Piezoresistive behaviours of carbon black cement-based sensors with layer-distributed conductive rubber fibres

© 2019 Conductive rubber fibres filled carbon black (CB)/cementitious composites were developed to achieve the cement-based sensors with excellent piezoresistivity in this study. Ameliorations on the conductivity and piezoresistive sensitivity of CB filled composites were mainly explored with conductive rubber fibres embedded. Their compressive strengths were investigated to evaluate the practical application possibility. The results indicated that the composites with CB content <4.0 wt% possessed acceptable compressive strengths. In terms of conductivity and piezoresistivity, both conductivity and piezoresistivity of composites filled with 0.5 wt% CB increased with the rubber content, and their gauge factor raised to 91 when embedded with 80 rubber fibres (1.27 vol%). Moreover, phenomenon of “piezoresistive percolation” was observed by sharp fractional changes of resistivity for the composites filled with 1.0 wt% CB, where existed highest gauge factor reaching 482 when embedded with same rubber fibres. However, because of the excellent conductivity of 2.0 wt% CB filled composites, the gauge factor firstly increased but then slightly decreased around 100 with increase of rubber fibre content. Overall, conductive rubber fibres can significantly improve the piezoresistivity of CB/cementitious composites by the increased gauge factor

Ethyl 7-(4-bromo­phen­yl)-5-trifluoro­methyl-4,7-dihydro­tetra­zolo[1,5-a]pyrimidine-6-carboxyl­ate

In the title compound, C14H11BrF3N5O2, the pyrimidine ring adopts a flattened envelope conformation with sp 3-hybridized carbon as the flap [deviation = 0.177 (3) Å]. The dihedral angle between tetra­zole and bromo­phenyl rings is 84.3 (1)°. In the crystal, mol­ecules are linked into centrosymmetric dimers by pairs of N—H⋯N hydrogen bonds

5′-Amino-2-oxo-2′,3′-dihydro­spiro­[indoline-3,7′-thieno[3,2-b]pyran]-6′-carbonitrile 1′,1′-dioxide

In the title compound, C15H11N3O4S, the dihedral angle between the mean planes of the dihydro­indol-2-one (r.m.s. deviation = 0.015 Å) and dihydro­thieno[3,2-b]pyran (r.m.s. deviation = 0.011 Å) ring systems is 89.53 (3)°. The crytal packing is consolidated by inter­molecular N—H⋯O and N—H⋯N hydrogen bonds, which link the mol­ecules into a two-dimensional network into sheets lying parallel to (100)

The heme-p53 interaction: Linking iron metabolism to p53 signaling and tumorigenesis

Recently, we reported that heme binds to tumor suppressor p53 protein (TP53, best known as p53) and promotes its nuclear export and cytosolic degradation, whereas iron chelation stabilizes p53 protein and suppresses tumors in a p53-dependent manner. This not only provides mechanistic insights into tumorigenesis associated with iron excess, but also helps guide the administration of chemotherapy based on iron deprivation in the clinic

Propagation of tidal waves up in Yangtze Estuary during the dry season

Tide is one of the most important hydrodynamic driving forces and has unique features in the Yangtze Estuary (YE) due to the complex geometry of third-order bifurcations and four outlets. This paper characterizes the tidal oscillations, tidal dampening, tidal asymmetry, and tidal wave propagation, which provides insights into the response of the estuary to tides during the dry season. The structural components of tidal oscillations are initially attained by tidal analysis. The increasingly richer spectrum inside the estuary shows an energy transfer corresponding to the generation and development of nonlinear overtides and compound tides. A 2-D numerical model is further set up to reproduce tidal dynamics in the estuary. The results show that the estuary is a strongly dissipative estuary with a strong nonlinear phenomenon. Three amplifications are presented in the evolution process of tidal ranges due to the channel convergence. Tidal asymmetry is spatiotemporally characterized by the M-4/M-2 amplitude ratio, the 2M(2)-M-4 phase difference, and the flood-ebb duration-asymmetry parameter, and the estuary tends to be flood-dominant. There exists mimic standing waves with the phase difference of the horizontal and vertical tide close to 90 degrees when tidal wave propagates into the estuary, especially during the neap tide. In addition, the differences in tidal distortion, tidal ranges, and tidal waves along the two routes in the South Branch (S-B) suggest the branched system behaves differently from a single system

5-Amino-7-(3-chloro­phen­yl)-3,7-di­hydro-2H-thieno[3,2-b]pyran-6-carbo­nitrile 1,1-dioxide

The title compound, C14H11ClN2O3S, with fused thiophene and pyran rings, was synthesized via the condensation of dihydro­thio­phen-3(2H)-one 1,1-dioxide and 2-(3-chloro­benz­yl­idene)malononitrile catalysed by triethyl­amine in ethanol. The thio­phene ring adopts an envelope conformation and the pyran ring is planar (r.m.s. deviation = 0.0067 Å). The dihedral angle between the pyran and phenyl rings is 80.8 (1)°. The crystal packing is stabilized by inter­molecular N—H⋯N and N—H⋯O hydrogen bonds in which the cyano N and sulphone O atoms, respectively, acting as acceptors