The Exact Linearization and LQR Control of Semiactive Connected Hydropneumatic Suspension System

Based on differential geometry theory, the nonlinear system of connected hydropneumatic suspension was transformed to a linear one. What is more, it realized the decoupling and inverter between the control variables and system outputs. With LQR (Linear Quadratic Regulator) control theory, a semiactive system has been developed for connected hydropneumatic suspension in this paper. By AMESim/Simulink cosimulation, the results show that the semiactive connected hydropneumatic suspension decreases the vibration of upper vehicle quickly and reduces the impact acceleration strongly both in displacement and inroll angle. Moreover, the semiactive suspension could increase the suspension dynamic deflection, which would make the system reach balance quickly and keep small vibration amplitude under the effect of disturbance

Process, microstructure and mechanical properties

Funding Information: This work was supported by National Natural Science Foundation of China (Grant No. 51875168/52002112 ), Natural Science Foundation of Hebei Province (Grant No. E2019208089 ) and “Three-Three-Three Talent Project” Foundation of Hebei Province ( C20221022 ). Sichuan Province Science Funding for Distinguished Young Scholars ( 3NSFJQ0064 ). JPO acknowledges funding by national funds from FCT – Fundação para a Ciência e a Tecnologia, I.P., in the scope of the projects LA/P/0037/2020. Science and Technology Research Project of Colleges and Universities in Hebei Province (Grant No. BJK2022020 ). Publisher Copyright: © 2023 The AuthorsAiming to decouple the inherent relationship between mass transfer and heat transfer in traditional arc-based directed energy deposition, a novel heterogeneous multi-wire indirect arc directed energy deposition (DED) has been developed for in-situ synthesis of Al-Zn-Mg-Cu alloy components. Multi-wires (Al-Cu and Al-Mg) with a bypassing Zn wire have been used to replace the traditional homogeneous twin-wires. The process, microstructure and mechanical properties of the deposited Al-Zn-Mg-Cu alloy components obtained by multi-wire indirect arc DED were investigated. The results indicate that the wire feeding speed, current and angle between the two wires have a significant influence on the multi-wire indirect arc DED process. When the current was 200 A, the different wire feeding speeds could be used for both wires and the angle between them was 90°. The resulting indirect arc presented a ‘heart’ shape and allowed to obtain an Al-5.7Zn-3.4Mg-1.6Cu (wt%) alloy with a high deposition rate of 5.1 kg/h. The Al-5.7Zn-3.4Mg-1.6Cu alloy is mainly composed of α-Al, S (Al2CuMg), η (Mg (Al, Zn, Cu)2) and η′ phases. The composition and phases are in accordance with the 7xxx series aluminum alloys. The microstructure is dominated by columnar and equiaxed grains, and it has obvious periodic distribution along the building direction, which is related to the process thermal cycle. Fine second phases η′ are observed to precipitate during the manufacturing process. Furthermore, the average hardness, ultimate tensile strength and elongation of the fabricated material are 98.6 HV, 243.9 MPa and 5.9%, respectively. These mechanical properties are higher than those of as-cast 7050 aluminum alloy, thus showing the potential of this new process variant to fabricate high strength Al alloys in the as-deposited state. The fracture morphology exhibit features mainly associated to a ductile-like fracture, accompanied by some transgranular and partial cleavage fracture characteristics. This novel multi-wire indirect arc DED provides a new choice for arc-based directed energy deposition of Al-Zn-Mg-Cu alloys and shows great potential for the in-situ synthesis of other high-performance alloys.publishersversionpublishe

A 3D conductive scaffold with lithiophilic modification for stable lithium metal batteries

In this study, a non-lithiophilic nickel foam (NF) was transformed into a 3D lithiophilic N-doped graphene/nickel foam (NGNF) scaffold by a simple hydrothermal method. This scaffold can increase the area for Li deposition, improve the poor lithiophilicity of NF, and decrease the overpotential for Li deposition, leading to uniform Li plating/stripping. Thus, the average coulombic efficiency for Li deposition on the NGNF electrode can remain as high as 98.3% over 200 cycles and 98.0% over 100 cycles at current densities of 2 mA cm-2and 4 mA cm-2, respectively. Even when the Li deposition capacity is increased to as high as 10 mA h cm-2, the cells with NGNF electrodes still exhibit stable cycling performance with a high coulombic efficiency of 98.9% after 84 cycles. Density functional theory (DFT) calculations were performed to achieve a deeper understanding of the interaction between Li atoms and the designed scaffold. In addition, the potential application of the scaffold is further demonstrated by the superior electrochemical performance of an assembled LiFePO4/Li-NGNF full cell under room-temperature and low-temperature conditions

Effect of Biochar on Methane Production and Structural Characteristics in the Anaerobic Digestion (AD) of Rape Straw

This study investigated the mesophilic and thermophilic anaerobic fermentation of rape straw with biochar addition. The effects of biochar on the biogas yield, degradation of lignocellulose, bacterial community, and crystallinity were explored. The results showed that the biogas yield and methane content increased as the biochar concentration was increased. The biochar concentration of 5.0% resulted in a high biogas yield in mesophilic and thermophilic anaerobic digestion at 142.2 mL/g and 193.5 mL/g, respectively, which were 40.5% and 21.0% improvements compared with the control. The corresponding methane contents were 59.4% and 57.0%, respectively. For the lignocellulose degradation, the cellulose content in the mesophilic AD decreased from 54.0% in the pretreated rape straw to between 18.7% and 25.0%. The microbial community results showed that as the biochar concentration was increased, the relative abundance of Firmicutes initially increased before it decreased. Among the microbial community results, the relative abundances of Firmicutes and Bacteroides in the biogas residue of the mesophilic anaerobic digestion were the highest in the biogas residue with the 5.0% biochar concentration sample in the mesophilic AD, at 27.06% and 39.20%, respectively. This result revealed the mechanism of biochar to improve the biogas production of rape straw in anaerobic fermentation

An Approach to Study Groundwater Flow Field Evolution Time Scale Effects and Mechanisms

The temporal scale effect is an important issue for groundwater system evolution research. The selection of an appropriate time scale will enhance the understanding of the characteristics and mechanisms of groundwater flow field evolution. In this study, a methodology was provided to analyze the groundwater system evolution, focusing on the choice of the suitable time step for identifying the distinct stages of evolution, characterized by different behavior linked to the management of the groundwater system. The evolution trend of the groundwater level in the center of the cone of depression at different time scales, combined with the F test and the groundwater system balance index (Re) categories, were used for the choice of the time step and the division of the evolution stages. Based on the transformed groundwater level time series using the selected best time step, the main factors controlling the groundwater evolution were assessed for the different stages. Our results show that the methodology can exactly identify the different important stages of the evolution, and they can be used to individually study these stages, which can help to reveal the mechanisms of the groundwater evolution more easily. Therefore, it is useful to obtain an increased knowledge of the regional groundwater dynamics

Facile synthesis of a novel P-doped carbon coated nickel phosphides nanorods as sodium storage anode materials

Nickel-based phosphides as anode materials of sodium ion batteries have high capacity, but poor cycle stability and low electrical conductivity. Rational structural design for nickel-based phosphides with carbon provides a new way to address the above shortcomings. This paper presents a simple method to synthesize a novel carbon coated NixP (x = 2.4–3.0, denoted as NixP@PC) nanorods using phosphoric acid resin as phosphorus and carbon sources. The NixP nanocrystals are in-situ generated in the P-doped carbon without further phosphatization. The carbon layer can confine the volume changes during charging/discharging process. Additionally, the enriched P doping in the carbon layer greatly increases the electrical conductivity of the NixP-based composite and provides more active sites for sodium storage. The as-obtained NixP@PC nanorods reveal excellent reversible sodium storage performance (271.6 mA·h/g based on the mass of NixP@PC at 0.1 A/g after 300 cycles) and outstanding cycling stability (0.005% capacity decay per cycle after 5 000 cycles at 2 A/g). Meanwhile, the formation mechanism of NixP@PC is evidenced by monitoring the evolution of morphology and structure during the preparing process. This paper may provide a feasible way for constructing high-performance transitional metal compounds for sodium-ion batteries

Effect of Pulse Frequency on Microstructure and Mechanical Properties of 2198 Al-Li Alloy Joints Obtained by Ultrahigh-Frequency Pulse AC CMT Welding

In this study, 2198 Al-Li alloy, a low density and high-performance material for aerospace equipment, was welded using ultrahigh-frequency pulse alternating current with cold metal transfer (UHF-ACCMT). Influence of different ultrahigh-frequency on the formation, porosity, microstructure, microhardness and tensile strength of the welded joints were investigated. The results showed that the coupled ultrahigh-frequency current generated electromagnetic force to stir the liquid metal of molten pool. The weld formation became much better with metallic luster and uniform ripples at frequency of 60 kHz and 70 kHz. The porosity was the minimum at frequency of 60 kHz. Furthermore, the molten pool was scoured and stirred by the electromagnetic force which provided the thermal and dynamic conditions for nucleation and grain refinement, the width of fine equiaxed grain zone became larger, and the number of equiaxed non-dendrite grains increased. With the grain refining and crystallize transition, the average microhardness and tensile strength of the joints at frequency of 60 kHz reached up the highest value, 116 HV0.1 and 338 MPa, respectively. The fracture of the welded joints presented the characteristics of quasi-cleavage fracture

Desired crystal oriented LiFePO4 nanoplatelets in situ anchored on a graphene cross-linked conductive network for fast lithium storage

Electron transfer and lithium ion diffusion rates are the key factors limiting the lithium ion storage in anisotropic LiFePO electrodes. In this work, we employed a facile solvothermal method to synthesize a "platelet-on-sheet" LiFePO/graphene composite (LFP@GNs), which is LiFePO nanoplatelets in situ grown on graphene sheets with highly oriented (010) facets of LiFePO crystals. Such a two-phase contact mode with graphene sheets cross-linked to form a three-dimensional porous network is favourable for both fast lithium ion and electron transports. As a result, the designed LFP@GNs displayed a high rate capability (∼56 mA h g at 60 C) and long life cycling stability (∼87% capacity retention over 1000 cycles at 10 C). For comparison purposes, samples ex situ modified with graphene (LFP/GNs) as well as pure LiFePO platelets (LFP) were also prepared and investigated. More importantly, the obtained LFP@GNs can be used as a basic unit for constructing more complex structures to further improve electrochemical performance, such as coating the exposed LFP surface with a thin layer of carbon to build a C@LFP@GN composite to further enhance its cycling stability (∼98% capacity retention over 1000 cycles at 10 C). This journal i