104 research outputs found
Frequency Dependence of Aging, Rejuvenation and Memory in a disordered ferroelectric
We characterize in details the aging properties of the ferroelectric phase of
K Ta_{1-x} Nb_x O_3 (KTN), where both rejuvenation and (partial) memory are
observed. In particular, we carefully examine the frequency dependence of
several quantities that characterize aging, rejuvenation and memory. We find a
marked subaging behaviour, with an a.c. dielectric susceptiblity scaling as
, where is the waiting time. We suggest an
interpretation in terms of pinned domain walls, much along the lines proposed
for aging in a disordered ferromagnet, where both domain wall reconformations
and overall (cumulative) domain growth are needed to rationalize the
experimental findings.Comment: submitted to EPJ
When Mass Spectrometry Meets Nanoparticles. Weighing, Manipulating and Fragmenting Single Nanoparticles in The Gas Phase
A new mass spectrometer based on charge detection has been developed. It enables the determination of mass distribution of various macromolecules and nanoparticles. By using an ion trap coupled to a CO2 laser, photoinduced dissociation of such macroions can be studied at the single ion level giving uniquely access to intrinsic features such as fragmentation patterns and unimolecular dissociation activation energy
When Mass Spectrometry Meets Nanoparticles. Weighing, Manipulating and Fragmenting Single Nanoparticles in The Gas Phase
A new mass spectrometer based on charge detection has been developed. It enables the determination of mass distribution of various macromolecules and nanoparticles. By using an ion trap coupled to a CO2 laser, photoinduced dissociation of such macroions can be studied at the single ion level giving uniquely access to intrinsic features such as fragmentation patterns and unimolecular dissociation activation energy
Electrodynamics of Amorphous Media at Low Temperatures
Amorphous solids exhibit intrinsic, local structural transitions, that give
rise to the well known quantum-mechanical two-level systems at low
temperatures. We explain the microscopic origin of the electric dipole moment
of these two-level systems: The dipole emerges as a result of polarization
fluctuations between near degenerate local configurations, which have nearly
frozen in at the glass transition. An estimate of the dipole's magnitude, based
on the random first order transition theory, is obtained and is found to be
consistent with experiment. The interaction between the dipoles is estimated
and is shown to contribute significantly to the Gr\"{u}neisen parameter anomaly
in low glasses. In completely amorphous media, the dipole moments are
expected to be modest in size despite their collective origin. In partially
crystalline materials, however, very large dipoles may arise, possibly
explaining the findings of Bauer and Kador, J. Chem. Phys. {\bf 118}, 9069
(2003).Comment: Submitted for publication; April 27, 2005 versio
Symmetrical Temperature-Chaos Effect with Positive and Negative Temperature Shifts in a Spin Glass
The aging in a Heisenberg-like spin glass Ag(11 at% Mn) is investigated by
measurements of the zero field cooled magnetic relaxation at a constant
temperature after small temperature shifts . A
crossover from fully accumulative to non-accumulative aging is observed, and by
converting time scales to length scales using the logarithmic growth law of the
droplet model, we find a quantitative evidence that positive and negative
temperature shifts cause an equivalent restart of aging (rejuvenation) in terms
of dynamical length scales. This result supports the existence of a unique
overlap length between a pair of equilibrium states in the spin glass system.Comment: 4 page
Nonlinear acoustic and microwave absorption in glasses
A theory of weakly-nonlinear low-temperature relaxational absorption of
acoustic and electromagnetic waves in dielectric and metallic glasses is
developed. Basing upon the model of two-level tunneling systems we show that
the nonlinear contribution to the absorption can be anomalously large. This is
the case at low enough frequencies, where freqeuency times the minimal
relaxation time for the two-level system are much less than one. In dielectric
glasses, the lowest-order nonlinear contribution is proportional to the wave's
intensity. It is negative and exhibits anomalous frequency and temperature
dependencies. In metallic glasses, the nonlinear contribution is also negative,
and it is proportional to the square root of the wave's intensity and to the
frequency. Numerical estimates show that the predicted nonlinear contribution
can be measured experimentally
Mean-field theory of temperature cycling experiments in spin-glasses
We study analytically the effect of temperature cyclings in mean-field
spin-glasses. In accordance with real experiments, we obtain a strong
reinitialization of the dynamics on decreasing the temperature combined with
memory effects when the original high temperature is restored. The same
calculation applied to mean-field models of structural glasses shows no such
reinitialization, again in accordance with experiments. In this context, we
derive some relations between experimentally accessible quantities and propose
new experimental protocols. Finally, we briefly discuss the effect of field
cyclings during isothermal aging.Comment: Some misprints corrected, references updated, final version to apper
in PR
The Energetics of Li Off-Centering in KLiTaO; First Principles Calculations
KLiTaO (KLT) solid solutions exhibit a variety of
interesting physical phenomena related to large displacements of Li-ions from
ideal perovskite A-site positions. First-principles calculations for KLT
supercells were used to investigate these phenomena. Lattice dynamics
calculations for KLT exhibit a Li off-centering instability. The energetics of
Li-displacements for isolated Li-ions and for Li-Li pairs up to 4th neighbors
were calculated. Interactions between nearest neighbor Li-ions, in a Li-Li
pair, strongly favor ferroelectric alignment along the pair axis. Such Li-Li
pairs can be considered "seeds" for polar nanoclusters in KLT.
Electrostriction, local oxygen relaxation, coupling to the KT soft-mode, and
interactions with neighboring Li-ions all enhance the polarization from Li
off-centering. Calculated hopping barriers for isolated Li-ions and for nearest
neighbor Li-Li pairs are in good agreement with Arrhenius fits to experimental
dielectric data.Comment: 14 pages including 10 figures. To Physical Review B. Replaced after
corrections due to referees' remark
Nonlinear acoustic and microwave absorption in disordered semiconductors
Nonlinear hopping absorption of ultrasound and electromagnetic waves in
amorphous and doped semiconductors is considered. It is shown that even at low
amplitudes of the electric (or acoustic) field the nonlinear corrections to the
relaxational absorption appear anomalously large. The physical reason for such
behavior is that the nonlinear contribution is dominated by a small group of
close impurity pairs having one electron per pair. Since the group is small, it
is strongly influenced by the field. An external magnetic field strongly
influences the absorption by changing the overlap between the pair components'
wave functions. It is important that the influence is substantially different
for the linear and nonlinear contributions. This property provides an
additional tool to extract nonlinear effects.Comment: correction : misspelled name in references correcte
Numerical Study of Aging in the Generalized Random Energy Model
Magnetizations are introduced to the Generalized Random Energy Model (GREM)
and numerical simulations on ac susceptibility is made for direct comparison
with experiments in glassy materials. Prominent dynamical natures of spin
glasses, {\it i.e.}, {\em memory} effect and {\em reinitialization}, are
reproduced well in the GREM. The existence of many layers causing continuous
transitions is very important for the two natures. Results of experiments in
other glassy materials such as polymers, supercooled glycerol and orientational
glasses, which are contrast to those in spin glasses, are interpreted well by
the Single-layer Random Energy Model.Comment: 8 pages, 9 figures, to be submitted to J. Phys. Soc. Jp
- …