ΅ ΠΎΠΊΠ°Π·ΡΠ²Π°Π»ΠΈ ΡΠ°ΠΊΡΠΎΡΡ, Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΠ·ΡΡΡΠΈΠ΅ ΡΠΈΠΊΡΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΡΠΈΡΠΎΠΊΠΎΠΏΠΎΠ»ΠΎΡΠ½ΡΡ ΡΠ²ΡΠ·Ρ ΠΈ ΡΠΈΡΡΠΎΠ²ΡΠ΅ Π³ΠΎΡΡΠ΄Π°ΡΡΡΠ²Π΅Π½Π½ΡΠ΅ ΡΡΠ»ΡΠ³ΠΈ. ΠΠ° ΡΡΠΎΠ²Π΅Π½Ρ ΠΠΠ ΡΡΡΠ°Π½ Π²ΡΠΎΡΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡΠ΅ΡΠ° ΠΎΠΊΠ°Π·ΡΠ²Π°Π»ΠΈ Π²Π»ΠΈΡΠ½ΠΈΠ΅ ΡΠ°ΠΊΠΆΠ΅ Π΄Π²Π΅ Π³ΡΡΠΏΠΏΡ ΡΠ°ΠΊΡΠΎΡΠΎΠ². ΠΠ΄Π½Π° Π³ΡΡΠΏΠΏΠ° ΡΠ°ΠΊΡΠΎΡΠΎΠ² ΠΎΠ±ΡΠ΅Π΄ΠΈΠ½ΠΈΠ»Π° ΠΏΠ΅ΡΠ΅ΠΌΠ΅Π½Π½ΡΠ΅, Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΠ·ΡΡΡΠΈΠ΅ Π½ΠΎΠ²ΡΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈ Π² Π±ΠΈΠ·Π½Π΅ΡΠ΅, Π΄ΡΡΠ³Π°Ρ Π³ΡΡΠΏΠΏΠ° β ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΠ½ΡΠ΅ΡΠ½Π΅ΡΠ° Π½Π°ΡΠ΅Π»Π΅Π½ΠΈΠ΅ΠΌ. ΠΠ·ΡΡΠ΅Π½ΠΈΠ΅ ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠ΅ΠΉ ΡΠ°Π·Π²ΠΈΡΠΈΡ ΡΠΈΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΠ½ΠΎΠΌΠΈΠΊΠΈ, ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ»ΠΎ ΡΠ΄Π΅Π»Π°ΡΡ Π²ΡΠ²ΠΎΠ΄, ΡΡΠΎ Π² ΡΠ΅Π»ΠΎΠΌ ΠΏΠΎ Π²ΡΠ΅ΠΌΡ ΠΌΠΈΡΡ ΡΠ°Π·Π²ΠΈΠ²Π°Π΅ΡΡΡ ΡΠ΅Π½Π΄Π΅Π½ΡΠΈΡ Π±ΡΡΡΡΠΎΠ³ΠΎ ΡΠ°ΡΠΏΡΠΎΡΡΡΠ°Π½Π΅Π½ΠΈΡ ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ. ΠΡΠΎ Π³ΠΎΠ²ΠΎΡΠΈΡ ΠΎ ΡΠΎΠΌ, ΡΡΠΎ ΠΎΠ±ΡΠ΅ΡΡΠ²Ρ Π² ΡΠ°Π·ΡΠ΅Π·Π΅ Π³ΠΎΡΡΠ΄Π°ΡΡΡΠ²Π° ΠΈ ΠΎΡΠ΄Π΅Π»ΡΠ½ΠΎΠΉ Π»ΠΈΡΠ½ΠΎΡΡΠΈ Π½Π΅ΠΎΠ±Ρ
ΠΎΠ΄ΠΈΠΌΠΎ Π±ΡΡΡ ΠΌΠΎΠ±ΠΈΠ»ΡΠ½ΡΠΌΠΈ ΠΈ Π³ΠΎΡΠΎΠ²ΡΠΌΠΈ ΠΊ ΠΏΡΠΈΠ½ΡΡΠΈΡ Π½ΠΎΠ²ΡΡ
ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ Π·Π°ΡΠ°Π½Π΅Π΅
Suspensions of magnetic nanogels at zero field: Equilibrium structural properties
Magnetic nanogels represent a cutting edge of magnetic soft matter research due to their numerous potential applications. Here, using Langevin dynamics simulations, we analyse the influence of magnetic nanogel concentration and embedded magnetic particle interactions on the self-assembly of magnetic nanogels at zero field. For this, we calculated radial distribution functions and structure factors for nanogels and magnetic particles within them. We found that, in comparison to suspensions of free magnetic nanoparticles, where the self-assembly is already observed if the interparticle interaction strength exceeds the thermal fluctuations by approximately a factor of three, self-assembly of magnetic nanogels only takes place by increasing such ratio above six. This magnetic nanogel self-assembly is realised by means of favourable close contacts between magnetic nanoparticles from different nanogels. It turns out that for high values of interparticle interactions, corresponding to the formation of internal rings in isolated nanogels, in their suspensions larger magnetic particle clusters with lower elastic penalty can be formed by involving different nanogels. Finally, we show that when the self-assembly of these nanogels takes place, it has a drastic effect on the structural properties even if the volume fraction of magnetic nanoparticles is low. Β© 2019 Elsevier B.V.This research has been supported by the Russian Science Foundation Grant No. 19-12-00209 . Authors acknowledge support from the Austrian Research Fund (FWF), START-Projekt Y 627-N27. Computer simulations were performed at the Vienna Scientific Cluster (VSC-3)
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