76 research outputs found

    A temperature-controlled device for volumetric measurements of Helium adsorption in porous media

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    We describe a set-up for studying adsorption of helium in silica aerogels, where the adsorbed amount is easily and precisely controlled by varying the temperature of a gas reservoir between 80 K and 180 K. We present validation experiments and a first application to aerogels. This device is well adapted to study hysteresis, relaxation, and metastable states in the adsorption and desorption of fluids in porous media

    Validating foundry technologies for extended mission profiles

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    This paper presents a process qualification and characterization strategy that can extend the foundry process reliability potential to meet specific automotive mission profile requirements. In this case study, data and analyses are provided that lead to sufficient confidence for pushing the allowed mission profile envelope of a process towards more aggressive (automotive) applications.\ud \u

    Aggregation-fragmentation and individual dynamics of active clusters

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    International audienceA remarkable feature of active matter is the propensity to self-organize. One striking instance of this ability to generate spatial structures is the cluster phase, where clusters broadly distributed in size constantly move and evolve through particle exchange, breaking or merging. Here we propose an exhaustive description of the cluster dynamics in apolar active matter. Exploiting large statistics gathered on thousands of Janus colloids, we measure the aggregation and fragmentation rates and rationalize the resulting cluster size distribution and fluctuations. We also show that the motion of individual clusters is entirely consistent with a model positing random orientation of colloids. Our findings establish a simple, generic model of cluster phase, and pave the way for a thorough understanding of clustering in active matter

    Helium condensation in aerogel: avalanches and disorder-induced phase transition

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    We present a detailed numerical study of the elementary condensation events (avalanches) associated to the adsorption of 4^4He in silica aerogels. We use a coarse-grained lattice-gas description and determine the nonequilibrium behavior of the adsorbed gas within a local mean-field analysis, neglecting thermal fluctuations and activated processes. We investigate the statistical properties of the avalanches, such as their number, size and shape along the adsorption isotherms as a function of gel porosity, temperature, and chemical potential. Our calculations predict the existence of a line of critical points in the temperature-porosity diagram where the avalanche size distribution displays a power-law behavior and the adsorption isotherms have a universal scaling form. The estimated critical exponents seem compatible with those of the field-driven Random Field Ising Model at zero temperature.Comment: 16 pages, 14 figure

    Local mean-field study of capillary condensation in silica aerogels

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    We apply local mean-field (i.e. density functional) theory to a lattice model of a fluid in contact with a dilute, disordered gel network. The gel structure is described by a diffusion-limited cluster aggregation model. We focus on the influence of porosity on both the hysteretic and the equilibrium behavior of the fluid as one varies the chemical potential at low temperature. We show that the shape of the hysteresis loop changes from smooth to rectangular as the porosity increases and that this change is associated to disorder-induced out-of-equilibrium phase transitions that differ on adsorption and on desorption. Our results provide insight in the behavior of 4^4He in silica aerogels.Comment: 19 figure

    Run and tumble particle under resetting:a renewal approach

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    We consider a particle undergoing run and tumble dynamics, in which its velocity stochastically reverses, in one dimension. We study the addition of a Poissonian resetting process occurring with rate rr. At a reset event the particle's position is returned to the resetting site XrX_r and the particle's velocity is reversed with probability η\eta. The case η=1/2\eta = 1/2 corresponds to position resetting and velocity randomization whereas η=0\eta =0 corresponds to position-only resetting. We show that, beginning from symmetric initial conditions, the stationary state does not depend on η\eta i.e. it is independent of the velocity resetting protocol. However, in the presence of an absorbing boundary at the origin, the survival probability and mean time to absorption do depend on the velocity resetting protocol. Using a renewal equation approach, we show that the the mean time to absorption is always less for velocity randomization than for position-only resetting.Comment: 16 pages, 1 figure, version accepted in Journal of Physics

    Studying Amphiphilic Self-assembly with Soft Coarse-Grained Models

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    Multiscale Molecular Simulations of Polymer-Matrix Nanocomposites

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