851 research outputs found
Analysis of the absorption and emission spectra of U4+ in α-ThBr 4
The low temperature form α-ThBr4 has a scheelite structure I41/a in which the tetravalent uranium occupies the thorium site which is S4. Assuming that the ground state remains Î 4 as in the ÎČ-ThBr4 form, the polarized absorption spectrum at 4.2 K shows that D2d is a good approximation. A peculiarity of this host is the exaltation of very numerous fluorescences of U4+ which permit to assign four Stark levels of the ground state 3H4 : Î5 at 110 cm-1, Î 1 at 473 cm-1, Î1 at 623 cm-1 and Î5 at 830 cm-1. 30 levels have been assigned and the crystal field parameters of U4+ (5f2) have been calculated in the D2d approximation : B20 = - 382, B40 = - 3 262, B44 = - 1734, B60 = - 851 and B64 = - 1828 cm-1. It is interesting to note that a small distortion in the scheelite structure of the α-ThBr4 compared with the zircon structure ÎČ-ThBr4 induces important changes in the crystal field parameters
Electromagnetic vacuum energy for two parallel slabs in terms of surface, wave guide and photonic modes
The formulation of the Lifshitz formula in terms of real frequencies is
reconsidered for half spaces described by the plasma model. It is shown that
besides the surface modes (for the TM polarization), and the photonic modes,
also waveguide modes must be considered.Comment: some references adde
Surface plasmon modes and the Casimir energy
We show the influence of surface plasmons on the Casimir effect between two
plane parallel metallic mirrors at arbitrary distances. Using the plasma model
to describe the optical response of the metal, we express the Casimir energy as
a sum of contributions associated with evanescent surface plasmon modes and
propagative cavity modes. In contrast to naive expectations, the plasmonic
modes contribution is essential at all distances in order to ensure the correct
result for the Casimir energy. One of the two plasmonic modes gives rise to a
repulsive contribution, balancing out the attractive contributions from
propagating cavity modes, while both contributions taken separately are much
larger than the actual value of the Casimir energy. This also suggests
possibilities to tailor the sign of the Casimir force via surface plasmons.Comment: 4 pages, 3 figures, revtex
Influence of water adsorbed on gold on van der Waals/Casimir forces
In this paper we investigate the influence of ultra thin water layer (1-1.5
nm) on the van der Waals/Casimir force between gold surfaces. Adsorbed water is
inevitably present on gold surfaces at ambient conditions as jump-up-to contact
during adhesion experiments demonstrate. Calculations based on the Lifshitz
theory give very good agreement with the experiment in absence of any water
layer for surface separations d>10 nm. However, a layer of thickness h<1.5 nm
is allowed by the error margin in force measurements. At shorter separations,
d<10 nm, the water layer can have a strong influence as calculations show for
flat surfaces. Nonetheless, in reality the influence of surface roughness must
also be considered, and it can overshadow any water layer influence at
separations comparable to the total sphere-plate rms roughness w_{shp}+w.Comment: 8 pages, 5 figure, to be published in Phys. Rev.
The role of Surface Plasmon modes in the Casimir Effect
In this paper we study the role of surface plasmon modes in the Casimir
effect. First we write the Casimir energy as a sum over the modes of a real
cavity. We may identify two sorts of modes, two evanescent surface plasmon
modes and propagative modes. As one of the surface plasmon modes becomes
propagative for some choice of parameters we adopt an adiabatic mode definition
where we follow this mode into the propagative sector and count it together
with the surface plasmon contribution, calling this contribution "plasmonic".
The remaining modes are propagative cavity modes, which we call "photonic". The
Casimir energy contains two main contributions, one coming from the plasmonic,
the other from the photonic modes. Surprisingly we find that the plasmonic
contribution to the Casimir energy becomes repulsive for intermediate and large
mirror separations. Alternatively, we discuss the common surface plasmon
defintion, which includes only evanescent waves, where this effect is not
found. We show that, in contrast to an intuitive expectation, for both
definitions the Casimir energy is the sum of two very large contributions which
nearly cancel each other. The contribution of surface plasmons to the Casimir
energy plays a fundamental role not only at short but also at large distances.Comment: 10 pages, 3 figures. TQMFA200
Conductivity in organic semiconductors hybridized with the vacuum field
Organic semiconductors have generated considerable interest for their
potential for creating inexpensive and flexible devices easily processed on a
large scale [1-11]. However technological applications are currently limited by
the low mobility of the charge carriers associated with the disorder in these
materials [5-8]. Much effort over the past decades has therefore been focused
on optimizing the organisation of the material or the devices to improve
carrier mobility. Here we take a radically different path to solving this
problem, namely by injecting carriers into states that are hybridized to the
vacuum electromagnetic field. These are coherent states that can extend over as
many as 10^5 molecules and should thereby favour conductivity in such
materials. To test this idea, organic semiconductors were strongly coupled to
the vacuum electromagnetic field on plasmonic structures to form polaritonic
states with large Rabi splittings ca. 0.7 eV. Conductivity experiments show
that indeed the current does increase by an order of magnitude at resonance in
the coupled state, reflecting mostly a change in field-effect mobility as
revealed when the structure is gated in a transistor configuration. A
theoretical quantum model is presented that confirms the delocalization of the
wave-functions of the hybridized states and the consequences on the
conductivity. While this is a proof-of-principle study, in practice
conductivity mediated by light-matter hybridized states is easy to implement
and we therefore expect that it will be used to improve organic devices. More
broadly our findings illustrate the potential of engineering the vacuum
electromagnetic environment to modify and to improve properties of materials.Comment: 16 pages, 13 figure
Weak Measurements of Light Chirality with a Plasmonic Slit
We examine, both experimentally and theoretically, an interaction of tightly
focused polarized light with a slit on a metal surface supporting
plasmon-polariton modes. Remarkably, this simple system can be highly sensitive
to the polarization of the incident light and offers a perfect
quantum-weak-measurement tool with a built-in post-selection in the
plasmon-polariton mode. We observe the plasmonic spin Hall effect in both
coordinate and momentum spaces which is interpreted as weak measurements of the
helicity of light with real and imaginary weak values determined by the input
polarization. Our experiment combines advantages of (i) quantum weak
measurements, (ii) near-field plasmonic systems, and (iii) high-numerical
aperture microscopy in employing spin-orbit interaction of light and probing
light chirality.Comment: 5 pages, 3 figure
Bone age estimation with the Greulich-Pyle atlas using 3T MR images of hand and wrist.
The age estimation of the hand bones by means of X-ray examination is a pillar of the forensic age estimation. Since the associated radiation exposure is controversial, the search for ionizing radiation-free alternatives such as MRI is part of forensic research. The aim of the current study was to use the Greulich-Pyle (GP) atlas on MR images of the hand and wrist to provide reference values for assessing the age of the hand bones. 3T hand MR images of 238 male participants between the ages of 13 and 21 were acquired using 3D gradient echo sequences (VIBE, DESS). Two readers rated the images using the X-ray-based GP atlas method. A descriptive analysis and a transitional analysis were used for the statistical processing of the data. The agreement between and within the raters was assessed. In addition, a comparison was made with the chronological age and with X-ray studies. The descriptive analysis and the transition analysis showed similar results. Both evaluations showed good agreement with X-ray studies. The comparison with the chronological age showed a difference of 0.37 and 0.54 years for the two readers. The age estimate based on the cross-validated transition analysis showed a mean error of -0.28 years. Inter- and intra-rater agreement were good. In summary, it can be concluded that age estimation of hand bones with MR images is routinely applicable with the GP atlas as an alternative without ionizing radiation. However, in order to reduce the estimation error, a multi-factorial assessment based on examinations of several body regions is still recommended
Casimir energy and geometry : beyond the Proximity Force Approximation
We review the relation between Casimir effect and geometry, emphasizing
deviations from the commonly used Proximity Force Approximation (PFA). We use
to this aim the scattering formalism which is nowadays the best tool available
for accurate and reliable theory-experiment comparisons. We first recall the
main lines of this formalism when the mirrors can be considered to obey
specular reflection. We then discuss the more general case where non planar
mirrors give rise to non-specular reflection with wavevectors and field
polarisations mixed. The general formalism has already been fruitfully used for
evaluating the effect of roughness on the Casimir force as well as the lateral
Casimir force or Casimir torque appearing between corrugated surfaces. In this
short review, we focus our attention on the case of the lateral force which
should make possible in the future an experimental demonstration of the
nontrivial (i.e. beyond PFA) interplay of geometry and Casimir effect.Comment: corrected typos, added references, QFEXT'07 special issue in J. Phys.
The Scattering Approach to the Casimir Force
We present the scattering approach which is nowadays the best tool for
describing the Casimir force in realistic experimental configurations. After
reminders on the simple geometries of 1d space and specular scatterers in 3d
space, we discuss the case of stationary arbitrarily shaped mirrors in
electromagnetic vacuum. We then review specific calculations based on the
scattering approach, dealing for example with the forces or torques between
nanostructured surfaces and with the force between a plane and a sphere. In
these various cases, we account for the material dependence of the forces, and
show that the geometry dependence goes beyond the trivial {\it Proximity Force
Approximation} often used for discussing experiments.Comment: Proceedings of the QFEXT'09 conference (Oklahoma, 2009
- âŠ