Competition between glass transition and liquid-gas separation in attracting colloids

We present simulation results addressing the phenomena of colloidal gelation induced by attractive interactions. The liquid-gas transition is prevented by the glass arrest at high enough attraction strength, resulting in a colloidal gel. The dynamics of the system is controlled by the glass, with little effect of the liquid-gas transition. When the system separates in a liquid and vapor phases, even if the denser phase enters the non-ergodic region, the vapor phase enables the structural relaxation of the system as a whole.Comment: Proceedings of the glass conference in Pisa (September 06

Non--Newtonian viscosity of interacting Brownian particles: comparison of theory and data

A recent first-principles approach to the non-linear rheology of dense colloidal suspensions is evaluated and compared to simulation results of sheared systems close to their glass transitions. The predicted scenario of a universal transition of the structural dynamics between yielding of glasses and non-Newtonian (shear-thinning) fluid flow appears well obeyed, and calculations within simplified models rationalize the data over variations in shear rate and viscosity of up to 3 decades.Comment: 6 pages, 2 figures; J. Phys. Condens. Matter to be published (Jan. 2003

Schnabl's L_0 Operator in the Continuous Basis

Following Schnabl's analytic solution to string field theory, we calculate the operators ${\cal L}_0,{\cal L}_0^\dagger$ for a scalar field in the continuous $\kappa$ basis. We find an explicit and simple expression for them that further simplifies for their sum, which is block diagonal in this basis. We generalize this result for the bosonized ghost sector, verify their commutation relation and relate our expressions to wedge state representations.Comment: 1+16 pages. JHEP style. Typos correcte

Hard discs under steady shear: comparison of Brownian dynamics simulations and mode coupling theory

Brownian dynamics simulations of bidisperse hard discs moving in two dimensions in a given steady and homogeneous shear flow are presented close to and above the glasstransition density. The stationary structure functions and stresses of shear-melted glass are compared quantitatively to parameter-free numerical calculations of monodisperse hard discs using mode coupling theory within the integration through transients framework. Theory qualitatively explains the properties of the yielding glass but quantitatively overestimatesthe shear-driven stresses and structural anisotropies.Comment: 1. The original Phil. Trans. R. Soc. contains an error in the caption of the y-axes of the upper left panel in figure 9: There's a factor \dot{\gamma} missing in the denominato

Aging in attraction-driven colloidal glasses

Aging in an attraction-driven colloidal glass is studied by computer simulations. The system is equilibrated without attraction and instantaneously ``quenched'', at constant colloid volume fraction, to one of two states beyond the glass transition; one is close to the transition, and the other one deep in the glass. The evolution of structural properties shows that bonds form in the system, increasing the local density, creating density deficits (holes) elsewhere. This process slows down with the time elapsed since the quench. As a consequence of bond formation, there is a slowing down of the dynamics, as measured by the mean squared displacement and the density, bond, and environment correlation functions. The density correlations can be time-rescaled to collapse their long time (structural) decay. The time scale for structural relaxation shows for both quenches a super-linear dependence on waiting time; it grows faster than the bond lifetime, showing the collective origin of the transition. At long waiting times and high attraction strength, we observe {\rem completely} arrested dynamics for more than three decades in time, although individual bonds are not permanent on this time scale. The localization length decreases as the state moves deeper in the glass; the non-ergodicity parameter oscillates in phase with the structure factor. Our main results are obtained for systems with a barrier in the pair potential that inhibits phase separation. However, when this barrier is removed for the case of a deep quench, we find changes in the static structure but almost none in the dynamics. Hence our results for the aging behavior remain relevant to experiments in which the glass transition competes with phase separation.Comment: 12 pages, 15 figure

Superstring field theory equivalence: Ramond sector

We prove that the finite gauge transformation of the Ramond sector of the modified cubic superstring field theory is ill-defined due to collisions of picture changing operators. Despite this problem we study to what extent could a bijective classical correspondence between this theory and the (presumably consistent) non-polynomial theory exist. We find that the classical equivalence between these two theories can almost be extended to the Ramond sector: We construct mappings between the string fields (NS and Ramond, including Chan-Paton factors and the various GSO sectors) of the two theories that send solutions to solutions in a way that respects the linearized gauge symmetries in both sides and keeps the action of the solutions invariant. The perturbative spectrum around equivalent solutions is also isomorphic. The problem with the cubic theory implies that the correspondence of the linearized gauge symmetries cannot be extended to a correspondence of the finite gauge symmetries. Hence, our equivalence is only formal, since it relates a consistent theory to an inconsistent one. Nonetheless, we believe that the fact that the equivalence formally works suggests that a consistent modification of the cubic theory exists. We construct a theory that can be considered as a first step towards a consistent RNS cubic theory.Comment: v1: 24 pages. v2: 27 pages, significant modifications of the presentation, new section, typos corrected, references adde

Mode Coupling and Dynamical Heterogeneity in Colloidal Gelation: A Simulation Study

We present simulation results addressing the dynamics of a colloidal system with attractive interactions close to gelation. Our interaction also has a soft, long range repulsive barrier which suppresses liquid-gas type phase separation at long wavelengths. The new results presented here lend further weight to an intriguing picture emerging from our previous simulation work on the same system. Whereas mode coupling theory (MCT) offers quantitatively good results for the decay of correlators, closer inspection of the dynamics reveals a bimodal population of fast and slow particles with a very long exchange timescale. This population split represents a particular form of dynamic heterogeneity (DH). Although DH is usually associated with activated hopping and/or facilitated dynamics in glasses, the form of DH observed here may be more collective in character and associated with static (i.e., structural) heterogeneity.Comment: 12 pages, 12 figure

Ghost story. III. Back to ghost number zero

After having defined a 3-strings midpoint-inserted vertex for the bc system, we analyze the relation between gh=0 states (wedge states) and gh=3 midpoint duals. We find explicit and regular relations connecting the two objects. In the case of wedge states this allows us to write down a spectral decomposition for the gh=0 Neumann matrices, despite the fact that they are not commuting with the matrix representation of K1. We thus trace back the origin of this noncommutativity to be a consequence of the imaginary poles of the wedge eigenvalues in the complex k-plane. With explicit reconstruction formulas at hand for both gh=0 and gh=3, we can finally show how the midpoint vertex avoids this intrinsic noncommutativity at gh=0, making everything as simple as the zero momentum matter sector.Comment: 40 pages. v2: typos and minor corrections, presentation improved in sect. 4.3, plots added in app. A.1, two refs added. To appear in JHE

Glass transitions and shear thickening suspension rheology

We introduce a class of simple models for shear thickening and/ or `jamming' in colloidal suspensions. These are based on schematic mode coupling theory (MCT) of the glass transition, having a memory term that depends on a density variable, and on both the shear stress and the shear rate. (Tensorial aspects of the rheology, such as normal stresses, are ignored for simplicity.) We calculate steady-state flow curves and correlation functions. Depending on model parameters, we find a range of rheological behaviours, including `S-shaped' flow curves, indicating discontinuous shear thickening, and stress-induced transitions from a fluid to a nonergodic (jammed) state, showing zero flow rate in an interval of applied stress. The shear thickening and jamming scenarios that we explore appear broadly consistent with experiments on dense colloids close to the glass transition, despite the fact that we ignore hydrodynamic interactions. In particular, the jamming transition we propose is conceptually quite different from various hydrodynamic mechanisms of shear thickening in the literature, although the latter might remain pertinent at lower colloid densities. Our jammed state is a stress-induced glass, but its nonergodicity transitions have an analytical structure distinct from that of the conventional MCT glass transition.Comment: 33 pages; 19 figure

On the validity of the solution of string field theory

We analyze the realm of validity of the recently found tachyon solution of cubic string field theory. We find that the equation of motion holds in a non trivial way when this solution is contracted with itself. This calculation is needed to conclude the proof of Sen's first conjecture. We also find that the equation of motion holds when the tachyon or gauge solutions are contracted among themselves.Comment: JHEP style, 9+1 pages. Typos correcte