Three-dimensional nuclear spin positioning using coherent radio-frequency control

Distance measurements via the dipolar interaction are fundamental to the application of nuclear magnetic resonance (NMR) to molecular structure determination, but they only provide information on the absolute distance $r$ and polar angle $\theta$ between spins. In this Letter, we present a protocol to also retrieve the azimuth angle $\phi$. Our method relies on measuring the nuclear precession phase after application of a control pulse with a calibrated external radio-frequency coil. We experimentally demonstrate three-dimensional positioning of individual carbon-13 nuclear spins in a diamond host crystal relative to the central electronic spin of a single nitrogen-vacancy center. The ability to pinpoint three-dimensional nuclear locations is central for realizing a nanoscale NMR technique that can image the structure of single molecules with atomic resolution.Comment: 5 pages, 4 figure

High-bandwidth microcoil for fast nuclear spin control

The active manipulation of nuclear spins with radio-frequency (RF) coils is at the heart of nuclear magnetic resonance (NMR) spectroscopy and spin-based quantum devices. Here, we present a microcoil transmitter system designed to generate strong RF pulses over a broad bandwidth, allowing for fast spin rotations on arbitrary nuclear species. Our design incorporates: (i) a planar multilayer geometry that generates a large field of 4.35 mT per unit current, (ii) a 50 Ohm transmission circuit with a broad excitation bandwidth of approximately 20 MHz, and (iii) an optimized thermal management for removal of Joule heating. Using individual 13C nuclear spins in the vicinity of a diamond nitrogen-vacancy (NV) center as a test system, we demonstrate Rabi frequencies exceeding 70 kHz and nuclear pi/2 rotations within 3.4 us. The extrapolated values for 1H spins are about 240 kHz and 1 us, respectively. Beyond enabling fast nuclear spin manipulations, our microcoil system is ideally suited for the incorporation of advanced pulse sequences into micro- and nanoscale NMR detectors operating at low (<1 T) magnetic field.Comment: 8 pages, 5 figures. Submitted to Rev. Sci. Inst

Quantum sensing with arbitrary frequency resolution

Quantum sensing takes advantage of well controlled quantum systems for performing measurements with high sensitivity and precision. We have implemented a concept for quantum sensing with arbitrary frequency resolution, independent of the qubit probe and limited only by the stability of an external synchronization clock. Our concept makes use of quantum lock-in detection to continuously probe a signal of interest. Using the electronic spin of a single nitrogen vacancy center in diamond, we demonstrate detection of oscillating magnetic fields with a frequency resolution of 70 uHz over a MHz bandwidth. The continuous sampling further guarantees an excellent sensitivity, reaching a signal-to-noise ratio in excess of 10,000:1 for a 170 nT test signal measured during a one-hour interval. Our technique has applications in magnetic resonance spectroscopy, quantum simulation, and sensitive signal detection.Comment: Manuscript resubmitted to Science. Includes Supplementary Material

Elastometry of deflated capsules elastic moduli from shape and wrinkle analysis

Elastic capsules, prepared from droplets or bubbles attached to a capillary (as in a pendant drop tensiometer), can be deflated by suction through the capillary. We study this deflation and show that a combined analysis of the shape and wrinkling characteristics enables us to determine the elastic properties in situ. Shape contours are analyzed and fitted using shape equations derived from nonlinear membrane-shell theory to give the elastic modulus, Poisson ratio and stress distribution of the membrane. We include wrinkles, which generically form upon deflation, within the shape analysis. Measuring the wavelength of wrinkles and using the calculated stress distribution gives the bending stiffness of the membrane. We illustrate this method on two very different capsule materials: polymerized octadecyltrichlorosilane (OTS) capsules and hydrophobin (HFBII) coated bubbles. Our results are in agreement with the available rheological data. For hydrophobin coated bubbles the method reveals an interesting nonlinear behavior consistent with the hydrophobin molecules having\ud a rigid core surrounded by a softer shell

Genetic conservation within managed forests in Amazonia: dendrogene project.

Editado por Bernd Degen, Marilyn D. Loveless e Antoine Kremer

Evolutionary implications of a high selfing rate in the freshwater snail Lymnaea truncatula.

Self-compatible hermaphroditic organisms that mix self-fertilization and outcrossing are of great interest for investigating the evolution of mating systems. We investigate the evolution of selfing in Lymnaea truncatula, a self-compatible hermaphroditic freshwater snail. We first analyze the consequences of selfing in terms of genetic variability within and among populations and then investigate how these consequences along with the species ecology (harshness of the habitat and parasitism) might govern the evolution of selfing. Snails from 13 localities (classified as temporary or permanent depending on their water availability) were sampled in western Switzerland and genotyped for seven microsatellite loci. F(IS) (estimated on adults) and progeny array analyses (on hatchlings) provided similar selfing rate estimates of 80%. Populations presented a low polymorphism and were highly differentiated (F(ST) = 0.58). Although the reproductive assurance hypothesis would predict higher selfing rate in temporary populations, no difference in selfing level was observed between temporary and permanent populations. However, allelic richness and gene diversity declined in temporary habitats, presumably reflecting drift. Infection levels varied but were not simply related to either estimated population selfing rate or to differences in heterozygosity. These findings and the similar selfing rates estimated for hatchlings and adults suggest that within-population inbreeding depression is low in L. truncatula

Entwicklung eines Messverfahrens auf Thermodesorptionsbasos zur Detektion schwerflüchtiger Kohlenwasserstoffe in Spurenkonzentrationen mit Gassensoren

In der Halbleiterindustrie ist eine unbelastete Umgebungsluft Voraussetzung für eine effiziente und störungsfreie Produktion. Von besonderem Interesse ist die Überwachung der Qualität der gefilterten Zuluft in den Reinräumen im Hinblick auf ihre Belastung mit kondensierbaren Kohlenwasserstoffen. Das im Rahmen dieser Arbeit entwickelte Messsystem Air Check ermöglicht mit einem neuartigen Messverfahren die selelktive Überwachung von Spurenkonzentrationen dieser schwerflüchtigen Sunbstanzen mit Gassensoren durch zeitaufgelöste Thermodesorption. das Messverfahren gliedert sich in einen adsorptiven Probenanreicherungsprozess, die Desortption der angereicherten Probe und die Messung der angereicherten Substanzen mit einem Array von Gassensoren. Die verfahrensparameter Trägergasgeschwindigkeit und Aufheizgeschwindigkeit während der Thermodesroption sowie Adsorbensmenge wurden hinsichtlich ihres Einfluss auf Empfindlichkeit und Selektivität des Messverfahrens systematisch untersucht. Das Verfahren ist unempfindlich gegen den Einfluss der Luftfeuchtigkeit und ermöglicht bei geeigneter Wahl der verfahrensparameter die Überwachung der kondensierbaren Kohlenwasserstoffe und ist dabei selbst in Konzentrationen bis hinab zu wenigen Parts per Billion (ppb) möglich

High resolution quantum sensing with shaped control pulses

We investigate the application of amplitude-shaped control pulses for enhancing the time and frequency resolution of multipulse quantum sensing sequences. Using the electronic spin of a single nitrogen vacancy center in diamond and up to 10,000 coherent microwave pulses with a cosine square envelope, we demonstrate 0.6 ps timing resolution for the interpulse delay. This represents a refinement by over 3 orders of magnitude compared to the 2 ns hardware sampling. We apply the method for the detection of external AC magnetic fields and nuclear magnetic resonance signals of carbon-13 spins with high spectral resolution. Our method is simple to implement and especially useful for quantum applications that require fast phase gates, many control pulses, and high fidelity.Comment: 5 pages, 4 figures, plus supplemental materia