4,037 research outputs found
Experimental phase equilibria constraints on pre-eruptive storage conditions of the Soufreiere Hills magma
Complex permeability of soft magnetic ferrite polyester resin composites at frequencies above 1 MHz
Composite soft magnetic materials consist of magnetic particles in a non-magnetic matrix. The properties of such materials can be modelled using effective medium theory. Measurements have been made of the complex permeability of composites produced using ferrite powder and polyester resin. The success of various effective medium expressions in predicting the variation of complex permeability with composition has been assessed
Petrologic evidence for pressure-temperature conditions and recent reheating of andesitic magma erupting at Soufriere Hills Volcano, Montserrat, WI
VLA Observations of the Infrared Dark Cloud G19.30+0.07
We present Very Large Array observations of ammonia (NH3) (1,1), (2,2), and
CCS (2_1-1_0) emission toward the Infrared Dark Cloud (IRDC) G19.30+0.07 at
~22GHz. The NH3 emission closely follows the 8 micron extinction. The NH3 (1,1)
and (2,2) lines provide diagnostics of the temperature and density structure
within the IRDC, with typical rotation temperatures of ~10 to 20K and NH3
column densities of ~10^15 cm^-2. The estimated total mass of G19.30+0.07 is
~1130 Msun. The cloud comprises four compact NH3 clumps of mass ~30 to 160
Msun. Two coincide with 24 micron emission, indicating heating by protostars,
and show evidence of outflow in the NH3 emission. We report a water maser
associated with a third clump; the fourth clump is apparently starless. A
non-detection of 8.4GHz emission suggests that the IRDC contains no bright HII
regions, and places a limit on the spectral type of an embedded ZAMS star to
early-B or later. From the NH3 emission we find G19.30+0.07 is composed of
three distinct velocity components, or "subclouds." One velocity component
contains the two 24 micron sources and the starless clump, another contains the
clump with the water maser, while the third velocity component is diffuse, with
no significant high-density peaks. The spatial distribution of NH3 and CCS
emission from G19.30+0.07 is highly anti-correlated, with the NH3 predominantly
in the high-density clumps, and the CCS tracing lower-density envelopes around
those clumps. This spatial distribution is consistent with theories of
evolution for chemically young low-mass cores, in which CCS has not yet been
processed to other species and/or depleted in high-density regions.Comment: 29 pages, 9 figures, accepted for publication by ApJ. Please contact
the authors for higher resolution versions of the figure
Role of Peptide Backbone Conformation on Biological Activity of Chemotactic Peptides
To investigate the role of peptide backbone conformation on the biological activity of chemotactic peptides, we synthesized a unique analog of N-formyl-Met-Leu-Phe-OH incorporating the C α,α disubstituted residue, dipropylglycine (Dpg) in place of Leu. The conformation of the stereochemically constrained Dpg analog was examined in the crystalline state by x-ray diffraction and in solution using NMR, IR, and CD methods. The secretagogue activity of the peptide on human neutrophils was determined and compared with that of a stereochemically constrained, folded type II β-turn analog incorporating 1-aminocyclohexanecarboxylic acid (Ac6c) at position 2 (f-Met- Ac6c -Phe-OMe), the parent peptide (f-Met-Leu-Phe-OH) and its methyl ester derivative (f-Met-Leu-Phe-OMe). In the solid state, the Dpg analog adopts an extended β-sheet-like structure with an intramolecular hydrogen bond between the NH and CO groups of the Dpg residue, thereby forming a fully extended (C5) conformation at position 2. The ϕ and ψ values for Met and Phe residues are significantly lower than the values expected for an ideal antiparallel beta conformation causing a twist in the extended backbone both at the N and C termini. Nuclear magnetic resonance studies suggest the presence of a significant population of the peptide molecules in an extended antiparallel β conformation and the involvement of Dpg NH in a C5 intramolecular hydrogen bond in solutions of deuterated chloroform and deuterated dimethyl sulfoxide. IR studies provide evidence for the presence of an intramolecular hydrogen bond in the molecule and the antiparallel extended conformation in chloroform solution. CD spectra in methanol, trifluoroethanol, and trimethyl phosphate indicate that the Dpg peptide shows slight conformational flexibility, whereas the folded Ac6c analog is quite rigid. The extended Dpg peptide consistently shows the highest activity in human peripheral blood neutrophils, being approximately 8 and 16 times more active than the parent peptide and the folded Ac6c analog, respectively. However, the finding that all four peptides have ED50 (the molar concentration of peptide to induce half-maximal enzyme release) values in the 10(-8)-10(-9) M range suggests that an induced fit mechanism may indeed be important in this ligand-receptor interaction. Moreover, it is also possible that alterations in the backbone conformation at the tripeptide level may not significantly alter the side chain topography and/or the accessibility of key functional groups important for interaction with the receptor
Instant Two-Body Equation in Breit Frame
A quasipotential formalism for elastic scattering from relativistic bound
states is based on applying an instant constraint to both initial and final
states in the Breit frame. This formalism is advantageous for the analysis of
electromagnetic interactions because current conservation and four momentum
conservation are realized within a three-dimensional formalism. Wave functions
are required in a frame where the total momentum is nonzero, which means that
the usual partial wave analysis is inapplicable. In this work, the
three-dimensional equation is solved numerically, taking into account the
relevant symmetries. A dynamical boost of the interaction also is needed for
the instant formalism, which in general requires that the boosted interaction
be defined as the solution of a four-dimensional equation. For the case of a
scalar separable interaction, this equation is solved and the Lorentz
invariance of the three-dimensional formulation using the boosted interaction
is verified. For more realistic interactions, a simple approximation is used to
characterize the boost of the interaction.Comment: 20 pages in revtex 3, 3 figures. Fixed reform/tex errors
Does tiny-scale atomic structure exist in the interstellar medium ?
We report on preliminary results from the recent multi-epoch neutral hydrogen
absorption measurements toward three pulsars, B0823+26, B1133+16 and B2016+28,
using the Arecibo telescope. We do not find significant variations in optical
depth profiles over periods of 0.3 and 9--10 yr, or on spatial scales of 10--20
and 70--85 AU. The large number of non detections of the tiny scale atomic
structure suggests that the AU-sized structure is not ubiquitous in the
interstellar medium and could be quite a rare phenomenon.Comment: Accepted by ApJ Letters, 5 pages, 2 figure
Electron-deuteron scattering in the equal-time formalism: beyond the impulse approximation
Using a three-dimensional formalism that includes relativistic kinematics,
the effects of negative-energy states, approximate boosts of the two-body
system, and current conservation, we calculate the electromagnetic form factors
of the deuteron up to Q^2 of 4 GeV^2. This is done using a dynamical boost for
two-body systems with spin. We first compute form factors in impulse
approxmation, but then also add an isoscalar meson-exchange current of pion
range that involves the gamma-pi contact operator associated with pseudovector
pi-N coupling. We also consider effects of the rho-pi-gamma meson-exchange
current. The experimentally measured quantities A, B, and t20 are calculated
over the kinematic range probed in recent Jefferson Laboratory experiments. The
rho-pi-gamma meson-exchange current provides significant strength in A at large
Q^2 and the gamma-pi contact-term exchange current shifts t20, providing good
agreement with the JLab data. Relativistic effects and the gamma-pi
meson-exchange current do not provide an explanation of the B observable, but
the rho-pi-gamma current could help to provide agreement if a nonstandard value
is used for the tensor rho-N coupling that enters this contribution.Comment: 15 pages, 10 figures. (v2) Added references on rho-pi-gamma current
as well as comparison to recent Novosibirsk data on T20. Implemented
\includegraphics in place of \BoxedEPSF. (v3) Modified in order to clarify
the nature of the boost we implemented for particles with spin. Other minor
changes. Version to be published in Physical Review
Electromagnetic Scattering from Relativistic Bound States
The quasipotential formalism for elastic scattering from relativistic bound
states is formulated based on the instant constraint in the Breit frame. The
quasipotential electromagnetic current is derived from Mandelstam's five-point
kernel and obeys a two-body Ward identity. Breit-frame wave functions are
obtained directly by solving integral equations with nonzero total
three-momentum, thus accomplishing a dynamical boost. Calculations of
electron-deuteron elastic form factors illustrate the importance of the
dynamical boost versus kinematic boosts of the rest frame wave functions.Comment: RevTeX 3.0 manuscript, 9 pages. UU-file is a single PostScript file
of the manuscript including figures. U. MD PP #93-17
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