579 research outputs found
Surface Induced Order in Liquid Metals and Binary Alloys
Measurements of the surface x-ray scattering from several pure liquid metals
(Hg, Ga, and In) and from three alloys (Ga-Bi, Bi-In, and K-Na) with different
heteroatomic chemical interactions in the bulk phase are reviewed.
Surface-induced layering is found for each elemental liquid metal. The surface
structure of the K-Na alloy resembles that of an elemental liquid metal. Bi-In
displays pair formation at the surface. Surface segregation and a wetting film
are found for Ga-Bi.Comment: 10 pages, 3 fig, published in Journal of Physics: Condensed Matte
Effect of vertical active vibration isolation on tracking performance and on ride qualities
An investigation to determine the effect on pilot performance and comfort of an active vibration isolation system for a commercial transport pilot seat is reported. The test setup consisted of: a hydraulic shaker which produced random vertical vibration inputs; the active vibration isolation system; the pilot seat; the pilot control wheel and column; the side-arm controller; and a two-axis compensatory tracking task. The effects of various degrees of pilot isolation on short-term (two-minute) tracking performance and comfort were determined
Microscopic Surface Structure of Liquid Alkali Metals
We report an x-ray scattering study of the microscopic structure of the
surface of a liquid alkali metal. The bulk liquid structure factor of the
eutectic K67Na33 alloy is characteristic of an ideal mixture, and so shares the
properties of an elemental liquid alkali metal. Analysis of off-specular
diffuse scattering and specular x-ray reflectivity shows that the surface
roughness of the K-Na alloy follows simple capillary wave behavior with a
surface structure factor indicative of surface induced layering. Comparison of
thelow-angle tail of the K67Na33 surface structure factor with the one measured
for liquid Ga and In previously suggests that layering is less pronounced in
alkali metals. Controlled exposure of the liquid to H2 and O2 gas does not
affect the surface structure, indicating that oxide and hydride are not stable
at the liquid surface under these experimental conditions.Comment: 12 pages, 3 figures, published in Phys. Rev.
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Competition between Surface Layering and Surface Phase Formation in Dilute Liquid Hg−Au Alloys
We present temperature-dependent X-ray reflectivity measurements of liquid Hg alloyed with 0.06−0.20 atom % Au. At low Au concentrations, we find temperature-dependent surface-induced layering similar to that observed in pure Hg, except that the presence of Au reduces the layering amplitude. Upon approaching the solubility limit of Au in Hg, a new surface phase forms which is 1−2 atomic diameters thick and has a density of about half that of bulk Hg. We present a surface phase diagram, summarizing the evolution of this unexpected surface structure upon varying composition and temperature. Such surface modifications may account for the variations observed in catalytic and electrochemical reactions at liquid metal surfaces upon alloying.Engineering and Applied Science
Fermi Surface reconstruction in the CDW state of CeTe3 observed by photoemission
CeTe3 is a layered compound where an incommensurate Charge Density Wave (CDW)
opens a large gap (400 meV) in optimally nested regions of the Fermi Surface
(FS), whereas other sections with poorer nesting remain ungapped. Through
Angle-Resolved Photoemission, we identify bands backfolded according to the CDW
periodicity. They define FS pockets formed by the intersection of the original
FS and its CDW replica. Such pockets illustrate very directly the role of
nesting in the CDW formation but they could not be detected so far in a CDW
system. We address the reasons for the weak intensity of the folded bands, by
comparing different foldings coexisting in CeTe3
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Wetting Behavior at the Free Surface of a Liquid Gallium–Bismuth Alloy: An X-ray Reflectivity Study Close to the Bulk Monotectic Point
We present X-ray reflectivity measurements from the free surface of a liquid gallium–bismuth alloy (Ga–Bi) in the temperature range close to the bulk monotectic temperature =222C. Our measurements indicate a continuous formation of a thick wetting film at the free surface of the binary system driven by the first order transition in the bulk at the monotectic point. We show that the behavior observed is that of a complete wetting at a tetra point of solid–liquid–liquid–vapor coexistence.Engineering and Applied Science
Atomic-scale surface demixing in a eutectic liquid BiSn alloy
Resonant x-ray reflectivity of the surface of the liquid phase of the
BiSn eutectic alloy reveals atomic-scale demixing extending over
three near-surface atomic layers. Due to the absence of underlying atomic
lattice which typically defines adsorption in crystalline alloys, studies of
adsorption in liquid alloys provide unique insight on interatomic interactions
at the surface. The observed composition modulation could be accounted for
quantitatively by the Defay-Prigogine and Strohl-King multilayer extensions of
the single-layer Gibbs model, revealing a near-surface domination of the
attractive Bi-Sn interaction over the entropy.Comment: 4 pages (two-column), 3 figures, 1 table; Added a figure, updated
references, discussion; accepted at Phys. Rev. Let
Anomalous layering at the liquid Sn surface
X-ray reflectivity measurements on the free surface of liquid Sn are
presented. They exhibit the high-angle peak, indicative of surface-induced
layering, also found for other pure liquid metals (Hg, Ga and In). However, a
low-angle peak, not hitherto observed for any pure liquid metal, is also found,
indicating the presence of a high-density surface layer. Fluorescence and
resonant reflectivity measurements rule out the assignment of this layer to
surface-segregation of impurities. The reflectivity is modelled well by a 10%
contraction of the spacing between the first and second atomic surface layers,
relative to that of subsequent layers. Possible reasons for this are discussed.Comment: 8 pages, 9 figures; to be submitted to Phys. Rev. B; updated
references, expanded discussio
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