Adsorption and recovery of phosphate from aqueous solution by the construction and demolition wastes sludge and its potential use as phosphate-based fertiliser

This study aimed to investigate phosphate removal from aqueous effluents by an inorganic sludge from the inert part of construction and demolition wastes (CSW) as adsorbent. It is also discussed the application of the loaded P adsorbent as potential fertiliser. The CSW was also thermally treated at 800¿°C for 2¿h (CSW-T), and its influence in the P removal was also investigated. The characterisation techniques highlighted low porosity on CSW and CSW-T adsorbents and that they are mainly formed by oxides which could enhance the P uptake and recovery. In pH experiments, P adsorption increased as initial pH increased, at pH higher than 7.8 the P removal sharply increased due to the formation of calcium phosphate precipitate. The mechanism of the P adsorption onto CSW indicated that the process was mainly controlled by chemical bonding or chemisorption. The results showed that CSW-T was more effective for P removal in comparison to CSW based on the Liu isotherm, the maximum sorption capacity attained was 24.04 (CSW) and 57.64¿mg¿g-1 (CSW-T). Based on the Avrami’s kinetic models, the time for attaining 95% of saturation was 212.6 (CSW), and 136.6¿min (CSW-T). CSW and CSW-T showed the highest phosphate-removal performance among many adsorbents found in the literature; therefore, this kind of waste can be used widely as an inexpensive phosphate-recovery adsorbent. Besides, the P loaded adsorbents could be used as potential fertilisers which could be an interesting and efficient way of reuse for this waste.Peer ReviewedPostprint (published version

Effect of concrete carbonation on phosphate removal through adsorption process and its potential application as fertilizer

© 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/Concrete slurry is an abundant, cheap, and commonly found waste all over the world where construction activities take place; concrete slurry, which is rich in calcium and metallic oxides, could be successfully employed in the phosphate (P) removal from aqueous media. For the first time, the effect of the carbonation process on concrete adsorbent properties and how it can influence on the removal of phosphate ions in aqueous media are studied. Besides, the potential applicability of P loaded concrete adsorbent is also evaluated. The results showed that a non-carbonated sample was more effective in the P removal, due to higher releasing of calcium (Ca2+) in comparison to carbonated sample. The dissolved Ca2+ from the dissolution of calcium hydroxide (Ca(OH)2), calcium carbonate (CaCO3), and calcium oxide (CaO) are preferably precipitated by phosphates in high pH solution, reflecting in a high initial adsorption rate. General order kinetic and Liu isotherm provided better-fitting models for the adsorption behavior of P onto both non-carbonated and carbonated concrete samples. Phosphate removal was mainly ruled by chemical adsorption through inner-sphere complexation and P precipitation on the surface of the adsorbent containing Ca2+ as an essential ion in the adsorption mechanism. Compared with other phosphate adsorbents, both non-carbonated and carbonated concrete showed to be economical and efficient adsorbent. The non-carbonated sample gave a high adsorption capacity of P (47.6 mg g-1) and presenting fast and high initial adsorption, reaching 72% of P removal within 5 min (min) at 22 °C, while carbonated showed adsorption capacity of 30.6 mg g-1, at the same experimental conditions. Therefore, concrete slurries can be used widely as an inexpensive phosphate-recovery adsorbent. Besides, the application of these P loaded waste as potential fertilizers in soil can be an exciting and environmentally approach for reusing this solid-waste. The environmental analysis highlighted that the adsorbents did not leach out chemicals above the allowable limits, preconized by The Food and Agriculture Organization of the United Nations (FAO) for irrigation waters. However, aspects related to monitoring the presence and mobility of heavy metals on soil must be better addressed and monitored.Peer ReviewedPostprint (author's final draft