Angular dependence of the emission wavelength in microactivity organic light-emitting diodes

In this work, we have calculated the emission wavelength dependence on the viewing angle for different combinations of metallic mirrors. The dispersion of the optical functions of ten different metals is fully taken into account using Lorentz oscillator model. The metals have been assigned to a function of top (cathode) or bottom (anode) mirror based on their work function. Refractive index dispersion of organic layers, N,N'-disphenyl-N,N'-bis(3-methylphenyl)-1,1'-disphenyl-4,4'-diamine (TPD) and tris (8-hydroxyquinoline) aluminum (emitting layer) is taken into account via Cauchy model. The change of the emission wavelength with angle has been calculated iteratively-to fully take into account wavelength dependence of indices of refraction and phase change. Calculations have been performed for different hole transport materials and different thickness of the emitting layer

Device optimization Based on Electrical and Optical Simulation of Tris(8-hydroxyquinoline) Aluminium Based Microacavity Organic Light Emitting Diode (MOLED)

OLED has emerged as a potential candidate for applications in display devices due to its prominent advantages in size, brightness and wide viewing angle. Following our previous work, where optical analysis of the OLED has been documented1 we present in this work detailed examination optical and electrical analysis of the performance of an OLEDs based on two organic layers: N,N'-di(naphthalene-1-yl)-N,N'-diphenylbenzidine (NPB) as the hole transport layer and tris (8-hydroxyquinoline) aluminium (Alq3) as the emitting layer, and two metallic mirrors. Our optical model fully takes into account dispersion in glass substrate, organic layers as well as the dispersion in metal contacts/mirrors. Influence of the incoherent transparent glass substrate is also accounted for. Two metal contacts Ag and Cu have been considered for anode and cathode respectively. For the hole transport layer NPB was used. The OLED structure is examined as a function of: thickness of the organic layers, and position of the hole transport layer/Alq3 interface. In order to obtain better agreement with EL experimental data, electrical models was developed in conjunction with the existing optical model to facilitate accurate optimisation of the OLED structure. The electrical model developed considers the metal contact as Schottky contact, the carrier mobility is taken to be field dependent with the Poole-Frenkel-like form and Langevin recombination model is used. The carrier transport was simulated using one-dimensional time-independent drift-diffusion model using device simulation software ATLAS.2 Finally, the optimised devices were fabricated and characterised and experimental and calculated optical emission spectra were compared together with results obtained from electrical transport model

Electrical and Optical Simulation of Tris(8-hydroxyquinoline) Aluminium-Based Microcavity Organic Light Emitting Diode (MOLED)

A detailed examination of the emitted radiation spectrum from tris(8-hydroxyquinoline) aluminum (Alq) based OLEDs on optical and electrical models have been presented. The OLED structure is examined as a function of choice of anode material and position of the NPB/Alq interface. The simulation results have been compared to those obtained from experiments, showing good agreement in both electrical and optical characteristics. The enhancement in light emission by aligning antinode of the stand wave pattern with effective carrier recombination region has been observed

Optimization of Transparent Electrode Processing Conditions for Bulk Heterojunction Solar Cells

In this work, semi-transparent inverted polymer solar cells with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate; PEDOT:PSS) top electrodes were fabricated by spin-coating process. Poly(3-hexylthiophene; P3HT):[6,6]-phenyl C 61 -butyric acid methyl ester (PCBM) was used as a model material combination for a bulk heterojunction solar cell, because this material combination has been frequently studied, and its properties and performance have been well established. For enhancing the wetting of P3HT:PCBM blend film, different plasma etching conditions were tried. In addition, different high boiling point organic additives were tried to enhance the conductivity of PEDOT:PSS. The performance of solar cells with different fabrication conditions for the top electrode was compared. The best performance was obtained for Ar plasma etching to improve wetting of PEDOT:PSS and the addition of ethylene glycol to improve conductivity.published_or_final_versio

Strategy for introducing antibacterial activity under ambient illumination in titania nanoparticles

Titanium dioxide (TiO2) is a wide bandgap (∼3.4 eV) semiconductor material which is commonly used as a photocatalyst and antibacterial material. UV illumination with energy similar to the bandgap is often needed to make the material active. It would be favorable for practical applications, if its action can also be activated under ambient. Recently, robust antibacterial action was demonstrated on ZnO nanoparticles under ambient illumination. In this study, we demonstrated robust antibacterial activity of TiO2 nanoparticles induced by annealing under ambient illumination. It was found that the antibacterial activity could be significantly changed by tuning the annealing temperatures and using different crucibles containing the nanoparticles. Bacterium Escherichia coli was used as the model organism in the test. It was observed that although no significant antibacterial activity was observed on the starting material (untreated commercial TiO2 nanoparticles), the activity increases significantly if the nanoparticles were annealed above 650 °C with crucible lined with copper foil. The survival rate of E. coli bacteria approaches to zero if the nanoparticles annealing temperature reaches 850 °C. Under optimized conditions, three different titania nanoparticle samples exhibited antibacterial activity under ambient illumination. This work sheds light on the development of ambient-active antibacterial coating and in particular, on the modification of any TiO2 material to become ambient-active with a suitable treatment. © 2015 SPIE.published_or_final_versio

Effect of ZnO surface defects on efficiency and stability of ZnO-based perovskite solar cells

ZnO as an alternative electron transport layer (ETL) material for perovskite solar cell applications has drawn increasing research interest due to its comparable energy levels to TiO2, relatively high electron mobility, as well as its feasibility to be processed at low temperatures for potential applications in flexible devices. Nevertheless, ZnO based perovskite devices usually exhibit inferior performance and severe stability drawbacks which are related to the surface defects of ZnO ETL. In this study, to investigate the correlation between ZnO defect composition and resulting device performance, different approaches of preparing ZnO ETL are compared in terms of the perovskite morphology and device performance. In addition, direct manipulations of ZnO surface defects are performed by various surface treatments, and the photovoltaic performance of devices with ZnO ETL subjected to different surface treatments is compared. Surface modification of ZnO ETL by ethanolamine (EA) is demonstrated to efficiently enhance the photovoltaic performance of resulting ZnO based devices. © (2017) COPYRIGHT Societypublished_or_final_versio

Shape transition in ZnO nanostructures and its effect on blue-green photoluminescence

We report that ZnO nanostructures synthesized by chemical route undergo a shape transition at ~ 20 nm from spherical to hexagonal morphology thereby changing the spectral components of the blue-green emission. Spherically shaped nanocrystals (size range 11 -18 nm) show emission in the range of 555-564 nm and the emission shifts to the longer wavelength as the size increases. On the other hand, rods and hexagonal platelets (size range 20-85 nm), which is the equilibrium morphology after the shape transition, show emission near 465-500 nm and it shifts to shorter wavelength as the size increases. The shape transition also leads to relaxation of microstrain in the system. Our analysis shows that the visible emission originates from a defect layer on the nanostructure surface which is affected by the shape transition. The change in the spectral component of the blue green emission on change of shape has been explained as arising from band bending due to depletion layer in smaller spherical particles which is absent in the larger particles with flat faces.Comment: 8 pages, 8 figure

Cycling performance of Mn2O3 porous nanocubes and hollow spheres for lithium-ion batteries

Post presentationMn2O3 is a promising anode material for lithium ion battery. Two different kinds of structures of Mn2O3 were synthesized via solution processes, the Mn2O3 porous cubes and hollow spheres. Scanning electron microscope images and transmission electron microscopy images clearly show the structures. Electrochemical impedance spectroscopy and cyclic voltammetry measurements were used to characterize their electrochemical properties. As anode materials for lithium ion batteries, Mn2O3 porous cubes performed similarly as Mn2O3 hollow spheres. Both samples started with high initial capacities (1583.2 mAh/g and 1550.7 mAh/g) which were reduced to 173.3 mAh/g and 162.0 mAh/g at 100th cycle at a current density of 100 mA/g. The decrease is likely due to morphology destruction the materials in charging and discharging process.published_or_final_versio

Template-free synthesis of hierarchical hollow V2O5 microspheres with highly stable lithium storage capacity

Hollow V2O5 microspheres were successfully synthesized by a solvothermal method and subsequent calcination. The rigid hollow V2O5 cathode prepared in isopropanol solvent exhibited excellent cycling performance and rate capability. Within a voltage window of 2.5 to 4 V, a maximum specific discharge capacity of 128 mA h g−1 was delivered at 1 A g−1. Even after 500 cycles, the capacity retention was 92.2%.published_or_final_versio

Optimization of Organic Light Emitting Diode Structures

In this work we present detailed analysis of the emitted radiation spectrum from tris(8-hydroxyquinoline) aluminum (Alq3) based OLEDs as a function of: the choice of cathode, the thickness of organic layers, and the position of the hole transport layer/Alq3 interface. The calculations fully take into account dispersion in glass substrate, indium tin oxide anode, and in the organic layers, as well as the dispersion in the metal cathode. Influence of the incoherent transparent substrate (1 mm glass substrate) is also fully accounted for. Four cathode structures have been considered: Mg/Ag, Ca/Ag, LiF/Al, and Ag. For the hole transport layer, N,N'-diphenyl-N,N'-(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) was considered. As expected, emitted radiation is strongly dependent on the position of the emissive layer inside the cavity and its distance from the metal cathode. Although our optical model for an OLED does not explicitly include exciton quenching in vicinity of the metal cathode, designs placing emissive layer near the cathode are excluded to avoid unrealistic results. Guidelines for designing devices with optimum emission efficiency are presented. Finally, the optimized devices were fabricated and characterized and experimental and calculated emission spectra were compared