108 research outputs found
Global thermodynamic behaviour of supercritical fluids: example of methane and ethane
Do to the fluctuations associated with the critical region of fluids. The behavior of thermodynamic properties these can not be predicted by mean field theories. To do so, a global equation of state based on the crossover model has been used. This equation of state is formulated on the basis of comparison of selected measurements of pressure-density-temperature data, isochoric and isobaric heat capacity of fluids.The model can be applied in a wide range of temperatures and densities around the critical point for ethane and methane. It is found that the developed model represents most of the reliable experimental data accurately
Thermal conductivity of mixtures in the dense gaseous state: The methane-carbon tetrafluoride system
Vapour Liquid Equilibria for Pure Fluids from the Perturbation Theory of the Kihara Molecule Systems
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