Synthesis and characterization of dioxidomolybdenum(VI) complexes with thiosemicarbazone ligands

The chemistry of thiosemicarbazone complexes of transition metals has been the subject of attention, primarily because of overgrowing biological properties. These activities have been correlated with their metal-chelating abilities and reductive capacity. The coordination chemistry of molybdenum receives special attention due to chemistry of its oxidation state, coordination number, ligating atom and their impact on structure and reactivity. To extend these observations, in this dissertation an attention is focused on the synthesis and characterization of new dioxidomolybdenum(VI) complexes featuring thiosemicarbazone ligands

Comment on "1/f noise in the Bak-Sneppen model"

Contrary to the recently published results by Daerden and Vanderzande [Phys. Rev. E 53, 4723 (1996)], we show that the time correlation function in the random-neighbor version of the Bak-Sneppen model can be well approximated by an exponential giving rise to a 1/f2 power spectrum.Comment: 2 pages, 2 figure

Reformas estructurales para la sostenibilidad del gasto sanitario: un análisis del caso de España.

La sostenibilidad del gasto sanitario ha sido objeto de estudio en nuestro país en las últimas décadas, y con la llegada de la crisis da lugar a un nuevo panorama de inseguridad a la hora de mantener los servicios que ofrece nuestro sistema sanitario, con la misma calidad y eficiencia. El análisis está orientado al estudio de la evolución del gasto sanitario, centrándose más tarde, en los factores que provocan su tendencia creciente, destacando el cambio demográfico que viviremos en un futuro cercano. Tras el análisis del gasto sanitario, profundizaremos en el estudio de las reformas, sus efectos, y recomendaciones para mejorar la situación en la que vivimos.Departamento de Economía AplicadaGrado en Economí

Cellular Automata Simulating Experimental Properties of Traffic Flows

A model for 1D traffic flow is developed, which is discrete in space and time. Like the cellular automaton model by Nagel and Schreckenberg [J. Phys. I France 2, 2221 (1992)], it is simple, fast, and can describe stop-and-go traffic. Due to its relation to the optimal velocity model by Bando et al. [Phys. Rev. E 51, 1035 (1995)], its instability mechanism is of deterministic nature. The model can be easily calibrated to empirical data and displays the experimental features of traffic data recently reported by Kerner and Rehborn [Phys. Rev. E 53, R1297 (1996)].Comment: For related work see http://www.theo2.physik.uni-stuttgart.de/helbing.html and http://traffic.comphys.uni-duisburg.de/member/home_schreck.htm

A Statistical Treatment of the Gamma-Ray Burst "No Host Galaxy" Problem: II. Energies of Standard Candle Bursts

With the discovery that the afterglows after some bursts are coincident with faint galaxies, the search for host galaxies is no longer a test of whether bursts are cosmological, but rather a test of particular cosmological models. The methodology we developed to investigate the original "no host galaxy" problem is equally valid for testing different cosmological models, and is applicable to the galaxies coincident with optical transients. We apply this methodology to a family of models where we vary the total energy of standard candle bursts. We find that total isotropic energies of E<2e52~erg are ruled out while log(E)~53 erg is favored.Comment: To appear in Ap.J., 514, 15 pages + 7 figures, AASTeX 4.0. Revisions are: additional author, updated data, and minor textual change

Properties of Ridges in Elastic Membranes

When a thin elastic sheet is confined to a region much smaller than its size the morphology of the resulting crumpled membrane is a network of straight ridges or folds that meet at sharp vertices. A virial theorem predicts the ratio of the total bending and stretching energies of a ridge. Small strains and curvatures persist far away from the ridge. We discuss several kinds of perturbations that distinguish a ridge in a crumpled sheet from an isolated ridge studied earlier (A. E. Lobkovsky, Phys. Rev. E. 53 3750 (1996)). Linear response as well as buckling properties are investigated. We find that quite generally, the energy of a ridge can change by no more than a finite fraction before it buckles.Comment: 13 pages, RevTeX, acknowledgement adde

The von Karman equations, the stress function, and elastic ridges in high dimensions

The elastic energy functional of a thin elastic rod or sheet is generalized to the case of an M-dimensional manifold in N-dimensional space. We derive potentials for the stress field and curvatures and find the generalized von Karman equations for a manifold in elastic equilibrium. We perform a scaling analysis of an M-1 dimensional ridge in an M = N-1 dimensional manifold. A ridge of linear size X in a manifold with thickness h << X has a width w ~ h^{1/3}X^{2/3} and a total energy E ~ h^{M} (X/h)^{M-5/3}. We also prove that the total bending energy of the ridge is exactly five times the total stretching energy. These results match those of A. Lobkovsky [Phys. Rev. E 53, 3750 (1996)] for the case of a bent plate in three dimensions.Comment: corrected references, 27 pages, RevTeX + epsf, 2 figures, Submitted to J. Math. Phy