Chemistry of Molybdaboranes: Synthesis, Structures, and Characterization of a New Class of Open-Cage Dimolybdaheteroborane Clusters

Reaction of [Cp*MoCl(4)], 1 (Cp*= eta(5)-C(5)Me(5)), with [LiBH(4) center dot thf] in toluene at -70 degrees C, followed by pyrolysis with excess dichalcogenides RE-ER (R = Ph, CH(2)Ph, 2,6-((t)Bu)(2)-C(6)H(2)OH, (CH(3))(3)C=(t)Bu); E=S, Se) yielded a new class of hybrid clusters, 3-8: (3, [(Cp*Mo)(2)(mu-eta(1)-SPh)(2)(mu(3)-S)(H(2)BSPh)]; 4, [(CP*Mo)(2)B(5)H(8)(SPh)]; 5, [(CP*Mo)(2)B(6)H(8)(SePh)]; 6, [(CP*Mo)(2)B(2)S(2)H(2)(mu-eta(1)-S)]; 7, [(CP*Mo)(2)B(2)H(5)(BSR)(2)(mu-eta(1)-SR)], (R = 2,6-((t)Bu)(2)-C(6)H(2)OH); and 8, [(Cp*Mo)(2)B(2)H(5)(BSePh)(2)(mu-eta(1)-SePh)]. Compounds 3-8 have been isolated in modest yields as green or brown crystalline solids. In parallel with 3-8, [(CP*Mo)(2)B(5)H(9)] was isolated as a major product in all cases. The isolation and structural characterization of compounds 3 and 6-8 provided the first direct evidence of the existence of [(Cp*Mo)(2)B(4)H(8)], 2, an intermediate in the formation of [(Cp*Mo)(2)B(5)H(9)]. These new compounds have been characterized in solution by mass spectrometry, (1)H, (11)B, (13)C NMR, and IR spectroscopy, and elemental analysis. The structural types were unequivocally established by X-ray crystallographic analysis of compounds 3-8

Detection of Bacillus subtilis spores using peptide-functionalized cantilever arrays

We move beyond anti body-antigen binding systems and demonstrate that short peptide ligands can be used to efficiently capture Bacillus subtilis (a simulant of Bacillus anthracis) spores in liquids. On an eight-cantilever array chip, four cantilevers were coated with binding peptide (NHFLPKV-GGGC) and the other four were coated with control peptide (LFNKHVP-GGGC) for reagentless detection of whole B. subtilis spores in liquids. The peptide-ligand-functionalized microcantilever chip was mounted onto a fluid cell filled with a B. subtilis spore suspension for similar to 40 min; a 40 nm net differential deflection was observed. Fifth-mode resonant frequency measurements were also performed before and after dipping microcantilever arrays into a static B. subtilis solution showing a substantial decrease in frequency for binding-peptide-coated microcantilevers as compared to that for control peptide cantilevers. Further confirmation was obtained by subsequent examination of the microcantilever arrays under a dark-field microscope. Applications of this technology will serve as a platform for the detection of pathogenic organisms including biowarfare agents

Sustainable Management of Root- Knot Nematode (Meloidogyne javanica) on Brinjal

Brinjal (Solanum melongena) is an important Solanaceae family vegetable, which is grown all around the world. It is affected by various fungal, bacterial, viral, nematode diseases but it is a major host for root-knot nematode, Meloidogyne javanica. Hence, for effective management of root-knot nematode experiment was conducted in field condition using the culture filtrate (3gm/kg soil) of bio-agents (viz., Trichoderma viride, Trichoderma harzianum, Purpureocillium lilacinum, Pochonia chlamydosporia and Pseudomonas fluorescens). The findings of the experiments revealed that, when compared to the control, all of the tested bio-agents considerably improved plant development characteristics and decreased nematode populations. Among the tested bio-agents T. viride was found most effective treatment with improve plant growth characters as well as in reducing nematode population over other treatment in field condition

Effect of Bio-Agent as Seed Treatment to Check the Initial Infection of Reniform Nematode, Rotylenchulus reniformis on Summer Mungbean (Vigna radiata L.)

Reniform nematode, Rotylenchulus reniformis received greater attention due to its polyphagous nature, cosmopolitan distribution and adaptability to different agro-ecological condition. It causes great losses to pulses including Mungbean (Singh, 2015). Therefore, an experiment was carried out to test the efficacy of botanicals to manage the reniform nematode infecting summer mungbean. Bioagents i.e. Metarhizium anisopliae and Beauveria bassiana were used at 5%, 10% and 15% as seed treatment. Trichoderma viride at 10% was kept as standard check. An untreated check was also maintained to compare the experimental findings. The experiment was conducted in completely randomized design with five replications. Results revealed that Metarhizium anisopliae at 15 % w/w as seed treatment significantly improve the plant growth parameters (44.81–77.21%) of summer mungbean followed by Beauveria bassiana at 15% (38.44-70.88%) and Metarhizium anisopliae at 10% (34.13–62.50%) as compared to untreated check. These treatments reduced the infestation of reniform nematode, R. reniformis on mungbean to the tune of 36.04-47.43%

Effect on Hatching and Mortality of Root-knot Nematode (Meloidogyne javanica) by Bio-agents

Investigations were carried out in vitro condition to evaluate the antagonistic effect of fungal and bacterial bio-agents. For effective management of root-knot nematode experiment was conducted in laboratory condition using the culture filtrate (5, 10 and 20 percent concentrate) of bio-agents (viz., Trichoderma viride, Trichoderma harzianum, Purpureocillium lilacinum, Pochonia chlamydosporia and Pseudomonas fluorescens). Experimental results showed that all the tested bio-agents significantly reduced the percent hatched juveniles and increased the percent mortality of juveniles. Among the tested bio-agents T. viride was found most effective treatment with minimum percent hatched juveniles and maximum percent mortality on eggs and juveniles of Meloidogyne javanica

Surfactant assisted synthesis of nickel vanadium oxide nanostructures with strong visible-light-induced photocatalytic activity

Nickel vanadium oxide (NiV2O6) nanoparticles were effectively synthesized using hydrothermal technique by changing the surfactants. The variation in the properties of the NiV2O6 based on the surfactants like cetyltrimethylammonium bromide (CTAB), polyethylene glycol (PEG) and Thio-glycolic acid (T-GA) was studied and reported. Methylene blue (MB) dye was utilized to investigate the photocatalytic activity of nickel vanadium oxide nanoparticles generated under the presence of CTAB as surfactant. The materials showed more than 80% degradation of methylene blue dye in 150 min. A putative photocatalytic process has been postulated in this paper. Nanoparticles were shown to have high photocatalytic activity and stability, according to the findings. Based on radical trapping experimental observations conducted with different scavengers such as 2-propanol, benzoquinone and EDTA, the major role played by OH−in the degradation process were reported in detail