2,056 research outputs found

    The isotopic and chemical evolution of planets: Mars as a missing link

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    The study of planetary bodies has advanced to a stage where it is possible to contemplate general models for the chemical and physical evolution of planetary interiors, which might be referred to as UMPES (Unified Models of Planetary Evolution and Structure). UMPES would be able to predict the internal evolution and structure of a planet given certain input parameters such as mass, distance from the sun, and a time scale for accretion. Such models are highly dependent on natural observations because the basic material properties of planetary interiors, and the processes that take place during the evolution of planets are imperfectly understood. The idea of UMPES was particularly unrealistic when the only information available was from the earth. However, advances have been made in the understanding of the general aspects of planetary evolution now that there is geochemical and petrological data available for the moon and for meteorites

    Models of Hawaiian volcano growth and plume structure: Implications of results from the Hawaii Scientific Drilling Project

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    The shapes of typical Hawaiian volcanoes are simply parameterized, and a relationship is derived for the dependence of lava accumulation rates on volcano volume and volumetric growth rate. The dependence of lava accumulation rate on time is derived by estimating the eruption rate of a volcano as it traverses the Hawaiian plume, with the eruption rate determined from a specified radial dependence of magma generation in the plume and assuming that a volcano captures melt from a circular area centered on the volcano summit. The timescale of volcano growth is t = 2 R/ν_plate where R is the radius of the melting zone of the (circular) plume and νplate is the velocity of the Pacific plate. The growth progress of a volcano can be described by a dimensionless time t′ = tν_plate/2R, where t′ = 0 is chosen to be the start of volcano growth and t′ = 1 approximates the end of “shield” growth. Using a melt generation rate for the whole plume of 0.2 km^(3)/yr, a plume diameter of 50 km, and a plate velocity of 10 cm/yr, we calculate that the lifetime of a typical volcano is 1000 kyr. For a volcano that traverses the axis of the plume, the “standard” dimensions are a volume of 57,000 km^3, a summit thickness of 18 km, a summit elevation of 3.6 km, and a basal radius of 60 km. The volcano first breaches the sea surface at t′ ≈ 0.22 when it has attained only 5% of its eventual volume; 80% of the volume accumulates between t′ = 0.3 and t′ = 0.7. Typical lava accumulation rates start out over 50 m/kyr in the earliest stages of growth from the seafloor, and level out at ∼35 m/kyr from t′ ≈ 0.05 until t′ = 0.4. From t′ = 0.4 to t′ = 0.9, the submarine lava accumulation rates decrease almost linearly from 35 m/kyr to ∼0; subaerial accumulation rates are about 30% lower. The lava accumulation rate is a good indicator of volcano age. A volcano that passes over the plume at a distance 0.4R off to the side of the plume axis is predicted to have a volume of about 60% of the standard volcano, a lifetime about 8% shorter, and lava accumulation rates about 15–20% smaller. The depth-age data for Mauna Kea lavas cored by the Hawaii Scientific Drilling Project are a good fit to the model parameters used, given that Mauna Kea appears to have crossed the plume about 15–20 km off-axis. The lifetime of Mauna Kea is estimated to be 920 kyr. Mauna Loa is predicted to be at a stage corresponding to t′ ≈ 0.8, Kilauea is at t′ ≈ 0.6, and Loihi is at t′ ≈0.16. The model also allows the subsurface structure of the volcanoes (the interfaces between lavas from different volcanoes) to be modeled. Radial geochemical structure in the plume may be blurred in the lavas because the volcanoes capture magma from a sizeable cross-sectional area of the plume; this inference is qualitatively born out by available isotopic data. The model predicts that new Hawaiian volcanoes are typically initiated on the seafloor near the base of the next older volcano but generally off the older volcano's flank

    Deep drilling into a Hawaiian volcano

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    Hawaiian volcanoes are the most comprehensively studied on Earth. Nevertheless, most of the eruptive history of each one is inaccessible because it is buried by younger lava flows or is exposed only below sea level. For those parts of Hawaiian volcanoes above sea level, erosion typically exposes only a few hundred meters of buried lavas (out of a total thickness of up to 10 km or more).Available samples of submarine lavas extend the time intervals of individual volcanoes that can be studied. However, the histories of individual Hawaiian volcanoes during most of their ~1-million-year passages across the zone of melt production are largely unknown

    The Passion Within: Challenging The Feminine Mystique By Educating Midlife Women To Fulfill Their Career Dreams

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    This study is a very personal reflection. The purpose of the study is to illuminate how following the calling of my heart led to a deeper passion in my own work whereupon I realized my natural and limitless creative potential. It is a blending of my narrative with research conducted over a ten year time period on midlife women, work, and the search for passion within. The capacity and fostering of creativity became a focus in my writing because that is exactly where my spirit has led me. It has been my personal joy to put something in this world that was not there before. My personal story is my unique Scholarly Personal Narrative, but the story itself and the constructs embedded within on midlife women moving beyond the feminine mystique to fulfill their career dreams by embracing their passion and seeking creativity is universal to many women. I believe that my experiences are both generalizable and transferable and will serve as a beacon of light in guiding other midlife women in their own journey to follow their dreams and nurture their true self. Scholarly Personal Narrative was used to blend my experiences with research on women\u27s identity, midlife, reinventing careers, opting-out, on-ramps for women returning to work and expressing creativity. My narrative speaks to how specific events in my life, as in many women\u27s lives, have contributed to finding my own authentic voice, navigating a course of rediscovery, and ultimately realizing the personal power of knowing you are empowered. Throughout my writing I highlight that midlife is a unique period of time. I believe it can be claustrophobic and it can be ripe with opportunity and adventure. If you allow it, this time of life affords an opportunity for self-discovery and unanticipated growth. Midlife is a time to dig deep in examining our life experiences to extrapolate meaning. My meanings derived combined with my dreams within has led me in finding my true creative calling through my work. But, I believe that we each are the only ones who can find the meaning in and through our life experiences because they both form and inform our own truth. It became about harmonizing creative development, my identity, and work to fuel major change. Universal themes that emerge include recognizing one\u27s creativity has worth, viewing future work life as an opportunity to incorporate that with which we are passionate, and embracing midlife as a time for positive personal growth and change. It is a complex narrative, but in finding the truth, I became open to building on the successes, experiences, and lessons of my past to pursue work that excites, enriches, and motivates me. Findings suggest that midlife is a crucial time of personal and professional growth. Findings also suggest many highly educated women have non-linear career paths which in turn deepen our self-understanding moving us toward authenticity and allowing ourselves to engage in work that matters to us. Embracing creativity in midlife, through our work. can fill us with both passion and purpose and ultimately lead us on a magical journey in discovering our own truth

    Chem 777-104:Principles Pharm Chemistry

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    Introduction to special section: Hawaii Scientific Drilling Project

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    Intraplate or "hot spot" volcanic island chains, exemplified by Hawaii, play an important role in plate tectonic theory as reference points for absolute plate motions, but the origin of these volcanoes is not explained by the plate tectonic paradigm [Engebretson et al., 1985; Molnar and Stock, 1987; Morgan, 1971, 1981, 1983; Wilson, 1963]. The most widely held view is that these chains of volcanoes form from magma generated by decompression melting of localized, buoyant upwellings in the mantle [Ribe and Christensen, 1994; Richards et al., 1988; Sleep, 1990; Watson and McKenzie, 1991] . These upwellings, or "plumes," are believed to originate at boundary layers in the mantle (e.g., at the core-mantle boundary or near the boundary at-670 km between the upper and lower mantle), and the cause of the buoyancy may be both compositional and thermal [Campbell and Griffiths, 1990; Griffiths, 1986; Richards et al., 1988; Watson and McKenzie, 1991]. Mantle plumes are responsible for about 10% of the Earth's heat loss and constitute an important mechanism for cycling mass from the deep mantle to the Earth's surface. Studies of the chemical and isotopic compositions of lavas from intraplate volcanoes, especially ocean island volcanoes, have contributed significantly to our knowledge of magma genesis in the mantle [Carmichael et al., 1974; Macdonald et al., 1983] and the compositional heterogeneity of the mantle [Allègre et al., 1983; Hart, 1988; Hart et al., 1986; Kurz et al., 1983]. Of particular importance is the identification of distinct compositional end members in the mantle, the origin and distribution of which provide insight into the long-term differentiation of the mantle-crust system, the recycling of oceanic crust and continental sediment into the mantle, and the history of the lithosphere [Allègre et al., 1995; Farley et al., 1992; Hart, 1988; Hofmann and White, 1982; McKenzie and O'Nions, 1983; Weaver, 1991; Zindler and Hart, 1986]

    Chem 126-102: General Chemistry II

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    CHEM 125-103: General Chemistry I

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    CHEM 714-101: Pharmaceutical Analysis

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