Xps Study of the Oxidation State of Uranium Dioxide

In this article we report an investigation of the oxidation state of uranium dioxide using X-Ray Photoelectron Spectroscopy, and by comparing to results obtained in previous studies. We find that uranium dioxide in powder appears to share its six valence electrons with the oxygen atoms to form crystalline UO3

Agroforestry can mitigate environmental problems in european agricultural deficit areas

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Dynamical and spectral properties of complex networks

Dynamical properties of complex networks are related to the spectral properties of the Laplacian matrix that describes the pattern of connectivity of the network. In particular we compute the synchronization time for different types of networks and different dynamics. We show that the main dependence of the synchronization time is on the smallest nonzero eigenvalue of the Laplacian matrix, in contrast to other proposals in terms of the spectrum of the adjacency matrix. Then, this topological property becomes the most relevant for the dynamics.Comment: 14 pages, 5 figures, to be published in New Journal of Physic

Radiative efficiencies for fluorinated esters: indirect global warming potentials of hydrofluoroethers

Density Functional Theory (DFT) has been used with an empirically-derived correction for the wavenumbers of vibrational band positions to predict the infrared spectra of several fluorinated esters (FESs). Radiative efficiencies (REs) were then determined using the method of Pinnock et al. and these were used with atmospheric lifetimes from the literature to determine the direct global warming potentials of FESs. FESs, in particular fluoroalkylacetates, alkylfluoroacetates and fluoroalkylformates, are potential greenhouse gases and their likely long atmospheric lifetimes and relatively large REs, compared to their parent HFEs, make them active contributors to global warming. Here, we use the concept of indirect global warming potential (indirect GWP) to assess the contribution to the warming of several commonly used HFEs emitted from the Earth's surface, explicitly taking into account that these HFEs will be converted into the corresponding FESs in the troposphere. The indirect GWP can be calculated using the radiative efficiencies and lifetimes of the HFE and its degradation FES products. We found that the GWPs of those studied HFEs which have the smallest direct GWP can be increased by 100-1600% when taking account of the cumulative effect due to the secondary FESs formed during HFE atmospheric oxidation. This effect may be particularly important for non-segregated HFEs and some segregated HFEs, which may contribute significantly more to global warming than can be concluded from examination of their direct GWPs

Scattering images from autocorrelation functions of P-wave seismic velocity images : the case of Tenerife Island (Canary Islands, Spain)

We thank Edoardo Del Pezzo for the valuable idea of this paper and suggestions regarding the methodology. J. Prudencio is partially supported by NSF1521855 Hazard SEES project. This paper has been partially supported by the Spanish project KNOWAVES (TEC2015-68752-R (MINECO/FEDER)), the European project MED-SUV funded by the European Union’s Seventh Framework Program for research, technological development and demonstration under Grant Agreement No 308665, and by the Regional project ‘Grupo de Investigación en Geofísica y Sismología de la Junta de Andalucía, RNM104’.Peer reviewedPostprin