Analysis of Particulate Matter Composition

According to current research, particulate matter (PM) has a negative impact on citizens in particular (respiratory and cardiovascular diseases). Based on EU studies, deaths of 347,900 Europeans are attributable to air pollution. Formation of particulate matter from road transport has been a concern for big cities in particular.For long time monitoring PM we choosed the sections of roads located both within urban areas and rural areas were selected for longterm monitoring, differing in particular by the surface of the roadway - either with asphalt concrete paving (AC) or with stone mastic asphalt (SMA) paving, an asphalt compound with disintegrated stone grade and a higher percentage of asphalt binder.We were executed the Air Samples with using medium-volume LECKEL MVS6 sampling pump

Differentiation of Particulate Matter Sources Based on the Chemical Composition of PM10 in Functional Urban Areas

Urban air quality is continuing to deteriorate. If we want to do something about this problem, we need to know the cause of the pollution. The big problem, not only in Europe, is the high concentrations of particulate matter (PM) in the urban environment. The origin of these particles can be different, including combustion, transport, industry, natural resources, etc. Particulate matter includes a large amount of the finest PM fractions, which can remain in the air for a long time, easily enter respiratory tracks, and damage human health. Particulate matter is also produced by the abrasion of different parts of roads and vehicle fleets and from resuspension road dust, which concerns matter with larger aerodynamic diameters. For this reason, we carried out a series of measurements at various measuring stations in Žilina, Slovakia, during different measuring seasons. The main objective was to find out the diversity of particulate matter sources in Žilina. The search for the particulate matter origin was carried out by particulate matter measurements, determination of the particulate matter fraction concentrations (PM10, PM2.5, and PM1), an investigation on the effect of secondary factors on the particulate matter concentrations, chemical analyses, and multivariate statistical analyses. Varied behavior of the particulate matter with respect to the measurement station and the measurement season was found. Differences in the concentrations of investigated chemical elements contained in the PM were found. Significant changes in the concentrations of particulate matter are caused not only by primary sources (e.g., road traffic in the city of Žilina), but mainly by the negative events (combination of air pollution sources and meteorological conditions). Maximum concentrations of particulate matter PM10 were measured during the winter season at the measuring station on Komenského Street: PM10 126.2 µg/m3, PM2.5 97.7 µg/m3, and PM1 90.4 µg/m3 were obtained using the gravimetric method. The coarse fraction PM2.5-10 was mainly represented by the chemical elements Mg, Al, Si, Ca, Cr, Fe, and Ba, and the fine fraction PM2.5 was represented by the chemical elements K, S, Cd, Pb, Ni, and Zn. Road transport as a dominant source of PM10 was identified from all measurements in the city of Žilina by using the multivariate statistical methods of principal component analysis (PCA) and factor analysis (FA)

Particulate matter mass concentrations produced from pavement surface abrasion

According to the latest findings particulate matter belong to the most significant pollutants in Europe together with ground-level ozone O3 and nitrogen dioxide NO2. Road traffic is one of the main sources of particulate matter. Traffic volume has unpleasant impact on longevity of the pavements and also on the environment. Vehicle motions cause mechanical wearing of the asphalt pavement surface - wearing course by vehicle tyres. The paper deals with abrasion of bituminous wearing courses of pavements. The asphalt mixtures are compared in terms of mechanically separated particulate matter. The samples of asphalt mixtures were rutted in wheel tracking machine. The particulate matter measurements were performed in laboratory conditions. The experimental laboratory measurements make it possible to sample particulates without contamination from exhaust emissions, abraded particles from vehicles, resuspension of road dust and climate affects. The paper offers partial results of measurements on six trial samples of asphalt mixtures with different composition. It presents particulate matter morphology and the comparison of rutted asphalt samples in terms of PM mass concentrations and chemical composition

Concentrations of Traffic Related Pollutants in the Vicinity of Different Types of Urban Crossroads

Pollution of the air by gases and particulate matter is a problem of everyday life. Particulate matter (PM) is one of the hazardous pollutants causing deterioration of the environment and thus quality of life of the population. Long-term exposure to effects of increased concentrations of gaseous pollutants can also cause deterioration of the environment and human health. Particulate matter and gases production by the road transport is a burning issue, particularly for larger urban areas. Many factors influence the air quality what determines its development and changes. Air pollution monitoring was focused on a possible change in the concentrations of pollutants after the change of the crossroad - three-arm crossroad to the roundabout. The subject of this paper is monitoring particulate matter (PM1, PM2.5, PM10) and gases (nitrogen oxides NO, NO2, NOx) in the vicinity of crossroads in the urban area and an evaluation of fraction ratios PM10, PM2.5 and PM1 with regard to construction of crossroad, meteorological conditions and traffic volume. The roundabout has specific construction and routing traffic, what can influence on production and dispersion of traffic related emissions. The obtained results indicate a decrease in particulate matter concentrations at the roundabout over a three-arm crossroad and an increase in nitrogen oxides concentrations at the roundabout compared to the three-arm crossroad. According to the data obtained and analyzed, the PM10 particulate matter concentrations at the roundabout could be reduced by up to 50% over the three-arm crossroad

Polychlorinated Dibenzodioxins and Dibenzofurans Emissions from Transportation

Measurement of Persistent Organic Pollutants (POPs) was performed in order to complement the set of known emission factors. Methodology for gasoline engines emission factors determination that uses POPs concentrations measured in exhaust gasses, limited pollutants emission factors (carbon monoxide CO, nitrogen oxides NOx and hydrocarbons HC) and other compounds (carbon dioxide CO2) was elaborated. Empirical value of exhaust gasses production announced by specialists of TUV SUD was used for diesel. Emission factors of four vehicle-fuel systems were determined particularly 11 congeners of Polychlorinated Dibenzodioxins (PCDDs), 34 congeners of Polychlorinated Dibenzofurans (PCDFs) and their toxic equivalents (TEQ) for each of the measured system. TEQ PCDD/F congener profile typical for POPs sources from transportation was compiled on the basis of measured data