749 research outputs found
Effects of electron-phonon interactions on the electron tunneling spectrum of PbS quantum dots
We present a tunnel spectroscopy study of single PbS Quantum Dots (QDs) as
function of temperature and gate voltage. Three distinct signatures of strong
electron-phonon coupling are observed in the Electron Tunneling Spectrum (ETS)
of these QDs. In the shell-filling regime, the degeneracy of the
electronic levels is lifted by the Coulomb interactions and allows the
observation of phonon sub-bands that result from the emission of optical
phonons. At low bias, a gap is observed in the ETS that cannot be closed with
the gate voltage, which is a distinguishing feature of the Franck-Condon (FC)
blockade. From the data, a Huang-Rhys factor in the range is
obtained. Finally, in the shell tunneling regime, the optical phonons appear in
the inelastic ETS .Comment: 5 pages, 5 figure
Glass transition in self organizing cellular patterns
We have considered the dynamical evolution of cellular patterns controlled by
a stochastic Glauber process determined by the deviations of local cell
topology from that of a crystalline structure. Above a critical temperature
evolution is towards a common equilibrium state from any initial configuration,
but beneath this temperature there is a dynamical phase transition, with a
start from a quasi-random state leading to non-equilibrium glassy freezing
whereas an ordered start rests almost unchanged. A temporal persistence
function decays exponentially in the high temperature equilibrating state but
has a characteristic slow non-equilibrium aging-like behaviour in the low
temperature glassy phase.Comment: Added references, text minor change
Effect of short range order on electronic and magnetic properties of disordered Co based alloys
We here study electronic structure and magnetic properties of disordered CoPd
and CoPt alloys using Augmented Space Recursion technique coupled with the
tight-binding linearized muffin tin orbital (TB-LMTO) method. Effect of short
range ordering present in disordered phase of alloys on electronic and magnetic
properties has been discussed. We present results for magnetic moments, Curie
temperatures and electronic band energies with varying degrees of short range
order for different concentrations of Co and try to understand and compare the
magnetic properties and ordering phenomena in these systems.Comment: 15 pages,17 postscript figures,uses own style file
Autocorrelation analysis for the unbiased determination of power-law exponents in single-quantum-dot blinking
We present an unbiased and robust analysis method for power-law blinking
statistics in the photoluminescence of single nano-emitters, allowing us to
extract both the bright- and dark-state power-law exponents from the emitters'
intensity autocorrelation functions. As opposed to the widely-used threshold
method, our technique therefore does not require discriminating the emission
levels of bright and dark states in the experimental intensity timetraces. We
rely on the simultaneous recording of 450 emission timetraces of single
CdSe/CdS core/shell quantum dots at a frame rate of 250 Hz with single photon
sensitivity. Under these conditions, our approach can determine ON and OFF
power-law exponents with a precision of 3% from a comparison to numerical
simulations, even for shot-noise-dominated emission signals with an average
intensity below 1 photon per frame and per quantum dot. These capabilities pave
the way for the unbiased, threshold-free determination of blinking power-law
exponents at the micro-second timescale
Topological correlations and asymptotic freedom in cellular aggregates
In random cellular systems, both observation and maximum entropy inference
give a specific form to the topological pair correlation: it is bi-affine in
the cells number of edges with coefficients depending on the distance between
the two cells of the pair. Assuming this form for the pair correlations, we
make explicit the conditions of statistical independence at large distance.
When, on average, the defects do not contribute, the layer population and the
enclosed topological charge both increase polynomially with distance. In
dimension 2, the exponent of the leading terms depend on sum rules satisfied,
or not, by the maximum entropy coefficients.Comment: Available online at http://www.sciencedirect.co
Strong Purcell effect observed in single thick shell CdSe/CdS nanocrystals coupled to localized surface plasmons
High quality factor dielectric cavities designed to a nanoscale accuracy are
mostly used to increase the spontaneous emission rate of a single emitter. Here
we show that the coupling, at room temperature, between thick shell CdSe/CdS
nanocrystals and random metallic films offers a very promising alternative
approach. Optical modes confined at the nanoscale induce strong Purcell factors
reaching values as high as 60. Moreover the quantum emission properties can be
tailored: strong antibunching or radiative biexcitonic cascades can be obtained
with high photon collection efficiency and extremely reduced blinking.Comment: 16 pages, 7 figure
Electron and hole g-factors and spin dynamics of negatively charged excitons in CdSe/CdS colloidal nanoplatelets with thick shells
We address spin properties and spin dynamics of carriers and charged excitons
in CdSe/CdS colloidal nanoplatelets with thick shells. Magneto-optical studies
are performed by time-resolved and polarization-resolved photoluminescence,
spin-flip Raman scattering and picosecond pump-probe Faraday rotation in
magnetic fields up to 30 T. We show that at low temperatures the nanoplatelets
are negatively charged so that their photoluminescence is dominated by
radiative recombination of negatively charged excitons (trions). Electron
g-factor of 1.68 is measured and heavy-hole g-factor varying with increasing
magnetic field from -0.4 to -0.7 is evaluated. Hole g-factors for
two-dimensional structures are calculated for various hole confining potentials
for cubic- and wurtzite lattice in CdSe core. These calculations are extended
for various quantum dots and nanoplatelets based on II-VI semiconductors. We
developed a magneto-optical technique for the quantitative evaluation of the
nanoplatelets orientation in ensemble
Towards precision medicine:What are the stratification hypotheses to identify homogeneous inflammatory subgroups
Diverse lines of research testify a link, presumably causal, between immune dysregulation and the development, course and clinical outcome of psychiatric disorders. However, there is a large heterogeneity among the patients? individual immune profile and this heterogeneity prevents the development of precise diagnostic tools and the identification of therapeutic targets. The aim of this review was to delineate possible subgroups of patients on the basis of clinical dimensions, investigating whether they could lead to particular immune signatures and tailored treatments. We discuss six clinical entry points; genetic liability to immune dysregula-tion, childhood maltreatment, metabolic syndrome, cognitive dysfunction, negative symptoms and treatment resistance. We describe the associated immune signature and outline the effects of anti-inflammatory drugs so far. Finally, we discuss advantages of this approach, challenges and future research directions. (c) 2021 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/
Addressing the exciton fine structure in colloidal nanocrystals: the case of CdSe nanoplatelets
We study the band-edge exciton fine structure and in particular its
bright-dark splitting in colloidal semiconductor nanocrystals by four different
optical methods based on fluorescence line narrowing and time-resolved
measurements at various temperatures down to 2 K. We demonstrate that all these
methods provide consistent splitting values and discuss their advances and
limitations. Colloidal CdSe nanoplatelets with thicknesses of 3, 4 and 5
monolayers are chosen for experimental demonstrations. The bright-dark
splitting of excitons varies from 3.2 to 6.0 meV and is inversely proportional
to the nanoplatelet thickness. Good agreement between experimental and
theoretically calculated size dependence of the bright-dark exciton slitting is
achieved. The recombination rates of the bright and dark excitons and the
bright to dark relaxation rate are measured by time-resolved techniques
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