Nonadiabatic simulation study of photoisomerization of azobenzene: Detailed mechanism and load-resisting capacity

Nonadiabatic dynamical simulations were carried out to study cis-to-trans isomerization of azobenzene under laser irradiation and/or external mechanical loads. We used a semiclassical electron-radiation-ion dynamics method that is able to describe the coevolution of the structural dynamics and the underlying electronic dynamics in a real-time manner. It is found that azobenzene photoisomerization occurs predominantly by an out-of-plane rotation mechanism even under a nontrivial resisting force of several tens of piconewtons. We have repeated the simulations systematically for a broad range of parameters for laser pulses, but could not find any photoisomerization event by a previously suggested in-plane inversion mechanism. The simulations found that the photoisomerization process can be held back by an external resisting force of 90 - 200 pN depending on the frequency and intensity of the lasers. This study also found that a pure mechanical isomerization is possible from the cis state if the azobenzene molecule is stretched by an external force of 1250 -1650 pN. Remarkably, the mechanical isomerization first proceeds through a mechanically activated inversion, and then is diverted to an ultrafast downhill rotation that accomplishes the isomerization. Implications of these findings to azobenzene-based nanomechanical devices are discussed.Comment: 9 printed page

The effect of low-molecular-weight organic-acids (LMWOAs) on treatment of chromium-contaminated soils by compost-phytoremediation: Kinetics of the chromium release and fractionation

A soil-plant biological system was developed from chromium (Cr) polluted soil treated by the compost-phytoremediation method. The transformation and migration of the Cr in this system is comprehensively studied in this research. The results illustrated that the co-composting treatment can reduce the Cr availability from 39% (F1 was about 31% of total, F2 was about 8% of total) to less than 2% by stabilizing the Cr. However, herbaceous plants can accumulate the concentrations of Cr from 113.8 to 265.2 mg/kg in the two crops, even though the concentration of soluble Cr in the substrate soil was below 0.1 mg/L. Cr can be assimilated and easily transferred in the tissues of plants because the low molecular- weight organic-acids (LMWOAs) derived from the plant root increase the bioavailability of Cr. The amount of extracted Cr dramatically increased when the organic acids were substituted in this order: citric acid > malic acid > tartaric acid > oxalic acid > acetic acid. On average the maximum(147.4 mg/kg) and the minimum(78.75 mg/kg) Cr were extracted by 20 mmol/L citric acid and acetic acid, respectively. The desorption of Cr in different acid solutions can be predicted by the pseudo second-order kinetics. The exchangeable Cr, carbonate-bound Cr, and residual Cr decreased, while Fe-Mn oxide bound Cr and organic bound Cr increased in the soil solid phase. According to the experimental results, the organic acids will promote the desorption and chelation processes of Cr, leading to the remobilization of Cr in the soil. (C) 2017 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V

The effect of low-molecular-weight organic-acids (LMWOAs) on treatment of chromium-contaminated soils by compost-phytoremediation: Kinetics of the chromium release and fractionation

A soil-plant biological system was developed from chromium (Cr) polluted soil treated by the compost-phytoremediation method. The transformation and migration of the Cr in this system is comprehensively studied in this research. The results illustrated that the co-composting treatment can reduce the Cr availability from 39% (F1 was about 31% of total, F2 was about 8% of total) to less than 2% by stabilizing the Cr. However, herbaceous plants can accumulate the concentrations of Cr from 113.8 to 265.2 mg/kg in the two crops, even though the concentration of soluble Cr in the substrate soil was below 0.1 mg/L. Cr can be assimilated and easily transferred in the tissues of plants because the low molecular- weight organic-acids (LMWOAs) derived from the plant root increase the bioavailability of Cr. The amount of extracted Cr dramatically increased when the organic acids were substituted in this order: citric acid > malic acid > tartaric acid > oxalic acid > acetic acid. On average the maximum(147.4 mg/kg) and the minimum(78.75 mg/kg) Cr were extracted by 20 mmol/L citric acid and acetic acid, respectively. The desorption of Cr in different acid solutions can be predicted by the pseudo second-order kinetics. The exchangeable Cr, carbonate-bound Cr, and residual Cr decreased, while Fe-Mn oxide bound Cr and organic bound Cr increased in the soil solid phase. According to the experimental results, the organic acids will promote the desorption and chelation processes of Cr, leading to the remobilization of Cr in the soil. (C) 2017 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V

Remediation of Cr(VI)-contaminated soil with co-composting of three different biomass solid wastes

This study was focused on co-composting of Cr(VI)-contaminated soil with three different biomass solid wastes for immobilizing Cr(VI).</p

The effect of low-molecular-weight organic-acids (LMWOAs) on treatment of chromium-contaminated soils by compost-phytoremediation: Kinetics of the chromium release and fractionation

A soil-plant biological system was developed from chromium (Cr) polluted soil treated by the compost-phytoremediation method. The transformation and migration of the Cr in this system is comprehensively studied in this research. The results illustrated that the co-composting treatment can reduce the Cr availability from 39% (F1 was about 31% of total, F2 was about 8% of total) to less than 2% by stabilizing the Cr. However, herbaceous plants can accumulate the concentrations of Cr from 113.8 to 265.2 mg/kg in the two crops, even though the concentration of soluble Cr in the substrate soil was below 0.1 mg/L. Cr can be assimilated and easily transferred in the tissues of plants because the low molecular- weight organic-acids (LMWOAs) derived from the plant root increase the bioavailability of Cr. The amount of extracted Cr dramatically increased when the organic acids were substituted in this order: citric acid &gt; malic acid &gt; tartaric acid &gt; oxalic acid &gt; acetic acid. On average the maximum(147.4 mg/kg) and the minimum(78.75 mg/kg) Cr were extracted by 20 mmol/L citric acid and acetic acid, respectively. The desorption of Cr in different acid solutions can be predicted by the pseudo second-order kinetics. The exchangeable Cr, carbonate-bound Cr, and residual Cr decreased, while Fe-Mn oxide bound Cr and organic bound Cr increased in the soil solid phase. According to the experimental results, the organic acids will promote the desorption and chelation processes of Cr, leading to the remobilization of Cr in the soil. (C) 2017 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.</p

On-Orbit Vicarious Radiometric Calibration and Validation of ZY1-02E Thermal Infrared Sensor

The ZY1-02E satellite carrying a thermal infrared sensor was successfully launched from the Taiyuan Satellite Launch Center on 26 December 2021. The quantitative characteristics of this thermal infrared camera, for use in supporting applications, were acquired as part of an absolute radiometric calibration campaign performed at the Ulansuhai Nur and Baotou calibration site (Inner Mongolia, July 2022). In this paper, we propose a novel on-orbit absolute radiometric calibration technique, based on multiple ground observations, that considers the radiometric characteristics of the ZY1-02E thermal infrared sensor. A variety of natural surface objects were selected as references, including bodies of water, bare soil, a desert in Kubuqi, and sand and vegetation at the Baotou calibration site. During satellite overpass, the 102F Fourier transform thermal infrared spectrometer and the SI-111 infrared temperature sensor were used to measure temperature and ground-leaving radiance for these surface profiles. Atmospheric water vapor, aerosol optical depth, and ozone concentration were simultaneously obtained from the CIMEL CE318 Sun photometer and the MICROTOP II ozonometer. Atmospheric profile information was acquired from radiosonde instruments carried by sounding balloons. Synchronous measurements of atmospheric parameters and ECMWF ERA5 reanalysis data were then combined and input to an atmospheric radiative transfer model (MODTRAN6.0) used to calculate apparent radiance. Calibration coefficients were determined from the measured apparent radiance and satellite-observed digital number (DN), for use in calculating the on-orbit observed radiance of typical surface objects. These values were then compared with the apparent radiance of each object, using radiative transfer calculations to evaluate the accuracy of on-orbit absolute radiometric calibration. The results show that the accuracy of this absolute radiometric calibration is better than 0.6 K. This approach allows the thermal infrared channel to be unrestricted by the limitations of spectrum matching between a satellite and field measurements, with strong applicability to various types of calibration sites