The response of the inner magnetosphere to the trailing edges of high‐speed solar‐wind streams

The effects of the leading edge stream interface of high‐speed solar‐wind streams (HSSs) upon the Earth’s magnetosphere have been extensively documented. The arrival of HSSs leads to significant changes in the plasmasphere, plasma sheet, ring current, and radiation belts, during the evolution from slow solar wind to persistent fast solar wind. Studies have also documented effects in the lower ionosphere and the neutral atmosphere. However, only cursory attention has been paid to the trailing‐edge stream interface during the transition back from fast solar wind to slow solar wind. Here we report on the statistical changes that occur in the plasmasphere, plasma sheet, ring current, and electron radiation belt during the passage of the trailing‐edge stream interface of HSSs, when the magnetosphere is in most respects in an extremely quiescent state. Counterintuitively, the peak flux of ~1 MeV electrons is observed to occur at this interface. In contrast, other regions of the magnetosphere demonstrate extremely quiet conditions. As with the leading‐edge stream interface, the occurrence of the trailing‐edge stream interface has a periodicity of 27 days, and hence, understanding the changes that occur in the magnetosphere during the passage of trailing edges of HSSs can lead to improved forecasting and predictability of the magnetosphere as a system.Key PointsThe electron radiation belt flux peaks during the passage of HSS trailing‐edge stream interfaceCounterintuitively, the peak flux occurs when the magnetosphere is in its most calm configurationThe hazard from so‐called killer electrons is maximized; at the same time, hazard from spacecraft surface charging is minimizedPeer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/136314/1/jgra53192.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/136314/2/jgra53192_am.pd

Poisson-Boltzmann Theory of Charged Colloids: Limits of the Cell Model for Salty Suspensions

Thermodynamic properties of charge-stabilised colloidal suspensions are commonly modeled by implementing the mean-field Poisson-Boltzmann (PB) theory within a cell model. This approach models a bulk system by a single macroion, together with counterions and salt ions, confined to a symmetrically shaped, electroneutral cell. While easing solution of the nonlinear PB equation, the cell model neglects microion-induced correlations between macroions, precluding modeling of macroion ordering phenomena. An alternative approach, avoiding artificial constraints of cell geometry, maps a macroion-microion mixture onto a one-component model of pseudo-macroions governed by effective interactions. In practice, effective-interaction models are usually based on linear screening approximations, which can accurately describe nonlinear screening only by incorporating an effective (renormalized) macroion charge. Combining charge renormalization and linearized PB theories, in both the cell model and an effective-interaction (cell-free) model, we compute osmotic pressures of highly charged colloids and monovalent microions over a range of concentrations. By comparing predictions with primitive model simulation data for salt-free suspensions, and with predictions of nonlinear PB theory for salty suspensions, we chart the limits of both the cell model and linear-screening approximations in modeling bulk thermodynamic properties. Up to moderately strong electrostatic couplings, the cell model proves accurate in predicting osmotic pressures of deionized suspensions. With increasing salt concentration, however, the relative contribution of macroion interactions grows, leading predictions of the cell and effective-interaction models to deviate. No evidence is found for a liquid-vapour phase instability driven by monovalent microions. These results may guide applications of PB theory to soft materials.Comment: 27 pages, 5 figures, special issue of Journal of Physics: Condensed Matter on "Classical density functional theory methods in soft and hard matter

Stability of Colloidal Quasicrystals

Freezing of charge-stabilized colloidal suspensions and relative stabilities of crystals and quasicrystals are studied using thermodynamic perturbation theory. Macroion interactions are modelled by effective pair potentials combining electrostatic repulsion with polymer-depletion or van der Waals attraction. Comparing free energies -- counterion terms included -- for elementary crystals and rational approximants to icosahedral quasicrystals, parameters are identified for which one-component quasicrystals are stabilized by a compromise between packing entropy and cohesive energy.Comment: 6 pages, 4 figure

The catalytic Mitsunobu reaction: a critical analysis of the current state-of-the-art

The Mitsunobu reaction is widely regarded as the pre-eminent method for performing nucleophilic substitutions of alcohols with inversion of configuration. However, its applicability to large-scale synthesis is undermined by the fact that alcohol activation occurs at the expense of two stoichiometric reagents – a phosphine and an azodicarboxylate. The ideal Mitsunobu reaction would be sub-stoichiometric in the phosphine and azodicarboxylate species and employ innocuous terminal oxidants and reductants to achieve recycling. This Review article provides a summary and analysis of recent advances towards the development of such catalytic Mitsunobu reactions

Preface: Unsolved problems of magnetospheric physics

The Unsolved Problems of Magnetospheric Physics Workshop was held in September 2015 in Scarborough, UK. In contrast to most other meetings, people were specifically asked not to present and discuss their recent results. Rather, they were asked to bring their opinions and thoughts on unsolved problems to the meeting. Short presentations were encouraged after which the audience would debate and discuss definitions of the problems and how they could be overcome. Were new observations required? New missions? Or simply did the community need to work better together to resolve pertinent and outstanding science questions? Around 50% of the meeting schedule was devoted to discussion sessions on these topics.Key PointsMany unsolved problems exist in magnetospheric physicsThe UPMP workshop discussed these problems and suggested possible solutionsFor some problems, the community already have the data and the tools to make rapid progressPeer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/135163/1/jgra53053_am.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/135163/2/jgra53053.pd

A modelling study of the latitudinal variations in the nighttime plasma temperatures of the equatorial topside ionosphere during northern winter at solar maximum

International audienceLatitudinal variations in the nighttime plasma temperatures of the equatorial topside ionosphere during northern winter at solar maximum have been examined by using values modelled by SUPIM (Sheffield University Plasmasphere Ionosphere Model) and observations made by the DMSP F10 satellite at 21.00 LT near 800 km altitude. The modelled values confirm that the crests observed near 15° latitude in the winter hemisphere are due to adiabatic heating and the troughs observed near the magnetic equator are due to adiabatic cooling as plasma is transported along the magnetic field lines from the summer hemisphere to the winter hemisphere. The modelled values also confirm that the interhemispheric plasma transport needed to produce the required adiabatic heating/cooling can be induced by F-region neutral winds. It is shown that the longitudinal variations in the observed troughs and crests arise mainly from the longitudinal variations in the magnetic meridional wind. At longitudes where the magnetic declination angle is positive the eastward geographic zonal wind combines with the northward (summer hemisphere to winter hemisphere) geographic meridional wind to enhance the northward magnetic meridional wind. This leads to deeper troughs and enhanced crests. At longitudes where the magnetic declination angle is negative the eastward geographic zonal wind opposes the northward geographic meridional wind and the trough depth and crest values are reduced. The characteristic features of the troughs and crests depend, in a complicated manner, on the field-aligned flow of plasma, thermal conduction, and inter-gas heat transfer. At the latitudes of the troughs/crests, the low/high plasma temperatures lead to increased/decreased plasma concentrations.Key words: Ionosphere (equatorial ionosphere; ionosphere-atmosphere interactions

Density functional theory of freezing for soft interactions in two dimensions

A density functional theory of two-dimensional freezing is presented for a soft interaction potential that scales as inverse cube of particle distance. This repulsive potential between parallel, induced dipoles is realized for paramagnetic colloids on an interface, which are additionally exposed to an external magnetic field. An extended modified weighted density approximation which includes correct triplet correlations in the liquid state is used. The theoretical prediction of the freezing transition is in good agreement with experimental and simulation data.Comment: 7 pages, 3 figures, submitted 200