Functional electrospun polymeric nanofibers incorporating geraniol-cyclodextrin inclusion complexes: High thermal stability and enhanced durability of geraniol

Cataloged from PDF version of article.In this study, solid geraniol/cyclodextrin inclusion complexes (geraniol/CD-IC) were successfully prepared by using three types of native CD (alpha-CD, beta-CD and gamma-CD). The modeling studies for inclusion complexation between CD and geraniol were performed by using ab initio techniques. Both experimentally and theoretically, the cornplexation efficiency between geraniol and gamma-CD was higher; therefore, geraniol/gamma-CD-IC was chosen and then incorporated into polyvinyl alcohol (PVA) nanofibers (NF) via electrospinning. The scanning electron microscopy imaging elucidated that the aggregates of geraniol/gamma-CD-IC crystals were distributed in the PVA NF, whereas bead-free and uniform PVA and PVA/geraniol NF without CD-IC were obtained. Higher thermal stability of geraniol was observed in the electrospun PVA/geraniol/gamma-CD-IC NF, However, geraniol molecules having volatile nature could not be preserved without CD-IC during electrospinning or during storage; therefore, the complete evaporation of geraniol in PVA/geraniol NF was unavoidable even after one day of its production. On the contrary, the loss of geraniol was minimal (similar to 10%) for PVA/geraniol/gamma-CD-IC NF even after storage of these NF for two years owing to inclusion complexation. Our study demonstrated that electrospun NF incorporating CD-IC may be quite applicable in food industry, e.g.: active food packaging or functional foods, due to very high surface area and nanoporous structure of NF; high thermal stability and enhanced durability of active agents and functional food ingredients. (C) 2014 Elsevier Ltd. All rights reserved

City planning using integrated urban modeling Jeddah structure plan

This paper explores the use of weighted space syntax models to contribute to the process of integrated urban planning for Jeddah as part of a major planning project in the Saudi Arabia. The Municipality of Jeddah commissioned the production of an integrated suite of planning documents. These plans coordinate Strategic, Sub-Regional, Structural and Local plans across a citywide region and aim to provide a framework for sustainable urban growth and development over the next 20 years. This paper focuses on the space syntax methodologies used to aid urban planners to develop the Structure Plan and builds on the research used to develop the Sub-Regional Plan (Karimi et al, 2015). The Structure Plan studied how the urban structure of the city could accommodate the growth of population by about three million over the next 20 years. This included developing and testing a centres strategy to distribute population, employment and supporting facilities along with a public transport strategy for the city. For analysing the potential and requirements of the city, an Integrated Urban Model (IUM) was constructed to combine the spatial network with land use, population, employment and public transport. The aim of this model was to test the impact of changes in the distribution of population and employment. It also allowed the assessment of public transport alignments. The IUM is a key design tool for planning and optimising the relationships between population, employment and public transport. It was also used to provide a benchmarking methodology to compare options. Because the model links people to employment using the spatial network and public transport, the performance of options can be expressed in terms of benefits to the city's population

Using an analytical process to contextualise architectural prototypes for metro stations

In order to meet the pressures of a growing population and employment base, a developing city in the Middle East is planning a new public transport system to allow its sustainable growth. Introducing a new mode of public transport to a city that has a complex urban structure and a dependency on car use necessitates specific design responses to inform the station design process. This paper focuses on a study at the micro scale level that addresses the impact of evidence-based design on contextualised architectural station prototypes. Furthermore, it addresses the processes of working with an architectural design office in creating dynamic design iterations. The research here is presented from a perspective of the process of iterative analytical study to real time projects, reflecting on the balance between academia and practice. In order to construct a set of design principles to station locations, three layers of potential movement patterns are analysed using agents based modelling: movement from station exits; movement towards station entrances and background movement generated through the spatial accessibility values of the surrounding context. In that respect, each prototype station has been contextualised to its unique site. Design proposals developed by architectural teams are informed through fine grain analysis of urban features such as pavement widths and signage locations. The analyses also inform the landscape design process through the positioning of street furniture in relation to potential movement patterns as well as the effect of shading and public realm quality through option testing. To integrate stations within their contexts they must have simple entrances and clear orientation from the points of exit. Overall, the dynamic nature of agent based modelling allows for rapid design feedback to occur permitting an iterative process of design development and optimisation

Gold nanoparticle/polymer nanofibrous composites by laser ablation and electrospinning

Cataloged from PDF version of article.Poly(vinylpyrolidone) (PVP) nanofibers incorporating gold nanoparticles (Au-NPs) were produced in combination with laser ablation and electrospinning techniques. The Au-NPs were directly synthesized in PVP solution by laser ablation and then, the electrospinning of PVP/Au-NPs solution was carried out for obtaining nanofibrous composites. The presence of Au-NPs in the PVP nanofibers was confirmed by SEM, TEM and EDX analyses. The SEM imaging elucidated that the electrospun PVP/Au-NPs nanofibers were bead-free having average fiber diameter of 810 ± 480 nm. The TEM imaging indicated that the Au-NPs were in spherical shape having diameters in the range of 5 to 20 nm and the Au-NPs were more or less dispersed homogeneously in the PVP nanofiber matrix. The FTIR study suggested the presence of molecular interactions between PVP matrix and the Au-NPs in the nanofibrous composites. The UV–Vis measurement confirmed the enhancement of the optical properties of the PVP/Au-NPs nanofibers in the solid state due to the surface plasma resonance effect of Au-NPs

The effect of regular physical activity on women's self-confidence levels: An exploratory research

Introduction: It is known that physical activity is good for many diseases such as obesity, heart diseases, various types of cancer, musculoskeletal disorders. Compared to men, women's participation in physical activity is more limited. Physical activity, on the other hand, contributes to both the increase in the quality of life and the socialization of people. In this context, the aim of this study is to determine the self-confidence levels of women who regularly participate in physical activity. Method: In the research, besides the personal information form prepared by the researchers, the self-confidence scale was used. The sample population survey in Turkey Kocaeli province has created 408 women participating regularly in physical activity. In the analysis of the data, arithmetic means, frequency and percentage values were taken. As a result of the normality test, it was seen that it showed a normal distribution. Accordingly, independent sample t-test was used in the analysis of paired groups and one way Anova tests were used in the analysis of multiple groups. Results: As a result of the analysis, no significant difference was found in any sub-dimension according to the marital status variable. Significant differences were observed in the sub-dimensions of the scale according to the variables of income level, physical activity duration, education level and age. Conclusion: It has been observed that as the duration of physical activity increases, the level of self-confidence increases. In addition, it was concluded that age and educational status were directly related to self-confidence, and as education level and age increased, self-confidence increased

Photoluminescent electrospun polymeric nanofibers incorporating germanium nanocrystals

Cataloged from PDF version of article.The photoluminescent germanium nanocrystals (Ge-NCs) were successfully incorporated into electrospun polymeric nanofiber matrix in order to develop photoluminescent nanofibrous composite web. In the first step, the synthesis of Ge-NCs was achieved by nanosecond pulsed laser ablation of bulk germanium wafer immersed in organic liquid. The size, the structural and the chemical characteristics of Ge-NCs investigated by TEM, XPS, XRD and Raman spectroscopy revealed that the Ge-NCs were highly pure and highly crystalline having spherical shape within 3–20 nm particle size distribution. In the second step, Ge-NCs were mixed with polyvinyl alcohol (PVA) polymer solution, and then, Ge-NC/PVA nanofibers were obtained via electrospinning technique. The electrospinning of Ge-NCs/PVA nanoweb composite structure was successful and bead-free Ge-NCs/PVA nanofibers having average fiber diameter of 185 ± 40 nm were obtained. The STEM analysis of the electrospun Ge-NCs/PVA nanofibers elucidated that the Ge-NCs were distributed homogeneously in the polymeric nanofiber matrix. The UV–Vis absorption and photoluminescence spectroscopy studies indicated the quantum confinement effect of Ge-NCs on the optical properties of the electrospun Ge-NCs/PVA nanoweb

Modular logic gates: cascading independent logic gates via metal ion signals

Cataloged from PDF version of article.Abstract Systematic cascading of molecular logic gates is an important issue to be addressed for advancing research in this field. We have demonstrated that photochemically triggered metal ion signals can be utilized towards that goal. Thus, independent logic gates were shown to work together while keeping their identity in more complex logic designs. Communication through the intermediacy of ion signals is clearly inspired from biological processes modulated by such signals, and implemented here with ion responsive molecules. © 2014 The Royal Society of Chemistry.

Comparison of pure and mixed gas permeation of the highly fluorinated polymer of intrinsic microporosity PIM-2 under dry and humid conditions: Experiment and modelling

This manuscript describes the gas separation performance of PIM-2, a partially fluorinated linear copolymer synthesized from 5,5',6,6'-tetrahydroxy-3,3,3',3'-tetramethylspirobisindane (TTSBI) and decafluorobiphenyl (DFBP). As one of the early members of the family of polymers of intrinsic microporosity, it had never been tested as a gas separation membrane because of insufficient mechanical resistance. This has been solved only recently, allowing the preparation of robust self-standing films. Molecular modelling studies demonstrated a high fractional free volume (34%) and an elevated surface area (642 m2 g-1), and the latter is in good agreement with experimental BET results. Pure gas permeabilities measured on a fixed-volume time-lag instrument at 1 bar compare well with the results of mixed separation tests on a variable volume setup from 1-6 bar(a). Molecular modelling and independent sorption measurements on a gravimetric sorption balance both show strong dual-mode sorption behaviour, especially for CO2 and to a lesser extent for CH4. Temperature-dependent pure gas permeation measurements show typical Arrhenius behaviour, with a clear increase in the activation energy for diffusion with the increasing molecular size of the gas, indicating high size-selectivity. This is in agreement with the highly rigid PIM structure, determined by AFM force spectroscopy measurements. The dual-mode behaviour results in a moderate pressure dependence of the CO2 permeability and the CO2/N2 and CO2/CH4 selectivity, all slightly decreasing with increasing pressure. The presence of humidity in the gas stream has a remarkable small effect on the membrane performance, which is probably due to the high fluorine content and the consequently low water vapour solubility in the polymer, as confirmed by gravimetric sorption measurements. The manuscript describes an extensive study on the structure-property relationships in PIM-2. © 2019 Elsevier B.V.European Commission, EC Grantová Agentura Ceské Republiky, GA Ä?R: 18-05484S --Research on biogas upgrading presented in this work was supported by EU structural funding in the frame of Operational Programme Research, Development and Education, project No. CZ.02.1.01./0.0/0.0/17_049/0008419 “COOPERATION”. This work was further supported by the CNR-CAS bilateral agreement 2016–2018 “Innovative polymeric membranes for pervaporation and advanced gas and vapour separations” and by the Czech Science Foundation (grant no. 18-05484S ). Appendix A -

Near-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions

Cataloged from PDF version of article.A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions

Authorship attribution: Performance of various features and classification methods

Authorship attribution is the process of determining the writer of a document. In literature, there are lots of classification techniques conducted in this process. In this paper we explore information retrieval methods such as tf-idf structure with support vector machines, parametric and nonparametric methods with supervised and unsupervised (clustering) classification techniques in authorship attribution. We performed various experiments with articles gathered from Turkish newspaper Milliyet. We performed experiments on different features extracted from these texts with different classifiers, and combined these results to improve our success rates. We identified which classifiers give satisfactory results on which feature sets. According to experiments, the success rates dramatically changes with different combinations, however the best among them are support vector classifier with bag of words, and Gaussian with function words. ©2007 IEEE