Original Conductive Nano-Co3O4 Investigated as Electrode Material for Hybrid Supercapacitors

Cobalt oxides have been extensively used as conductive additives for Ni-MH batteries. We report in this paper the performances of an original nanometric cobalt oxide, close to Co3O4, as electrode material for hybrid supercapacitors. This spinel type phase contains hydrogen, lithium, cobalt vacancies, and especially Co4þ ions within the structure, leading to a high electronic conductivity. Cyclic voltammetry and impedance spectroscopy measurements show interesting capacitance (320 F/g in 8M-KOH), as well as good electrochemical cycling with a small amount of carbon black (5%)

Robustness of subspace-based algorithms with respect to the distribution of the noise: application to DOA estimation

International audienceThis paper addresses the theoretical analysis of the robustness of subspace-based algorithms with respect to non-Gaussian noise distributions using perturbation expansions. Its purpose is twofold. It aims, first, to derive the asymptotic distribution of the estimated projector matrix obtained from the sample covariance matrix (SCM) for arbitrary distributions of the useful signal and the noise. It proves that this distribution depends only of the second-order statistics of the useful signal, but also on the second and fourth-order statistics of the noise. Second, it derives the asymptotic distribution of the estimated projector matrix obtained from any M-estimate of the covariance matrix for both real (RES) and complex elliptical symmetric (CES) distributed observations. Applied to the MUSIC algorithm for direction-of-arrival (DOA) estimation, these theoretical results allow us to theoretically evaluate the performance loss of this algorithm for heavy-tailed noise distributions when it is based on the SCM, which is significant for weak signal-to-noise ratio (SNR) or closely spaced sources. These results also make it possible to prove that this performance loss can be alleviated by replacing the SCM by an M-estimate of the covariance for CES distributed observations, which has been observed until now only by numerical experiments

Slepian-Bangs formula and Cramér Rao bound for circular and non-circular complex elliptical symmetric distributions

International audienceThis letter is mainly dedicated to an extension of the Slepian-Bangs formula to non-circular complex elliptical symmetric (NC-CES) distributions, which is derived from a new stochastic representation theorem. This formula includes the non-circular complex Gaussian and the circular CES (C-CES) distributions. Some general relations between the Cramér Rao bound (CRB) under CES and Gaussian distributions are deduced. It is proved in particular that the Gaussian distribution does not always lead to the largest stochastic CRB (SCRB) as many authors tend to believe it. Finally a particular attention is paid to the noisy mixture where closed-form expressions for the SCRBs of the parameters of interest are derived

Asymptotic optimal SINR performance bound for space-time beamforming

International audienceIn many detection applications, the main performance criterion is the signal to interference plus noise ratio (SINR). After linear filtering, the optimal SINR corresponds to the maximum value of a Rayleigh quotient, which can be interpreted as the largest generalized eigenvalue of two covariance matrices. Using an extension of Szegö's theorem for the generalized eigenvalues of Hermitian block Toeplitz matrices, an expression of the theoretical asymptotic optimal SINR w.r.t. the number of taps is derived for arbitrary arrays with a limited but arbitrary number of sensors and arbitrary spectra. This bound is interpreted as an optimal zero-bandwidth spatial SINR in some sense. Finally, the speed of convergence of the optimal wideband SINR for a limited number of taps is analyzed for several interference scenario

Performance limits of alphabet diversities for FIR SISO channel identification

10 pagesInternational audienceFinite Impulse Responses (FIR) of Single-Input Single-Output (SISO) channels can be blindly identified from second order statistics of transformed data, for instance when the channel is excited by Binary Phase Shift Keying (BPSK), Minimum Shift Keying (MSK) or Quadrature Phase Shift Keying (QPSK) inputs. Identifiability conditions are derived by considering that noncircularity induces diversity. Theoretical performance issues are addressed to evaluate the robustness of standard subspace-based estimators with respect to these identifiability conditions. Then benchmarks such as asymptotically minimum variance (AMV) bounds based on various statistics are presented. Some illustrative examples are eventually given where Monte Carlo experiments are compared to theoretical performances. These comparisons allow to quantify limits to the use of the alphabet diversities for the identification of FIR SISO channels, and to demonstrate the robustness of algorithms based on High-Order Statistics

Application of TELEMAC2D for water levels assessment in the Laita estuary, France

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Spectral-Spatial Method for Hyperspectral Image classification in Noisy Environment

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On the sensitivity of third-order Volterra MVDR beamformers to interference-pulse shaping filter

International audienceLinear beamformers are optimal, in a mean square (MS) sense, when the signal of interest (SOI) and observations are jointly Gaussian and circular. Otherwise, optimal beamformers become non-linear with a structure depending on the unknown joint probability distribution of the SOI and observations. In this context, third-order Volterra minimum variance distortionless response (MVDR) beamformers have been proposed recently to improve the performance of linear beamformers in the presence of non-Gaussian and potentially non-circular interference, omnipresent in practical situations. High performance gains have been obtained for binary phase shift keying (BPSK) and quadrature phase shift keying (QPSK) interference having a square pulse shaping filter in particular. However in practice, for spectral efficiency reasons, most of signals use non-square pulse shaping filters, such as square root raised cosine filter. It is then important to analyze the sensitivity of third-order MVDR beamformers to interference pulse shaping filter, which is the purpose of this paper