Capillary imbibition in cementitious materials : effect of salts and exposure condition

Concrete structures are often exposed to harsh environmental conditions during their service life. Therefore, the investigation of transport properties and deterioration of concrete in different environments is an important topic. This paper reports the influence of salts (NaCl and Na2SO4) and exposure conditions (ideal laboratory (20 °C, 95% RH), a city and sea environment; including sheltered and exposed conditions) on capillary imbibition in cementitious materials with different water to cement ratios (0.4 and 0.6). First, the pore structure was assessed by water absorption under vacuum, torrent permeability, resistivity, and moisture content. The second part revolves around the capillary imbibition phenomenon with different imbibition liquids (water, NaCl, and Na2SO4). The results showed that, among the studied exposure conditions, sheltered conditions resulted in the largest porosity values and capillary imbibition rates (CIR). The influence of the imbibing liquid on the CIR depends on the w/c of the concrete. The CIR value for samples with a w/c of 0.4 is lower for Na2SO4 as imbibing liquid in comparison to water and NaCl. The sulfates might cause a pore blocking effect leading to a decreased CIR. For concrete with a w/c of 0.6, there was no significant difference between the different imbibition liquids. The influence of the pore blocking effect is probably smaller due to the larger porosity in this case. The findings of this research are important to understand the influence of real-life exposure conditions and therefore the influence of relative humidity, temperature, carbonation, and chloride ingress on the capillary imbibition phenomenon

Influencing factors to the capillary water uptake of (un)cracked cementitious materials

Capillary water absorption tests are widely used in uncracked cementitious materials to assess the quality and durability. Due to the easy execution of the test, it is also frequently used to assess the self-healing efficiency of self-healing concrete and mortar. It is established that the presence of a crack significantly increases the water uptake by a specimen. However, it is not known how the crack width, healing agents and mix composition influence the capillary water absorption. In this research, for cylindrical mortar specimens with four different crack widths, both a capillary water absorption test and water permeability were test were executed in order to investigate the relation between these two test methods. After the first round of testing, cracked specimens were healed manually with polyurethane and methyl methacrylate and the capillary absorption test was performed again to investigate the sensitivity of the test method to different degrees of crack healing. Furthermore, prismatic specimens were cast to investigate the influence of crack creation and geometry. It was found that the crack width does not have an influence on the capillary absorption rate. However, the crack width has a significant influence on the water flow through the crack. As expected, manual healing with polyurethane is better in comparison to the sealing of the crack mouth with methyl methacrylate

Chloride resistance of self-healing mortar containing superabsorbent polymers measured via a (quasi) steady-state migration test

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