2 research outputs found
Compositional nanodomain formation in hybrid formate perovskites
We report the synthesis and structural characterisation of three mixed-metal
formate perovskite families [C(NH)]MCu(HCOO) (M = Mn,
Zn, Mg). Using a combination of infrared spectroscopy, non-negative matrix
factorization, and reverse Monte Carlo refinement, we show that the Mn- and
Zn-containing compounds support compositional nanodomains resembling the polar
nanoregions of conventional relaxor ferroelectrics. The M = Mg family exhibits
a miscibility gap that we suggest reflects the limiting behaviour of nanodomain
formation.Comment: 4 pages, 3 figure