113 research outputs found
Five-coordinate Schiff base complexes of gallium. Potential catalysts for the copolymerization of carbon dioxide and epoxides
Get PDFNew Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis
No full textThe advent of new infrared sampling accessories has allowed in situ study of organometallic systems under conditions that were previously not readily accessible. The techniques of Cylindrical Internal Reflectance (CIR) and Diffuse Reflectance spectroscopies are described herein. The CIR phenomenon was employed in three different apparatus. Two different high pressure CIR cells were used to study reactions homogeneously catalyzed by [μ-HW_2(CO)_(10)]^-. Low temperature reactions of Mo and W complexes were studied using an ambient pressure CIR cell. The diffuse reflectance technique was employed to study powdered samples of Ru carbonyl complexes supported on Al_2O_3
New Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis
No full textThe advent of new infrared sampling accessories has allowed in situ study of organometallic systems under conditions that were previously not readily accessible. The techniques of Cylindrical Internal Reflectance (CIR) and Diffuse Reflectance spectroscopies are described herein. The CIR phenomenon was employed in three different apparatus. Two different high pressure CIR cells were used to study reactions homogeneously catalyzed by [μ-HW_2(CO)_(10)]^-. Low temperature reactions of Mo and W complexes were studied using an ambient pressure CIR cell. The diffuse reflectance technique was employed to study powdered samples of Ru carbonyl complexes supported on Al_2O_3
A Quest for Polycarbonates Provided via Sustainable Epoxide/CO2 Copolymerization Processes
No full textLigand substitution processes in tetranuclear carbonyl clusters. 3. Molecular structures of Co4(CO)8(.mu.-CO)3[P(C6H5)3] and Co4(CO)7(.mu.-CO)3[P(OCH3)3]2
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A Quest for Polycarbonates Provided via Sustainable Epoxide/CO2 Copolymerization Processes
No full textStudies of the Carbon Dioxide and Epoxide Coupling Reaction in the Presence of Fluorinated Manganese(III) Acacen Complexes: Kinetics of Epoxide Ring-Opening
No full textInfrared intensities of the carbonyl stretching modes and electronic spectra of substituted molybdenum carbonyls
No full textX-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide–CO2 copolymerization process
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