10,781 research outputs found
How many metals does it take to fix N2? A mechanistic overview of biological nitrogen fixation
During the process of biological nitrogen fixation, the enzyme nitrogenase catalyzes the ATP-dependent reduction of dinitrogen to ammonia. Nitrogenase consists of two component metalloproteins, the iron (Fe) protein and the molybdenum-iron (MoFe) protein; the Fe protein mediates the coupling of ATP hydrolysis to interprotein electron transfer, whereas the active site of the MoFe protein contains the polynuclear FeMo cofactor, a species composed of seven iron atoms, one molybdenum atom, nine sulfur atoms, an interstitial light atom, and one homocitrate molecule. This Perspective provides an overview of biological nitrogen fixation and introduces three contributions to this special feature that address central aspects of the mechanism and assembly of nitrogenase
Nitrogenase: A nucleotide-dependent molecular switch
In the simplest terms, the biological nitrogen cycle is the reduction of atmospheric dinitrogen (N2) to ammonia with the subsequent reoxidation ammonia to dinitrogen (1). At the reduction level of ammonia, nitrogen incorporated into precursors for biological macromolecules such as proteins and nucleic acids. Reoxidation of ammonia to dinitrogen ("denitrification") by a variety of microbes (by way of nitrite and other oxidation levels of nitrogen) leads to the depletion of the "fixed," biologically usable, nitrogen pool. Besides the relatively small contribution from commercial ammonical fertilizer production, replenishing of the nitrogen pool falls mainly to a limited number of physiologically diverse microbes (e.g. eubacteria and archaebacteria; free-living and symbiotic; aerobic and anaerobic) that contain the nitrogenase enzyme system
Flow visualization of a rocket injector spray using gelled propellant simulants
A study was conducted at NASA-Lewis to compare the atomization characteristics of gelled and nongelled propellant simulants. A gelled propellant simulant composed of water, sodium hydroxide, and an acrylic acid polymer resin (as the gelling agent) was used to simulate the viscosity of an aluminum/PR-1 metallized fuel gel. Water was used as a comparison fluid to isolate the rheological effects of the water-gel and to simulate nongelled RP-1. The water-gel was injected through the central orifice of a triplet injector element and the central post of a coaxial injector element. Nitrogen gas flowed through the outer orifices of the triplet injector element and through the annulus of the coaxial injector element and atomized the gelled and nongelled liquids. Photographs of the water-gel spray patterns at different operating conditions were compared with images obtained using water and nitrogen. A laser light was used for illumination of the sprays. The results of the testing showed that the water sprays produced a finer and more uniform atomization than the water-gel sprays. Rheological analysis of the water-gel showed poor atomization caused by high viscosity of water-gel delaying the transition to turbulence
Sharing Ownership via Employee Stock Ownership
Broad-based stock options, Employee ownership, Incentive compensation,
On the Survivability and Metamorphism of Tidally Disrupted Giant Planets: the Role of Dense Cores
A large population of planetary candidates in short-period orbits have been
found through transit searches. Radial velocity surveys have also revealed
several Jupiter-mass planets with highly eccentric orbits. Measurements of the
Rossiter-McLaughlin effect indicate some misaligned planetary systems. This
diversity could be induced by post-formation dynamical processes such as
planet-planet scattering, the Kozai effect, or secular chaos which brings
planets to the vicinity of their host stars. In this work, we propose a novel
mechanism to form close-in super-Earths and Neptune-like planets through the
tidal disruption of giant planets as a consequence of these dynamical
processes. We model the core-envelope structure of giant planets with composite
polytropes. Using three-dimensional hydrodynamical simulations of close
encounters between planets and their host stars, we find that the presence of a
core with a mass more than ten Earth masses can significantly increase the
fraction of envelope which remains bound to it. After the encounter, planets
with cores are more likely to be retained by their host stars in contrast with
previous studies which suggested that coreless planets are often ejected. As a
substantial fraction of their gaseous envelopes is preferentially lost while
the dense incompressible cores retain most of their original mass, the
resulting metallicity of the surviving planets is increased. Our results
suggest that some gas giant planets can be effectively transformed into either
super-Earths or Neptune-like planets after multiple close stellar passages.
Finally, we analyze the orbits and structure of known planets and Kepler
candidates and find that our model is capable producing some of the
shortest-period objects.Comment: Accepted for publication in ApJ. 15 pages, 9 figures, 3 tables. Two
movies at http://youtu.be/jHxPKAEgFic and http://youtu.be/QXqkS0vDi5
The Challenge to Catholic Teacher Education in Scotland
Maintaining a strong sense of religious purpose is a challenge facing private education. Institutions of higher learning confront special challenges when addressing issues of religious identity, governance, and mission. Scotland’s Catholic community encountered a major challenge when the only teacher education college for those aspiring to teach in Catholic schools, St. Andrew’s College, began merger talks with the University of Glasgow, an institution with historical ties to the Church of Scotland. After reviewing the historical context of the merger discussions, the authors provide a helpful analysis of the process and offer a four-fold model of analysis for other institutions in similar transitional stages
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