Kinetics of Surfactant Adsorption at Fluid/Fluid Interfaces: Non-ionic Surfactants

We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the kinetics taking place at the interface using a free-energy formulation. In addition, it offers a general method of calculating dynamic surface tensions. Non-ionic surfactants are shown, in general, to undergo a diffusion-limited adsorption, in accord with experimental findings.Comment: 6 pages, 3 figures, see also cond-mat/960814

Unstable topography of biphasic surfactant monolayers

We study the conformation of a heterogeneous surfactant monolayer at a fluid-fluid interface, near a boundary between two lateral regions of differing elastic properties. The monolayer attains a conformation of shallow, steep `mesas' with a height difference of up to 10 nm. If the monolayer is progressively compressed (e.g. in a Langmuir trough), the profile develops overhangs and finally becomes unstable at a surface tension of about K(delta c_0)^2, where (delta c_0) is the difference in spontaneous curvature and K a bending stiffness. We discuss the relevance of this instability to recently observed folding behavior in lung surfactant monolayers, and to the absence of domain structures in films separating oil and water in emulsions.Comment: 7 pages, 7 figures, LaTex using epl.cls, accepted for Europhys Let

Low-Income Adolescents Face More Barriers to Healthy Weight

Examines the causes behind the higher prevalence of obesity among low-income adolescents, including unhealthy food environments, few opportunities for physical activity, and irregular family meals. Makes policy recommendations to address such disparities