Broadband Coherent Absorption in Chirped-Planar-Dielectric Cavities for 2D-Material-Based Photovoltaics and Photodetectors

Atomically thin materials such as graphene and transition metal dichalcogenides are being developed for a range of optoelectronic devices, but their applications are currently limited by low light absorption. Here, we describe a dielectric cavity design with chirped Bragg reflectors for broadband coherent absorption. The chirped cavity absorption is calculated by the transfer matrix method and optimized using the Nelder–Mead optimization protocol. We numerically demonstrate that with cavity enhancement, a monolayer MoS₂ photodetector absorbs as much as 33% of incident visible light over a 300 nm bandwidth, and the external quantum efficiency of an atomically thin monolayer graphene/monolayer MoS₂ solar cell can be enhanced 3.6 times to a predicted value of 7.09%. The proposed layered dielectric structures operate across a wide range of incident angles and could enable applications for atomically thin photodetectors or solar cells

Wide-Field Multispectral Super-Resolution Imaging Using Spin-Dependent Fluorescence in Nanodiamonds

Recent advances in fluorescence microscopy have enabled spatial resolution below the diffraction limit by localizing multiple temporally or spectrally distinguishable fluorophores. Here, we introduce a super-resolution technique that <i>deterministically</i> controls the brightness of uniquely addressable, photostable emitters. We modulate the fluorescence brightness of negatively charged nitrogen-vacancy (NV^–) centers in nanodiamonds through magnetic resonance techniques. Using a CCD camera, this “deterministic emitter switch microscopy” (DESM) technique enables super-resolution imaging with localization down to 12 nm across a 35 × 35 μm² area. DESM is particularly well suited for biological applications such as multispectral particle tracking since fluorescent nanodiamonds are not only cytocompatible but also nonbleaching and bright. We observe fluorescence count rates exceeding 1.5 × 10⁶ photons per second from single NV^– centers at saturation. When combined with emerging NV^–-based techniques for sensing magnetic and electric fields, DESM opens the door to rapid, super-resolution imaging for tracking and sensing applications in the life and physical sciences

Nanoscale Engineering of Closely-Spaced Electronic Spins in Diamond

Numerous theoretical protocols have been developed for quantum information processing with dipole-coupled solid-state spins. Nitrogen vacancy (NV) centers in diamond have many of the desired properties, but a central challenge has been the positioning of NV centers at the nanometer scale that would allow for efficient and consistent dipolar couplings. Here we demonstrate a method for chip-scale fabrication of arrays of single NV centers with record spatial localization of about 10 nm in all three dimensions and controllable inter-NV spacing as small as 40 nm, which approaches the length scale of strong dipolar coupling. Our approach uses masked implantation of nitrogen through nanoapertures in a thin gold film, patterned via electron-beam lithography and dry etching. We verified the position and spin properties of the resulting NVs through wide-field super-resolution optically detected magnetic resonance imaging

LNoS: Lithium Niobate on Silicon Spatial Light Modulator

Programmable spatiotemporal control of light is crucial for advancements in optical communications, imaging, and quantum technologies. Commercial spatial light modulators (SLMs) typically have megapixel-scale apertures but are limited to ~kHz operational speeds. Developing a device that controls a similar number of spatial modes at high speeds could potentially transform fields such as imaging through scattering media, quantum computing with cold atoms and ions, and high-speed machine vision, but to date remains an open challenge. In this work we introduce and demonstrate a free-form, resonant electro-optic (EO) modulator with megapixel apertures using CMOS integration. The optical layer features a Lithium Niobate (LN) thin-film integrated with a photonic crystal (PhC), yielding a guided mode resonance (GMR) with a Q-factor>1000, a field overlap coefficient ~90% and a 1.6 GHz 3-dB modulation bandwidth (detector limited). To realize a free-form and scalable SLM, we fabricate the PhC via interference lithography and develop a procedure to bond the device to a megapixel CMOS backplane. We identify limitations in existing EO materials and CMOS backplanes that must be overcome to simultaneously achieve megapixel-scale, GHz-rate operation. The `LN on Silicon' (LNoS) architecture we present is a blueprint towards realizing such devices

Supplement 1: Bright and photostable single-photon emitter in silicon carbide

Supplemental document Originally published in Optica on 20 July 2016 (optica-3-7-768

Reliable Exfoliation of Large-Area High-Quality Flakes of Graphene and Other Two-Dimensional Materials

Mechanical exfoliation has been a key enabler of the exploration of the properties of two-dimensional materials, such as graphene, by providing routine access to high-quality material. The original exfoliation method, which remained largely unchanged during the past decade, provides relatively small flakes with moderate yield. Here, we report a modified approach for exfoliating thin monolayer and few-layer flakes from layered crystals. Our method introduces two process steps that enhance and homogenize the adhesion force between the outermost sheet in contact with a substrate: Prior to exfoliation, ambient adsorbates are effectively removed from the substrate by oxygen plasma cleaning, and an additional heat treatment maximizes the uniform contact area at the interface between the source crystal and the substrate. For graphene exfoliation, these simple process steps increased the yield and the area of the transferred flakes by more than 50 times compared to the established exfoliation methods. Raman and AFM characterization shows that the graphene flakes are of similar high quality as those obtained in previous reports. Graphene field-effect devices were fabricated and measured with back-gating and solution top-gating, yielding mobilities of ∼4000 and 12 000 cm²/(V s), respectively, and thus demonstrating excellent electrical properties. Experiments with other layered crystals, <i>e.g.</i>, a bismuth strontium calcium copper oxide (BSCCO) superconductor, show enhancements in exfoliation yield and flake area similar to those for graphene, suggesting that our modified exfoliation method provides an effective way for producing large area, high-quality flakes of a wide range of 2D materials

Strong Enhancement of Light–Matter Interaction in Graphene Coupled to a Photonic Crystal Nanocavity

We demonstrate a large enhancement in the interaction of light with graphene through coupling with localized modes in a photonic crystal nanocavity. Spectroscopic studies show that a single atomic layer of graphene reduces the cavity reflection by more than a factor of one hundred, while also sharply reducing the cavity quality factor. The strong interaction allows for cavity-enhanced Raman spectroscopy on subwavelength regions of a graphene sample. A coupled-mode theory model matches experimental observations and indicates significantly increased light absorption in the graphene layer. The coupled graphene–cavity system also enables precise measurements of graphene’s complex refractive index

Surface Structure of Aerobically Oxidized Diamond Nanocrystals

We investigate the aerobic oxidation of high-pressure, high-temperature nanodiamonds (5–50 nm dimensions) using a combination of carbon and oxygen K-edge X-ray absorption, wavelength-dependent X-ray photoelectron, and vibrational spectroscopies. Oxidation at 575 °C for 2 h eliminates graphitic carbon contamination (>98%) and produces nanocrystals with hydroxyl functionalized surfaces as well as a minor component (<5%) of carboxylic anhydrides. The low graphitic carbon content and the high crystallinity of HPHT are evident from Raman spectra acquired using visible wavelength excitation (λ_excit = 633 nm) as well as carbon K-edge X-ray absorption spectra where the signature of a core–hole exciton is observed. Both spectroscopic features are similar to those of chemical vapor deposited (CVD) diamond but differ significantly from the spectra of detonation nanodiamond. The importance of these findings to the functionalization of nanodiamond surfaces for biological labeling applications is discussed

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Supplementary Materia

Fiber-Coupled Diamond Micro-Waveguides toward an Efficient Quantum Interface for Spin Defect Centers

We report the direct integration and efficient coupling of nitrogen vacancy (NV) color centers in diamond nanophotonic structures into a fiber-based photonic architecture at cryogenic temperatures. NV centers are embedded in diamond micro-waveguides (μWGs), which are coupled to fiber tapers. Fiber tapers have low-loss connection to single-mode optical fibers and hence enable efficient integration of NV centers into optical fiber networks. We numerically optimize the parameters of the μWG-fiber-taper devices designed particularly for use in cryogenic experiments, resulting in 35.6% coupling efficiency, and experimentally demonstrate cooling of these devices to the liquid helium temperature of 4.2 K without loss of the fiber transmission. We observe sharp zero-phonon lines in the fluorescence of NV centers through the pigtailed fibers at 100 K. The optimized devices with high photon coupling efficiency and the demonstration of cooling to cryogenic temperatures are an important step to realize fiber-based quantum nanophotonic interfaces using diamond spin defect centers