Understanding The Low Temperature Electrical Propertiesof Nanocrystalline Sno2 For Gas Sensor Applications

Nanocrystalline metal/metal oxide is an important class of transparent and electronic materials due to its potential use in many applications, including gas sensors. At the nanoscale, many of the phenomena observed that give nanocrystalline semiconducting oxide enhanced performance as a gas sensor material over other conventional engineering materials is still poorly understood. This study is aimed at understanding the low temperature electrical and chemical properties of nanocrystalline SnO2 that makes it suitable for room temperature gas detectors. Studies were carried out in order to understand how various synthesis methods affect the surfaces on the nano-oxides, interactions of a target gas (in this study hydrogen) with different surface species, and changes in the electrical properties as a function of dopants and grain size. A correlation between the surface reactions and the electrical response of doped nanocrystalline metal-oxide-semiconductors exposed to a reducing gas is established using Fourier Transform Infrared (FTIR) Spectroscopy attached to a specially built custom designed catalytic cell. First principle calculations of oxygen vacancy concentrations from absorbance spectra are presented. FTIR is used for effectively screening of these nanostructures for gas sensing applications. The effect of processing temperature on the microstructural evolution and on the electronic properties of nanocrystalline trivalent doped-SnO2 is also presented. This study includes the effect of dopants (In and Ce) on the growth of nano-SnO2, as well as their effects on the electronic properties and gas sensor behavior of the nanomaterial at room temperature. Band bending affects are also investigated for this system and are related to enhanced low temperature gas sensing. The role and importance of oxygen vacancies in the electronic and chemical behavior of surface modified nanocrystalline SnO2 are explored in this study. A generalized explanation for the low temperature gas sensor behavior of nanocrystalline oxide is presented that can be generalized to other nano-oxide systems and be useful in specific engineering of other nanomaterials. Deeper understanding of how nano-oxides react chemically and electronically would be extremely beneficial to issues present in current low cost, low temperature sensor technology. Ability to exactly monitor and then engineer the chemistry of nanostructures in the space charge region as well as the surface is also of great significance. Knowledge of the mechanisms responsible for enhanced sensor response in this material system could viably be applied to other material systems for sensor applications

Hydrogen-discriminating nanocrystalline doped-tin-oxide room-temperature microsensor

Highly hydrogen (H-2)-selective [relative to carbon monoxide (CO)] sensor, operating at room temperature, has been fabricated using the micronanointegration approach involving the deposition of the nanocrystalline indium oxide (In2O3)-doped tin oxide (SnO2) thin film on microelectromechanical systems device. The present microsensor exhibits high room-temperature sensitivity towards H-2 (S=12 700); however, it is insensitive to CO at room temperature. In view of the different gas selectivity mechanisms proposed in the literature, it is deduced that the In2O3 doping, the presence of InSn4 phase, the low operating temperature (room temperature), the mesostructure, the small sizes of H-2 and H2O molecules, the bulky intermediate and final reaction products for CO, and the electrode placement at the bottom are the critical parameters, which significantly contribute to the high room-temperature H-2 selectivity of the present microsensor over CO. The constitutive equation for the gas sensitivity of the semiconductor oxide thin-film sensor, proposed recently by the authors, has been modified to qualitatively explain the observed H-2 selectivity behavior

ALMA 400 pc Imaging of a z = 6.5 Massive Warped Disk Galaxy

© 2023. The Author(s). Published by the American Astronomical Society. This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY), https://creativecommons.org/licenses/by/4.0/We present 0.″075 (≈400 pc) resolution Atacama Large Millimeter/submillimeter Array (ALMA) observations of the [C ii] and dust continuum emission from the host galaxy of the z = 6.5406 quasar, P036+03. We find that the emission arises from a thin, rotating disk with an effective radius of 0.″21 (1.1 kpc). The velocity dispersion of the disk is consistent with a constant value of 66.4 ± 1.0 km s−1, yielding a scale height of 80 ± 30 pc. The [C ii] velocity field reveals a distortion that we attribute to a warp in the disk. Modeling this warped disk yields an inclination estimate of 40.°4 ± 1.°3 and a rotational velocity of 116 ± 3 km s−1. The resulting dynamical mass estimate of (1.96 ± 0.10) × 1010 M ⊙ is lower than previous estimates, which strengthens the conclusion that the host galaxy is less massive than expected based on local scaling relations between the black hole mass and the host galaxy mass. Using archival MUSE Lyα observations, we argue that counterrotating halo gas could provide the torque needed to warp the disk. We further detect a region with excess (15σ) dust continuum emission, which is located 1.3 kpc northwest of the galaxy’s center and is gravitationally unstable (Toomre Q < 0.04). We posit this is a star-forming region whose formation was triggered by the warp because the region is located within a part of the warped disk where gas can efficiently lose angular momentum. The combined ALMA and MUSE imaging provides a unique view of how gas interactions within the disk–halo interface can influence the growth of massive galaxies within the first billion years of the Universe.Peer reviewe

Increase Postpartum Gestational Diabetes Screening

Introduction: Diabetic women did not get follow up screening after delivery. Nurses are finding a way to screen more women

Effects of increasing the affinity of CarD for RNA polymerase on Mycobacterium tuberculosis growth, rRNA transcription, and virulence

CarD is an essential RNA polymerase (RNAP) interacting protein in Mycobacterium tuberculosis that stimulates formation of RNAP-promoter open complexes. CarD plays a complex role in M. tuberculosis growth and virulence that is not fully understood. Therefore, to gain further insight into the role of CarD in M. tuberculosis growth and virulence, we determined the effect of increasing the affinity of CarD for RNAP. Using site-directed mutagenesis guided by crystal structures of CarD bound to RNAP, we identified amino acid substitutions that increase the affinity of CarD for RNAP. Using these substitutions, we show that increasing the affinity of CarD for RNAP increases the stability of the CarD protein in M. tuberculosis. In addition, we show that increasing the affinity of CarD for RNAP increases the growth rate in M. tuberculosis without affecting 16S rRNA levels. We further show that increasing the affinity of CarD for RNAP reduces M. tuberculosis virulence in a mouse model of infection despite the improved growth rate in vitro. Our findings suggest that the CarD-RNAP interaction protects CarD from proteolytic degradation in M. tuberculosis, establish that growth rate and rRNA levels can be uncoupled in M. tuberculosis and demonstrate that the strength of the CarD-RNAP interaction has been finely tuned to optimize virulence. IMPORTANCE Mycobacterium tuberculosis, the causative agent of tuberculosis, remains a major global health problem. In order to develop new strategies to battle this pathogen, we must gain a better understanding of the molecular processes involved in its survival and pathogenesis. We have previously identified CarD as an essential transcriptional regulator in mycobacteria. In this study, we detail the effects of increasing the affinity of CarD for RNAP on transcriptional regulation, CarD protein stability, and virulence. These studies expand our understanding of the global transcription regulator CarD, provide insight into how CarD activity is regulated, and broaden our understanding of prokaryotic transcription

Molecular dissection of RbpA-mediated regulation of fidaxomicin sensitivity in mycobacteria

RNA polymerase (RNAP) binding protein A (RbpA) is essential for mycobacterial viability and regulates transcription initiation by increasing the stability of the RNAP-promoter open complex (R

Domains within RbpA serve specific functional roles that regulate the expression of distinct mycobacterial gene subsets

The RNA polymerase (RNAP) binding protein A (RbpA) contributes to the formation of stable RNAP-promoter open complexes (R

Natural Sciences at Parkland College - Fall 2017

The Parkland College Natural Sciences Department Newsletter for Fall 2017 -- this issue features an article on IR cameras, use of display case, engaging students outside the classroom with the Astronomy Club and the Parkland Science Club, the solar eclipse, updates from the professional development subcommittee for faculty, summaries from events and meetings, a report on Phenotypic Pasticity Research Experience for Community College Students (PRECS) first summer, and a special feature from former professor Rich Blazier, with a special feature on the history of the Natural Sciences Department