Anomalous diffusion and stretched exponentials in heterogeneous glass-forming liquids: Low-temperature behavior

We propose a model of a heterogeneous glass forming liquid and compute the low-temperature behavior of a tagged molecule moving within it. This model exhibits stretched-exponential decay of the wavenumber-dependent, self intermediate scattering function in the limit of long times. At temperatures close to the glass transition, where the heterogeneities are much larger in extent than the molecular spacing, the time dependence of the scattering function crosses over from stretched-exponential decay with an index $b=1/2$ at large wave numbers to normal, diffusive behavior with $b = 1$ at small wavenumbers. There is a clear separation between early-stage, cage-breaking $\beta$ relaxation and late-stage $\alpha$ relaxation. The spatial representation of the scattering function exhibits an anomalously broad exponential (non-Gaussian) tail for sufficiently large values of the molecular displacement at all finite times.Comment: 9 pages, 6 figure

Dynamics of Large-Scale Plastic Deformation and the Necking Instability in Amorphous Solids

We use the shear transformation zone (STZ) theory of dynamic plasticity to study the necking instability in a two-dimensional strip of amorphous solid. Our Eulerian description of large-scale deformation allows us to follow the instability far into the nonlinear regime. We find a strong rate dependence; the higher the applied strain rate, the further the strip extends before the onset of instability. The material hardens outside the necking region, but the description of plastic flow within the neck is distinctly different from that of conventional time-independent theories of plasticity.Comment: 4 pages, 3 figures (eps), revtex4, added references, changed and added content, resubmitted to PR

Direct Identification of the Glass Transition: Growing Length Scale and the Onset of Plasticity

Understanding the mechanical properties of glasses remains elusive since the glass transition itself is not fully understood, even in well studied examples of glass formers in two dimensions. In this context we demonstrate here: (i) a direct evidence for a diverging length scale at the glass transition (ii) an identification of the glass transition with the disappearance of fluid-like regions and (iii) the appearance in the glass state of fluid-like regions when mechanical strain is applied. These fluid-like regions are associated with the onset of plasticity in the amorphous solid. The relaxation times which diverge upon the approach to the glass transition are related quantitatively.Comment: 5 pages, 5 figs.; 2 figs. omitted, new fig., quasi-crystal discussion omitted, new material on relaxation time

Shear flow of angular grains: acoustic effects and non-monotonic rate dependence of volume

Naturally-occurring granular materials often consist of angular particles whose shape and frictional characteristics may have important implications on macroscopic flow rheology. In this paper, we provide a theoretical account for the peculiar phenomenon of auto-acoustic compaction -- non-monotonic variation of shear band volume with shear rate in angular particles -- recently observed in experiments. Our approach is based on the notion that the volume of a granular material is determined by an effective-disorder temperature known as the compactivity. Noise sources in a driven granular material couple its various degrees of freedom and the environment, causing the flow of entropy between them. The grain-scale dynamics is described by the shear-transformation-zone (STZ) theory of granular flow, which accounts for irreversible plastic deformation in terms of localized flow defects whose density is governed by the state of configurational disorder. To model the effects of grain shape and frictional characteristics, we propose an Ising-like internal variable to account for nearest-neighbor grain interlocking and geometric frustration, and interpret the effect of friction as an acoustic noise strength. We show quantitative agreement between experimental measurements and theoretical predictions, and propose additional experiments that provide stringent tests on the new theoretical elements.Comment: 12 pages, 3 figure

Stick-slip instabilities in sheared granular flow: the role of friction and acoustic vibrations

We propose a theory of shear flow in dense granular materials. A key ingredient of the theory is an effective temperature that determines how the material responds to external driving forces such as shear stresses and vibrations. We show that, within our model, friction between grains produces stick-slip behavior at intermediate shear rates, even if the material is rate-strengthening at larger rates. In addition, externally generated acoustic vibrations alter the stick-slip amplitude, or suppress stick-slip altogether, depending on the pressure and shear rate. We construct a phase diagram that indicates the parameter regimes for which stick-slip occurs in the presence and absence of acoustic vibrations of a fixed amplitude and frequency. These results connect the microscopic physics to macroscopic dynamics, and thus produce useful information about a variety of granular phenomena including rupture and slip along earthquake faults, the remote triggering of instabilities, and the control of friction in material processing.Comment: 12 pages, 8 figure

Nonequilibrium Thermodynamics of Amorphous Materials III: Shear-Transformation-Zone Plasticity

We use the internal-variable, effective-temperature thermodynamics developed in two preceding papers to reformulate the shear-transformation-zone (STZ) theory of amorphous plasticity. As required by the preceding analysis, we make explicit approximations for the energy and entropy of the STZ internal degrees of freedom. We then show that the second law of thermodynamics constrains the STZ transition rates to have an Eyring form as a function of the effective temperature. Finally, we derive an equation of motion for the effective temperature for the case of STZ dynamics.Comment: 8 pages. Third of a three-part serie

Steady-State Cracks in Viscoelastic Lattice Models II

We present the analytic solution of the Mode III steady-state crack in a square lattice with piecewise linear springs and Kelvin viscosity. We show how the results simplify in the limit of large width. We relate our results to a model where the continuum limit is taken only along the crack direction. We present results for small velocity, and for large viscosity, and discuss the structure of the critical bifurcation for small velocity. We compute the size of the process zone wherein standard continuum elasticity theory breaks down.Comment: 17 pages, 3 figure

Rate dependent shear bands in a shear transformation zone model of amorphous solids

We use Shear Transformation Zone (STZ) theory to develop a deformation map for amorphous solids as a function of the imposed shear rate and initial material preparation. The STZ formulation incorporates recent simulation results [Haxton and Liu, PRL 99 195701 (2007)] showing that the steady state effective temperature is rate dependent. The resulting model predicts a wide range of deformation behavior as a function of the initial conditions, including homogeneous deformation, broad shear bands, extremely thin shear bands, and the onset of material failure. In particular, the STZ model predicts homogeneous deformation for shorter quench times and lower strain rates, and inhomogeneous deformation for longer quench times and higher strain rates. The location of the transition between homogeneous and inhomogeneous flow on the deformation map is determined in part by the steady state effective temperature, which is likely material dependent. This model also suggests that material failure occurs due to a runaway feedback between shear heating and the local disorder, and provides an explanation for the thickness of shear bands near the onset of material failure. We find that this model, which resolves dynamics within a sheared material interface, predicts that the stress weakens with strain much more rapidly than a similar model which uses a single state variable to specify internal dynamics on the interface.Comment: 10 pages, 13 figures, corrected typos, added section on rate strengthening vs. rate weakening material

Langevin Equation for the Density of a System of Interacting Langevin Processes

We present a simple derivation of the stochastic equation obeyed by the density function for a system of Langevin processes interacting via a pairwise potential. The resulting equation is considerably different from the phenomenological equations usually used to describe the dynamics of non conserved (Model A) and conserved (Model B) particle systems. The major feature is that the spatial white noise for this system appears not additively but multiplicatively. This simply expresses the fact that the density cannot fluctuate in regions devoid of particles. The steady state for the density function may however still be recovered formally as a functional integral over the coursed grained free energy of the system as in Models A and B.Comment: 6 pages, latex, no figure

Metastability in Two Dimensions and the Effective Potential

We study analytically and numerically the decay of a metastable phase in (2+1)-dimensional classical scalar field theory coupled to a heat bath, which is equivalent to two-dimensional Euclidean quantum field theory at zero temperature. By a numerical simulation we obtain the nucleation barrier as a function of the parameters of the potential, and compare it to the theoretical prediction from the bounce (critical bubble) calculation. We find the nucleation barrier to be accurately predicted by theory using the bounce configuration obtained from the tree-level (``classical'') effective action. Within the range of parameters probed, we found that using the bounce derived from the one-loop effective action requires an unnaturally large prefactor to match the lattice results. Deviations from the tree-level prediction are seen in the regime where loop corrections would be expected to become important.Comment: 13pp, LaTex with Postscript figs, CLNS 93/1202, DART-HEP-93/0