676 research outputs found
Hydrodynamics and mass transfer in bubble column: Influence of liquid phase surface tension
According to literature, few experiments are performed in organic solvents which are mostly used in commercial gas–liquid reactors. However, it is commonly accepted that data obtained in aqueous solution allow to predict the surface tension effects, and to model the behaviour of
organic solvents. In this work, we examine the validity of this approximation. In this objective, the flows observed in two pure media having similar viscosity but different surface tension—respectively, water (reference) and cyclohexane (solvent)—are successively compared at two scales: in a bubble column and in bubble plumes.
In bubble plumes, as expected, the mean bubble size is smaller in the medium having the smallest surface tension (cyclohexane), but for this medium the destabilisation of flow is observed to occur at smaller gas velocity, due to break-up and coalescence phenomena. In bubble
column, these phenomena induce the bubbling transition regime at lower gas velocity, whatever the operating conditions for liquid phase: batch or continuous. Consequently, when the two media are used at similar gas superficial velocity, but in different hydrodynamic regimes, greater gas hold-up and smaller bubble diameter can be observed in water; the interfacial area is then not always higher in cyclohexane.
This result differs from the behaviour observed in the literature for aqueous solutions. The analysis of bubble plumes in aqueous solutions of butanol shows that this difference is due to a fundamental difference in coalescent behaviour between pure solvents and aqueous mixtures:
the surface tension effect is less important in pure liquid than in aqueous solutions, because of the specific behaviour of surfactants.
It is then still difficult to predict a priori the bubbling regime or the flow characteristics for a given medium, and all the more to choose an appropriate liquid as a model for industrial solvents
Axial and Radial Investigation of Hydrodynamics in a Bubble Column;Influence of Fluids Flow Rates and Sparger Type
A detailed investigation of local hydrodynamics in a pilot plant bubble column has been performed using various techniques, exploring both axial and radial variations
of the gas hold-up, bubble average diameter and frequency, surface area. A wide range of operating conditions has been explored up to large gas and liquid
flow rates, with two sparger types. Two main complementary techniques were used: a quasi local measurement of gas hold-up via series of differential pressure
sensors to get the axial variation and a double optic probe giving radial variations of gad hold-up, bubble average size and frequency and surface area.
According to axial evolutions, three zones, where radial evolutions have been detailed,have been separated: at the bottom the gas injection zone, the large central region or column bulk and the disengagement zone at the column top. It was found that significant axial and radial variations of the two phase flow characteristics
do exist even in the so called homogeneous regime. The normalized profiles of bubble frequency appear sparger and gas velocity independent contrary to bubble
diameter, gas hold-up and interfacial area normalized profiles. In any case bubbles are larger in the sparger zone than elsewhere.
The main result of this work is the very strong effect of liquid flow on bubble column
hydrodynamics at low gas flow rate. First the flow regime map observed in batch mode is dramatically modified with a drastic reduction of the homogeneous
regime region, up to a complete heterogeneous regime in the working conditions (uG> 0.02 m/s). On the contrary, liquid flow has limited effects at very high gas
flow rates. A large data bank is provided to be used for example in detailed comparison with
CFD calculations
Ultrasound in gas–liquid systems: Effects on solubility and mass transfer
The effect of ultrasound on the pseudo-solubility of nitrogen in water and on gas–liquid mass transfer kinetics has been investigated in an autoclave reactor equipped with a gas induced impeller. In order to use organic liquids and to investigate the effect of pressure, gas–liquid mass transfer coefficient was calculated from the evolution of autoclave pressure during gas absorption to avoid any side-effects of ultrasound on the concentrations measurements. Ultrasound effect on the apparent solubility is very low (below 12%). Conversely ultrasound greatly improves gas–liquid mass transfer, especially below gas induction speed, this improvement being boosted by pressure. In typical conditions of organic synthesis: 323 K, 1100 rpm, 10 bar, kL a is multiplied by 11 with ultrasound (20 kHz/62.6 W). The impact of sonication is much higher on gassing out than on gassing in. In the same conditions, this enhancement is at least five times higher for degassing
Refractory compounds abatement by adsorption and oxidative catalytic regeneration on activated carbon Experimental and modelling of competitive adsorption
Experimental and modelling of competitive adsorptio
Adsorption of aqueous organic mixtures on activated carbon: experiments and modelling of competitive adsorption
Experiments and modelling of competitive adsorptio
Theoretical analysis of tracer method for the measurement of wetting efficiency
This work investigates the tracer technique for the measurement of catalyst wetting efficiency, f, in
trickle-bed reactor.
The model of Ramachandran et al. (1986), based on a 2D description of the tracer diffusion, is applied for
the full range of wetting efficiency. It is also extended to account for the effects of axial dispersion, liquidsolid
mass transfer, pattern of the wetted zone on the pellet, and distribution of the partial wetting along the
reactor.
The numerical method for parameter optimisation implies a frequency domain least-squares procedure. A sensitivity analysis has been performed proving the wetting efficiency may be derived with convenient accuracy in usual trickle-bed conditions: high Peclet and Biot numbers.
For f>0.3, it is shown that wetting efficiency can be accurately calculated from apparent particle diffusivities
derived in liquid-full conditions (Deapp,LF) and in partial wetting regime (Deapp,TB), using the following
relation: f=sqrt(Deapp,TB)/(Deapp,LF)
Selective hydrogenation in trickle-bed reactor. Experimental and modelling including partial wetting.
A steady state model of a trickle bed reactor is developed for the consecutive hydrogenation of 1,5,9-cyclododecatriene on a Pd/Al2O3 catalyst. Various experiments have shown that the selectivity of this reaction towards the product of interest is much lower in co-current down-flow (trickle-bed) than in up-flow. This is due to uneven liquid distribution and to partial wetting of the catalyst surface at low liquid flow rates. The non-isothermal heterogeneous model proposed here takes into account the partial wetting of the catalyst, as well as the resistances to heat and mass transfer at the gas-liquid, liquid-solid and solid-gas interfaces. It assumes that the catalyst particles can be divided into two distinct concentration zones corresponding to the wetted and dry catalyst surfaces; mass transfer between these two zones is described by a simplified diffusion mechanism. Compared to previous models assuming a uniform concentration of liquid-phase components inside the catalyst particles, this model improves the prediction of the outlet concentrations of hydrogenation products
Mass transfer in bubble column for industrial conditions—effects of organic medium, gas and liquid flowrates and column design
Most of available gas–liquid mass transfer data in bubble column have been obtained in aqueous media and in liquid batch conditions, contrary to industrial chemical reactor conditions. This work provides new data more relevant for industrial conditions, including comparison of water and organic media, effects of large liquid and gas velocities, perforated plates and sparger hole diameter. The usual dynamic O2 methods for mass transfer investigation were not convenient in this work (cyclohexane, liquid circulation). Steadystate mass transfer of CO2 in an absorption–desorption loop has been quantified by IR spectrometry. Using a simple RTD characterization, mass transfer efficiency and kLa have been calculated in a wide range of experimental conditions. Due to large column height and gas velocity, mass transfer efficiency is high, ranging between 40% and 90%. kLa values stand between 0.015 and 0.050 s−1 and depend mainly on superficial gas velocity. No significant effects of column design and media have been shown. At last, using both global and local hydrodynamics data, mass transfer connection with hydrodynamics has been investigated through kLa/G and kLa/a
On the reliability of an optical fibre probe in bubble column under industrial relevant operating conditions
When bubble columns are operated under industrial relevant conditions (high gas and liquid flow rates, large bubbles and vortices,. . .), local data, and especially bubble size values, are difficult to obtain. However, such data are essential for the comprehension of two-phase flow phenomena in order to design or to improve industrial installations.
When high gas flow rates and organic liquids are used, intrusive optic probes are considered. This work investigates different ways to derive reliable local information on gas phase from double optic probe raw data. As far as possible, these results have been compared
with global data, easier to measure in such conditions.
Local gas hold-up, eG, and bubble frequency, fB, are easily obtained, but bubble velocity and bubble diameter determination is not obvious. For a better reliability, the final treatment that is proposed for velocity and size estimation is based on mean values only: the bubble velocity is considered as the most probable velocity ~v issued from raw signals inter-correlation function and the mean Sauter diameter is calculated through dSM ¼ 3~veG
2f B
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