807 research outputs found
Self-Assembly on a Cylinder: A Model System for Understanding the Constraint of Commensurability
A crystal lattice, when confined to the surface of a cylinder, must have a
periodic structure that is commensurate with the cylinder circumference. This
constraint can frustrate the system, leading to oblique crystal lattices or to
structures with a chiral seam known as a "line slip" phase, neither of which
are stable for isotropic particles in equilibrium on flat surfaces. In this
study, we use molecular dynamics simulations to find the steady-state structure
of spherical particles with short-range repulsion and long-range attraction far
below the melting temperature. We vary the range of attraction using the
Lennard-Jones and Morse potentials and find that a shorter-range attraction
favors the line-slip. We develop a simple model based only on geometry and bond
energy to predict when the crystal or line-slip phases should appear, and find
reasonable agreement with the simulations. The simplicity of this model allows
us to understand the influence of the commensurability constraint, an
understanding that might be extended into the more general problem of
self-assembling particles in strongly confined spaces.Comment: 12 pages, 9 figures. Submitted for publication, 201
Grain Boundary Scars and Spherical Crystallography
We describe experimental investigations of the structure of two-dimensional
spherical crystals. The crystals, formed by beads self-assembled on water
droplets in oil, serve as model systems for exploring very general theories
about the minimum energy configurations of particles with arbitrary repulsive
interactions on curved surfaces. Above a critical system size we find that
crystals develop distinctive high-angle grain boundaries, or scars, not found
in planar crystals. The number of excess defects in a scar is shown to grow
linearly with the dimensionless system size. The observed slope is expected to
be universal, independent of the microscopic potential.Comment: 4 pages, 3 eps figs (high quality images available from Mark Bowick
Hard Spheres in Vesicles: Curvature-Induced Forces and Particle-Induced Curvature
We explore the interplay of membrane curvature and nonspecific binding due to
excluded-volume effects among colloidal particles inside lipid bilayer
vesicles. We trapped submicron spheres of two different sizes inside a
pear-shaped, multilamellar vesicle and found the larger spheres to be pinned to
the vesicle's surface and pushed in the direction of increasing curvature. A
simple model predicts that hard spheres can induce shape changes in flexible
vesicles. The results demonstrate an important relationship between the shape
of a vesicle or pore and the arrangement of particles within it.Comment: LaTeX with epsfig; ps available at
http://dept.physics.upenn.edu/~nelson/index.shtml Phys Rev Lett in press
(1997
Depletion forces near curved surfaces
Based on density functional theory the influence of curvature on the
depletion potential of a single big hard sphere immersed in a fluid of small
hard spheres with packing fraction \eta_s either inside or outside of a hard
spherical cavity of radius R_c is calculated. The relevant features of this
potential are analyzed as function of \eta_s and R_c. There is a very slow
convergence towards the flat wall limit R_c \to \infty. Our results allow us to
discuss the strength of depletion forces acting near membranes both in normal
and lateral directions and to make contact with recent experimental results
Properties of cage rearrangements observed near the colloidal glass transition
We use confocal microscopy to study the motions of particles in concentrated
colloidal systems. Near the glass transition, diffusive motion is inhibited, as
particles spend time trapped in transient ``cages'' formed by neighboring
particles. We measure the cage sizes and lifetimes, which respectively shrink
and grow as the glass transition approaches. Cage rearrangements are more
prevalent in regions with lower local concentrations and higher disorder.
Neighboring rearranging particles typically move in parallel directions,
although a nontrivial fraction move in anti-parallel directions, usually from
pairs of particles with initial separations corresponding to the local maxima
and minima of the pair correlation function , respectively.Comment: 5 pages, 4 figures; text & figures revised in v
Forced motion of a probe particle near the colloidal glass transition
We use confocal microscopy to study the motion of a magnetic bead in a dense
colloidal suspension, near the colloidal glass transition volume fraction
. For dense liquid-like samples near , below a threshold force
the magnetic bead exhibits only localized caged motion. Above this force, the
bead is pulled with a fluctuating velocity. The relationship between force and
velocity becomes increasingly nonlinear as is approached. The
threshold force and nonlinear drag force vary strongly with the volume
fraction, while the velocity fluctuations do not change near the transition.Comment: 7 pages, 4 figures revised version, accepted for publication in
Europhysics Letter
Direct visualization of aging in colloidal glasses
We use confocal microscopy to directly visualize the dynamics of aging
colloidal glasses. We prepare a colloidal suspension at high density, a simple
model system which shares many properties with other glasses, and initiate
experiments by stirring the sample. We follow the motion of several thousand
colloidal particles after the stirring and observe that their motion
significantly slows as the sample ages. The aging is both spatially and
temporally heterogeneous. Furthermore, while the characteristic relaxation time
scale grows with the age of the sample, nontrivial particle motions continue to
occur on all time scales.Comment: submitted to proceedings for Liquid Matter Conference 200
Addiction Counseling Practice Competencies and Curriculum in CACREP-Accredited Programs
Addiction counseling is a growing field with emerging practice competencies and standards that have implications for counselor education programs. This study examined addiction counseling practice competencies and curriculum elements in CACREP-accredited programs to determine curriculum and program needs. A survey of 62 CACREP programs found that programs are including addiction counseling content into the curriculum, employing faculty who have experience in addiction counseling, and addressing the skill practice competency by adding increased credit hours in addiction counseling and teaching from a didactic and constructivist pedagogy. Recommendations are made to align addiction counseling training curriculum, including adding an addiction counseling specialization track that incorporates practice experiences
Title IX and the Cleary Act: What Counselor Educators Must Know
Because of the far-reaching legal, monetary, academic, and public relations ramifications of the sex abuse scandal at Pennsylvania State University, campus administrators are reviewing and more strictly enforcing the mandatory reporting requirements of Title IX of the 1972 Education Amendments and the Clery Act related to sexual harassment and sexual violence. This creates challenges in didactic and clinical coursework for counselor educators who must balance adhering to university reporting guidelines with the ethical responsibilities to provide informed consent and maintain confidentially of information disclosed by students and their clients during training. Issues involved for counselor educators and student counselors-in-training, the process of securing appropriate exceptions to mandatory reporting, and a sample exception policy are presented
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